mannose, one of the eight essential monosaccharides, is biosynthesized as its 6-phosphate derivative from fructose 6-phosphate. no cofactor is required. draw curved arrows to show the movement of electrons in this step of the reaction mechanism.

In calorimetry, whatever happens in the system, the exact same change must occur to the surroundings is False.

What occurs in calorimetry?

Heat transfer rates to or from a substance are measured using calorimetry. Heat is transferred to do this using a calibrated item (calorimeter). Calculating the quantity of heat transmitted by the process under study requires using the temperature change recorded by the calorimeter.

The sealed calorimeter has thermometers that track temperature changes as a reaction takes place. This closed system functions similarly to a chemical reactor.

It's crucial to realize that in calorimetry difficulties, the material reacting is the "system," whilst the surroundings are made up of water and calorimetry. The heat exchanged between the "system" and "surroundings" is what is measured.

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The product of the following reaction has the constitution shown. No stereochemistry is implied. If the stereochemistry on the basis of the fact that iodolactonization is normally an anti addition and it was determined experimentally that the ring junction is cis then the correct option is Option A.

Since ring junction is cis means it Should be axial, equatorial or equatorial, axial.

And addition of Iodine is anti, that means iodine and ring junction are trans, it should be axial, axial or equatorial, equatorial position of Iodine and one of ring junction.

Note: 1,2-cis - axial, equatorial or equatorial, axial

         1,2-trans: axial, axial or equatorial, equatorial

So, The constitution is revealed in the result of the given reaction. There is no implication of stereochemistry. Option A is the correct option if the stereochemistry is based on the knowledge that iodolactonization is generally an anti addition and the ring junction was determined empirically to be cis.

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The 2 isotopes of Nitrogen are Nitrogen-14  and Nitrogen-15 .

Isotopes are atoms with the same number of protons and different number of neutrons. Even though they have nearly identical chemical properties, they differ in mass which affects their physical properties.

As you know, the atomic number of nitrogen is = 7.

Isotopes are forms of elements that have the same atomic number (Z) but different mass numbers because they have different numbers of neutrons (A).

Now,

Atomic number = number of protons

Isotopes have the same atomic number.

Atomic number for both isotopes = 7. However, the mass numbers of the two isotopes are different.

In other words, the mass number = the number of (protons + electrons).

Therefore, nitrogen-14 has a mass number of 14 and nitrogen-15 has a mass number of 15.

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Answer:

A. Protons and neutrons have the same mass; the mass of an electron is very close to zero

Explanation:

NaHCO3 is soluble in water.  NaHCO3 is ionic polar compound. water is polar quantities so, polar disolve in polar.

The basic concept of solubility is that like dissolves like. It means that polar substances are soluble in polar solvents and non-polar substances are soluble in non-polar solvents.

Solubility is described as the most amount of a substance so that it will dissolve in a given amount of solvent at a exact temperature. Solubility is a function property of a particular solute–solvent aggregate, and unique substances have substantially differing solubilities.

Solubility is the ability of a substance (solute) to form a solution with another substance (solvent). Insolubility is the opposite property, the inability of a solute to form such a solution.

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Bone density can be affected by a mutation. This mutation can cause very dense bones that are almost unbreakable therefore the true statement about mutations in organism is that changes caused by mutations can be harmful, beneficial, or neutral to an organism which is therefore denoted as option B.

This is referred to as a change in the DNA sequence of an organism and it occurs when there are errors during cell division.

The changes caused have different effects on the organisms which could be harmful, beneficial, or neutral.

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Silver nitrate 1:500 w/v solution 60 ml make isotonic solution using nacl sig. for eye use The method's equation is V=E x W(g)x (100mL) (0.9g)

Isotonic solutions are those that have the exact same water and solute concentrations as the cytoplasm of a cell. Since there is no net gain or loss of water, cells placed in an isotonic solution won't either contract or expand.

The Greek word isotonic, which approximately translates to equal or same tone. In an article on medicine.net, isotonic exercise causes the muscle to shorten while maintaining equal tone. Thus, throughout the activity, your muscles are under the same tension.

Isotonic solutions are used to increase the volume of extracellular fluid lost as a result of blood loss, surgery, dehydration, and fluid loss.

IV fluids known as isotonic solutions have a comparable level of dissolved particles to blood. Normal saline, or 0.9% sodium chloride, is an illustration of an isotonic IV solution.

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The empirical formula for each compound are as follow,

a)[tex]Ag_2 O[/tex]

b)[tex]Co_3As_2O_8[/tex]

c)[tex]SeBr_4[/tex]

As per the data share in the above question are as follow,

The mass of their constituent elements are as follow,

a) Ag=1.651 g

   O=0.1224 g

b)Co =0.672 g

    As =0.569 g

    O=0.486 g

c) Se =1.443 g

    Br =5.841 g

We have to calculate the empirical formula for each compound.

a)Now Moles of (given mass upon Molar mass) [tex]Ag=\frac{1.651}{108} =0.015 \:moles[/tex]

Moles of [tex]O=\frac{0.1224}{8\times 2} =0.0077 \:moles[/tex]

Smallest mole value [tex]0.0077 \:moles[/tex]

Divide all component by smallest mass.

Therefore [tex]Ag \Rightarrow\frac{0.015}{0.0077} \rightarrow2\\\\O \Rightarrow\frac{0.0077}{0.0077} \rightarrow1[/tex]

Combine to get empirical formula,

[tex]Ag_2 O[/tex]

b)Now Moles of (given mass upon Molar mass) [tex]Co=\frac{0672}{59} =0.011 \:moles[/tex]

Moles of [tex]As=\frac{0.569}{75} =0.0076\: moles[/tex]

Moles of [tex]O=\frac{0.486}{16} =0.0304 \:moles[/tex]

Smallest mole value [tex]0.0076 \:moles[/tex]

Divide all component by smallest mass.

Therefore

[tex]Co \Rightarrow\frac{0.011}{0.0076} \rightarrow1.5\rightarrow1.5 \times 2\rightarrow3\\\\As \Rightarrow\frac{0.0076}{0.0076} \rightarrow1\rightarrow1 \times 2\rightarrow2\\\\O \Rightarrow\frac{0.0304}{0.0076} \rightarrow4\rightarrow4 \times 2\rightarrow8[/tex]

Combine to get empirical formula,

[tex]Co_3As_2O_8[/tex]

c)Now Moles of (given mass upon Molar mass) [tex]Se=\frac{1.443}{79} =0.018 \:moles[/tex]

Moles of [tex]Br=\frac{5.841}{80} =0.073 \:moles[/tex]

Smallest mole value [tex]0.018 \:moles[/tex]

Divide all component by smallest mass.

Therefore

[tex]Se \Rightarrow\frac{0.018}{0.018} \rightarrow1\\\\Br \Rightarrow\frac{0.073}{0.018} \rightarrow4[/tex]

Combine to get empirical formula,

[tex]SeBr_4[/tex]

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1. The number of moles of KHP is found by dividing the mass of KHP by the molecular weight of KHP.

2. The number of moles of NaOH is found by multiplying the moles of KHP by the mole ratio of NaOH to KHP given by the above, balanced chemical reaction.

It will be presumed that more KHP is present in the solution if additional NaOH is added. As a result, the % KHP will be higher than anticipated. If the concentration of NaOH is doubled, just half the volume from the initial experiment is needed. To titrate NaOH with KHP, add NaOH from the burette to a predetermined amount of KHP. The mass and volume of KHP utilized to create the KHP solution are used to calculate the molarity of the KHP solution. The molarity of the NaOH is then determined using the information from the titration.

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Using xuv series, deduct about relationship between iodized energy and reactivity of metals that, The first ionization energy of a metal has little bearing on its reactivity.

Ionization energy, sometimes referred to as ionization potential, is the amount of energy needed to remove an electron from an isolated atom or molecule in physics and chemistry. Ionization energies are related with the removal of each subsequent electron, however they are most frequently employed when the first (and loosely held) electron is removed. In an electric discharge tube, when a quickly moving electron produced by an electric current collides with a gaseous atom of the element, causing it to eject one of its electrons, the ionization energy of a chemical element, given in joules or electron volts, is often measured. A hydrogen atom, which consists of an orbiting electron connected to a nucleus of one proton, requires one ionization energy of 1018 joules (13.6 electron volts) to completely expel an electron. The amount of an element's ionization energy depends on a number of factors, including the size of the atom, its electronic make-up, and the electric charge of its nucleus. Alkali metals are the simplest chemical elements to remove an electron from, whereas noble gases are the most difficult.

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Hexamethylphosphorous triamide is useful as a reagent in organic synthesis as a phosphorylating agent. It is engaged with carbon tetrachloride for the substitution of hydroxy groups with chlorides.

It is jumbled in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the composing of carbonates as well as the reduction of ozonides.

Air and moisture sensitive. Keep the container tightly direct in a dry and well-ventilated place. clashing with strong oxidizing agents.

lower aromatic aldehydes to symmetrical epoxides in good yield. Both cis- and trans-isomers are formed.

Under suitable conditions, the reaction of the intermediate with a second aldehyde can lead to mixed deoxybenzoins or diaryl enamines.

Has also been used for a variation of other reductions including that of ozonolysis intermediates: Helv. Chim. Acta, 50, 2387 (1967), and of primary alkyl nitro compounds to nitriles: Synthesis, 36 (1979).

Bromohydrins can be change to alkenes, by reductive elimination from their triflate esters

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At equilibrium, HCN is weaker Bronsted-Lowry acid, C₉H₇NH⁺ is stronger Bronsted-Lowry acid, C₉H₇NH is weaker  Bronsted-Lowry base and CN⁻ is stronger Bronsted-Lowry base.

CN⁻ + C₉H₇NH⁺ → HCN + C₉H₇N

Products are favored. So, CN⁻ accepted the proton instead of C₉H₇N and C₉H₇NH⁺ lost its proton instead of HCN.

 C₉H₇NH⁺ - stronger Bronsted-Lowry acid

 C₉H₇N - weaker  Bronsted-Lowry base

 HCN - weaker Bronsted-Lowry acid

 CN⁻ - stronger Bronsted-Lowry base

So, at equilibrium, HCN is weaker Bronsted-Lowry acid, C₉H₇NH⁺ is stronger Bronsted-Lowry acid, C₉H₇NH is weaker  Bronsted-Lowry base and CN⁻ is stronger Bronsted-Lowry base.

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The Dayton accords brought the deployment of peacekeeping troops to Bosnia and is therefore denoted as option A.

This is referred to a peace agreement which was reached on Nov. 21, 1995 in which warring parties agreed to peace and to a single sovereign state known as Bosnia and Herzegovina.

This type of accord was led to the deployment of peacekeeping troops to the area in other to tackle the conflict and ensures that human right due to the killings and other vices which occurred during this period and is still maintained thereby making option A the correct choice.

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The volume of the hydrogen gas in atm.0.97 atm is 1.78 L.

An ideal gas is a theoretical gas composed of many randomly transferring factor particles that aren't difficult to interparticle interactions. the best gasoline idea is beneficial because it obeys the precise gas law, a simplified equation of country, and is amenable to evaluation under statistical mechanics.

An ideal gas is described as one for which both the extent of molecules and forces between the molecules are so small that they have got no effect at the behavior of the gas. The real gas that acts almost like a really perfect gasoline is helium. that is due to the fact helium, in contrast to maximum gases, exists as an unmarried atom, which makes the van der Waals dispersion forces as low as viable

Caculation:-

P1= 0.97 atm

V1= 2 L

T1= 298 K

P2= 1 atm

V2= ?

T2= 273 atm

V2 = 0.97 atm × 2 L × 273  /298 k

= 1.78 L

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A)The needed amount of phenacaine HCl is 0.6g and chlorobutanol is 0.3 g B) 40.8 ml is the required volume of 1.9% boric acid C) 0.7752 grams you do not have 1.9% boric acid solution and have to compound from boric acid powder

A)for calculating amount. of drug requieed Amount of phenacine Hcl SO = 1% w/v measure 19 in  100 ml

60/100×1g= 0.6 gm

Amount  of chlorobutanol = 0.5%  w/v  means 0.5g in 100 ml.

So 0.5g ⇒100ms

>> 60/100 ×0.5g = 0.39gm

b) so total volume

= Yol

At Vol. B

= 7.2ml + 12

= 19-2nd

So Volume Boric acid

= total volume of solution - volume of drug

= 60ml - 19.2ml

= 40.8gm

c) in this preparation. we need

40.8 ml = 0.4089 of Nac to =0.77529 grams boric acid powder to 40.8 ml

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Experiment is a scientific procedure carried out to test an idea or hypothesis. It provide insight about the cause and effect.

joseph decides to test the idea of his friend carl that heating certain compounds releases a strange new gas with interesting properties. he carefully weighs out a number of samples and puts them in sealed tubes, then heats them until they stop changing, then records the new weights. by subtracting the weights he is able to tell whether an invisible gas released during the Experiment. An experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into cause-and-effect by demonstrating what outcome occurs when a particular factor is manipulated.

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Formation of A In the preceding technique, 4-methylcyclopenhexa-3-enone (dienophile) reacts with a cyclic diene to create a bicyclic product with two rings fused. This reaction is known as the Diels-Alder reaction. This coordinated reaction can be represented as shown in the image attached.

Consequently, the procedure outlined above shows how the Diels-Alder reaction results in product A. As a result, A's structure is shown in the following way.

From A, change to B

Due to compound A's tricyclic fused ring with two six-membered rings, a carbon dioxide molecule is destroyed when it is heated, coupled with a decarboxylation electrocyclic pericyclic reaction.

On Earth, organic molecules make up every living thing. Molecules are made up of bonded atoms. All living things contain organic molecules, which are the majority of carbon-containing compounds.

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The anode and cathode, or the oxidation and reduction halves of the cell, always exchange electrons. The electrons will move from the more negative half reaction to the more positive half reaction in an Eocell of the half reactions.

The electrochemical series' lower-ranking metal will become the positive terminal. The positive ions in the electrolyte will receive the released electrons from the positive terminal. The negative terminal of a voltaic cell is called the anode, and the positive terminal is called the cathode.

Electrons in the wire and electrodes carry electrical current, although it is transported by opposingly moving anions and cations within the cell. Oxidation takes place at the anode because it can accept electrons.

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Nuclides below the valley of stability can become more stable through  positron emission.

A positron emission tomography (puppy) test is an imaging check which can assist reveal the metabolic or biochemical feature of your tissues and organs. The puppy test uses a radioactive drug (tracer) to reveal both ordinary and abnormal metabolic pastime.

A positron is the anti-particle of a beta particle, and is emitted with the aid of a proton-rich nucleus. The collision of an electron and a positron yields two 0.511 MeV gamma rays. Positron gamma radiation can penetrate via inches of iron, concrete, timber, plastic, water, and many others.

They're converted into two high-electricity gamma rays moving immediately faraway from every other.

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The true statement is d. Both gases have the same average kinetic energy. Since the gases are at the same temperature in this situation, they will have the same average kinetic energy.

The average kinetic energy of a gas is determined by the temperature of the gas. The molecular speed of a gas is determined by the temperature of the gas and the mass of the gas molecules. Helium and neon have different atomic weights, so their molecular speeds will be different at the same temperature. The density of a gas is determined by the number of molecules and the volume they occupy. If the number of molecules of each gas is equal, but the atomic weights of the gases are different, then the density of the mixture will be different from the densities of the individual gases.

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The following cases would recrystallization be favored over extraction when purifying a mixture of two solid compounds is  II. Option B.

A compound is a substance in which two or more different chemical elements are combined in a certain ratio. When elements come together, they react with each other to form unbreakable chemical bonds.

The definition of recrystallization is a compound purification technique in which a compound is dissolved in a solvent and slowly cooled to form crystals that represent a purer form of the compound. Scientists use recrystallization to purify solids usually products from various chemical reactions in a compound are dissolved.

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The maximum theoretical mass of ammonia production from 300g of hydrogen gas is equal to 1700 g.

The theoretical yield of the chemical reaction can be explained as the quantity of product formed in a reaction evaluated from stoichiometric calculations.

Given the reaction of the formation of ammonia from hydrogen gas:

3H₂ (s) + N₂  (g) →  2NH₃ (g)

The molecular mass of the ammonia =  17 g/mol

Given the mass of the hydrogen gas = 300 g

The number of moles of the hydrogen gas = 300/2 = 150 mol

From the above equation, 2 moles of ammonia are produced from 3 moles of hydrogen gas.

150 mol of hydrogen gas will produce ammonia = (2/3) ×150 = 100mol

The mass of ammonia is produced = 100 × 17 = 1700 g

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Both Peptide 1 and Peptide 2 are effective as toxin concentration in the graft is minimum. So, Peptide 1 is an effective inhibitor of the pathway, and peptide 2 is an effective inhibitor of the TRAP pathway in human infection.

Along the same lines, peptide 2 is an effective inhibitor of the TRAP pathway in human infection, but  Peptide 1 is NOT an effective inhibitor of the AGR pathway in human infection. Similarly: Peptide 1 is an effective inhibitor of the AGR pathway, however, peptide 2 is NOT an effective inhibitor of the TRAP pathway in human infection. A peptide is a short chain of amino acids (commonly 2 to 50) connected by substance bonds (called peptide bonds). A more extended chain of connected amino acids (at least 51) is a polypeptide. The proteins fabricated inside cells are produced using at least one polypeptide.

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Answer: B

Explanation: 2 isotopes of boron are present.

Let percent abundance of B-10 is x

percent abundance of B-11 is (100-x)

Average atomic mass,      

 [tex]10.80=\frac{x*10+(100-x)*11}{100}[/tex]

        [tex]10.80=\frac{10x+1100-11x}{100}[/tex]

        [tex]1080=1100-x[/tex]

        [tex]x=20[/tex]

The amount of heat released from the system as the pentane cools is 67.5kJ.

To determine the heat released from the system as the pentane cools, we need to consider the heat absorbed or released during each of the phase changes (vaporization and fusion) as well as the heat absorbed or released during the temperature change of the substance in each phase.

The heat absorbed or released during a phase change can be calculated using the enthalpy of vaporization (AHvap) or enthalpy of fusion (AHfus) and the number of moles of substance undergoing the phase change.

The heat absorbed or released during a temperature change can be calculated using the specific heat of the substance and the number of moles of substance and the temperature change.

In this case, we can first calculate the heat absorbed or released during the vaporization of the pentane:

Heat = ΔHvap * moles

Heat = 45.3 kJ/mol * 144.29 g / (58.12 g/mol) = 102.1 kJ

Next, we can calculate the heat absorbed or released during the cooling of the pentane vapor to the melting point:

Heat = specific heat * moles * temperature change

Heat = 168 J/mol K * 144.29 g / (58.12 g/mol) * (117 - (-84)) K = 68400 J = 68.4 kJ

Then, we can calculate the heat absorbed or released during the fusion of the pentane:

Heat = ΔHfus * moles

Heat = 120 kJ/mol * 144.29 g / (58.12 g/mol) = 270 kJ

Finally, we can calculate the heat absorbed or released during the cooling of the pentane from the melting point to the final temperature:

Heat = specific heat * moles * temperature change

Heat = 168 J/mol K * 144.29 g / (58.12 g/mol) * (-84 - (-84)) K = 0 J

The total heat released from the system can be calculated by adding up the heat absorbed or released during each of these processes:

Total heat = 102.1 kJ + 68.4 kJ + 270 kJ + 0 kJ = 440.5 kJ

The correct answer is therefore D) 67.5 kJ.

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The Balanced Eqn is 2CO+O2→2CO2.

A chemical reaction is a method wherein one or more materials, also called reactants, are transformed into at least one or more special substances, called merchandise. Materials are both chemical elements or compounds.

A few synthesis reactions can result in more than one product. Photosynthesis is one of the maximum important chemical reactions on earth. It allows plants and a few microbes to transform water and carbon dioxide gas into storable sugar and oxygen.

Chemical compounds are made from atoms of different elements, joined collectively through chemical bonds. A chemical synthesis normally involves the breaking of existing bonds and the formation of recent ones.

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​

The thing that the curves tell us about the distribution of dark matter in these galaxies is option B: Most of the dark matter is in the galaxies’ outskirts.

Beyond the visible borders of galaxies, the velocity of stars remains relatively constant, suggesting that there must be more matter present than what we can see as stars and gas.

When the impact of DE became noticeable, the rotation curves are shown to dip at a specific distance. r. These flat, v = constant, rotation curve data suggest that the amount of dark matter is increasing linearly with r up to great distances from the spiral galaxies' centers.

From the graph you can see they all pointing or going one direction, hence we can deduce that it is option B.

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 44.98 grams of al(s) are needed to produce 154.6 g of al2o3 .

4 Al(s) + 3 O₂(g) → 2 Al₂O₃(s)

mass obtained of an  Al₂O₃ (experimental yield) is 154..6 g.

Theoretical yield of an  Al₂O₃ is x g.

Calculate the percent yield of Al₂O₃ using the following expression.

%yield = (experimental yield / theoretical yield) × 100%

(154..6 / x) × 100% = 87.8%

theoretical yield= 176.08

molar mass of Al₂O₃ is 101.96 g/mol

mass of Al = 26.98 u*176.08/101.96= 44.98g

A bond's yield is a number that represents the return on investment. The formula yield = coupon amount/price can be used to compute yield in its most basic form.

Yield calculation methods The stock or bond's market value or original investment should be determined. Identify the profit the investment produced. Subtract the income from the market value. Add 100 to this amount.

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From the given graph plotting the rate of photosynthesis versus the temperature, the rate of oxygen production is greatest at the point M.

Photosynthesis is the biochemical process of synthesising chemical energy by green plants  with the aid of light energy. The photosynthetic reaction involves the combination of carbon dioxide and water producing oxygen gas and glucose.

The chemical energy is stored in plants in the form of glucose which is then break down by the need of energy forming ATP.  The photosynthetic reaction is affected by the temperature and pressure of the atmosphere.

From the graph, it is clear that, the rate of photosynthesis is higher at the point M. Higher the rate of photosynthesis, higher will be the oxygen production. Hence, option B is correct.

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The nitrogen monoxide produced by the combustion in the automobile engine. the grams of the oxygen gas are used to form the 0.154 moles of the nitrogen dioxide is 2.46 g.

The reaction is given below :

2NO  +  O₂  --->  2NO₂

2 moles of the NO₂ produce by the 1 moles of O₂

moles of the  of NO₂ = 0.154 mol

moles of the  O₂ = (1/2) × 0.154

                            = 0.077 mol

molar mass of  O₂ = 32 g/mol

mass of  O₂ = moles × molar mass

                    = 0.077 × 32

                    = 2.46 g

The mass of oxygen gas needed to form the nitrogen dioxide is 2.46 g.

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