Sodium bicarbonate has a 250 mg/ml concentration in the stock solution.
How is a concentrated stock solution created?The right amount of a pure solid or pure liquid must be measured out, weighed, and placed in the appropriate flask before being diluted to the required volume to create a stock solution. The reagent can be measured using a variety of techniques depending on the required concentration unit.
C1V1 = C2V2
We are given that:
V1 = 3 L
V2 = 5 L
C2 = 150 mg/ml
C1(3 L) = (150 mg/ml)(5 L)
Simplifying, we get:
C1 = (150 mg/ml)(5 L) / (3 L)
C1 = 250 mg/ml
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What is the daughter nucleus (nuclide) produced when Pb211 undergoes beta decay by emitting an electron
the daughter nucleus (nuclide) produced when Pb-211 undergoes beta decay by emitting an electron is Bi-211.
When Pb-211 undergoes beta decay, it transforms into a new nuclide by emitting an electron. Beta decay occurs when a neutron in the nucleus of an atom is transformed into a proton, and an electron (known as a beta particle) is emitted from the nucleus.
In this case, Pb-211 decays into Bi-211 through beta-minus decay. Beta-minus decay occurs when a neutron in the nucleus is converted into a proton, and an electron (beta particle) and an antineutrino are emitted. The process can be represented as follows:
Pb-211 → Bi-211 + e- + ν
In this equation, Pb-211 represents the parent nuclide, Bi-211 is the daughter nuclide, e- is the beta particle (electron) emitted during the decay, and ν is an antineutrino.
what is beta particle?
A beta particle, also known as a beta particle or beta radiation, is a high-energy, high-speed electron or positron that is emitted from the nucleus of an atom during radioactive decay.
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What ion is crucial to skeletal muscle fiber contraction?A) Cl-B) K+C) Ca2+D) Na+E) H+
The ion crucial to skeletal muscle fiber contraction is C) Ca2+ (calcium ions). Calcium ions play a key role in initiating the sliding filament mechanism, which leads to muscle contraction in skeletal muscle fibers.
The distance between an atom's nucleus and its last electron in its outermost shell is known as the ionic radius. An atom's ionic radius falls when it loses an electron (becomes a cation), but it increases when it gets an electron (becomes an anion).
As we well know, chemical synapsis is the form of synapsis that causes muscular contractions; therefore, when calcium enters, a neurotransmitter is released that stimulates the neighbouring cell, and sodium enters.
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Question 22 Marks: 1 Methane in the presence of air is explosive at concentrations betweenChoose one answer. a. 5 and 15 percent b. 3 and 5 percent c. 20 and 25 percent d. 50 and 60 percent
Methane in the presence of air is explosive at concentrations between 5 and 15 percent. So the correct answer is a. 5 and 15 percent.
Methane is a flammable gas that can form explosive mixtures with air when its concentration falls within certain ranges. The Lower Explosive Limit (LEL) is the minimum concentration of methane in air below which it is too lean to burn, and the Upper Explosive Limit (UEL) is the maximum concentration of methane in air above which it is too rich to burn. The explosive range for methane is typically considered to be between 5 and 15 percent by volume in air. This means that if the concentration of methane in air falls within this range, there is a risk of an explosive atmosphere being formed. It is important to take appropriate precautions and follow safety guidelines when working with or around methane or any other flammable gas to prevent accidents and ensure safe operations.
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Gases & KMT 1:Question 7
The particles of two different gases at 0°C will have
Select one:
Oan average kinetic energy that depends on the
amount of the gas
O the same average kinetic energy
Ono kinetic energy
O different average kinetic energies
The particles of two different gases at 0°C will have on an averave kinetic energy that vbdepends on the amount of the gas.
At 0°C, the particles of two different gases will have different kinetic energies and velocities due to their different masses and molecular structures.
According to the kinetic theory of gases, the average kinetic energy of a gas is proportional to its temperature, and the average kinetic energy of the particles in a gas is directly proportional to their mass and the square of their velocity.
Therefore, at the same temperature of 0°C, the lighter gas particles will have higher average velocities and kinetic energies than the heavier gas particles. This is because the lighter gas particles have less mass and can move more quickly, while the heavier gas particles have more mass and move more slowly.
Where do the majority (98%) of rare earth minerals come from in the world?
The majority (98%) of rare earth minerals come from China, which has a virtual monopoly on the production and export of these valuable minerals. However, other countries such as Australia, Russia, and the United States also have significant reserves of rare earth minerals.
China has a significant market share in the global production of rare earth minerals, which are a group of 17 elements that are crucial in the manufacturing of various high-tech products, including electronics, magnets, and batteries. China's dominance in rare earth production is due to a combination of factors, including its abundant rare earth deposits, relatively low labor and production costs, and government policies that support and protect its rare earth industry,
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How do you change the aldol condensation to form a benzalacetone?
To change the aldol condensation to form a benzalacetone, you need to perform a dehydration reaction.
This can be done by heating the aldol product, which is a beta-hydroxy ketone, in the presence of an acid catalyst such as sulfuric acid. The acid catalyst will protonate the hydroxyl group, making it a better leaving group. The beta-hydroxy ketone will then lose a molecule of water, forming a double bond between the alpha and beta carbons. This results in the formation of the desired product, benzalacetone. The mechanism of this reaction involves the formation of an enolate intermediate, which is stabilized by the aromatic ring of the benzaldehyde.
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Question 32
Prior to 2008, there have been no new nuclear reactors ordered by US utility companies in the US since:
a. 1976
b. 1978
c. 1980
d. 1982
There have been no new nuclear reactors ordered by US utility companies in the US since 1976.The correct answer is option A.
This is a significant fact, considering that nuclear energy was once seen as the solution to the world's energy problems due to its low carbon emissions and high energy density. However, the nuclear disaster at Three Mile Island in 1979 and the Chornobyl disaster in 1986 changed the perception of nuclear power, making it less popular among the public.
Moreover, the cost of building and maintaining nuclear power plants is incredibly high, and the risk of accidents is always present. These factors, combined with the increasing availability and decreasing cost of renewable energy sources, have led many utility companies to focus on renewable energy instead of nuclear power.
However, in recent years, there has been renewed interest in nuclear energy as a potential solution to climate change. Many new nuclear reactor designs have been proposed that claim be safer and more efficient than traditional designs. Still, the high cost of building nuclear power plants remains a significant barrier to widespread adoption. Therefore, it is uncertain whether nuclear power will play a significant role in meeting future energy demands or not. The correct answer is option A.
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Question 11 Marks: 1 To raise the pH, addChoose one answer. a. chlorine b. muriatic acid c. sodium carbonate d. sulfuric acid
To raise the pH, sodium carbonate (Na2CO3) can be added. Sodium carbonate is a basic compound that can neutralize acid and raise the pH of the solution.
When sodium carbonate is added to water, it dissociates into sodium ions (Na+) and carbonate ions (CO32-). The carbonate ions react with the hydrogen ions (H+) in the water to form bicarbonate ions (HCO3-), which reduces the acidity of the solution and raises the pH.
On the other hand, adding muriatic acid (hydrochloric acid) or sulfuric acid to water would have the opposite effect and lower the pH. Chlorine is not used to raise pH, but rather as a disinfectant to kill microorganisms in water.
It is important to note that when adding sodium carbonate to water to raise the pH, the amount added should be carefully controlled to avoid over-treating the water, which can lead to scaling, cloudiness, or other water quality issues. pH testing should be regularly conducted to ensure that the desired pH level is achieved and maintained.
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Hyperpolarization, or the undershoot phase, occurs after an action potential because some ______ channels remain ________.A) Na+; openB) Na+ and K+; openC) K+; closedD) K+; openE) Na+; closed
Hyperpolarization, or the undershoot phase, occurs after an action potential because some K+ channels remain open.
This allows more potassium ions to exit the cell, making the inside of the cell more negative than the resting potential, resulting in hyperpolarization.
It exists in the body as a particle physiologically. The electrolyte potassium(K+), a cation, is present throughout the body in both intracellular and extracellular liquids. It has a distinct charge. Over 90% of the body's potassium is found inside cells. the undershoot phase, occurs after an action potential because some K+ channels remain open.
This allows more potassium ions to exit the cell, making the inside of the cell more negative than the resting potential, resulting in hyperpolarization.
Typically, your cells contain 98% of the potassium in your body. You have 80% of this in your muscle cells, while the remaining 20% is in your bones, liver, and red blood cells (6). When ingested, it functions as an electrolyte.
This gap causes a massive convergence of sodium ions that are strongly charged to enter the cell, producing an activity potential. To maintain the resting film potential, chloride particles are periodically syphoned back over the cell surface.
A neuron is a phone that transmits electrical motivations. It is sometimes referred to as a nerve cell or a neurone. The fundamental (auxiliary and utilitarian) components of our sensory system are neurons. Axons, dendrites, and the phone body (also known as the soma or cyton) make up each neuron. Nerve fibres include dendrites and axons.
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Write a 200 word summary paragraph discussing this experiment and the results. Use the following questions and topics to help guide the content of your paragraph.
What happened to the cabbage indicator when breath was bubbled into the water? Why?
What happened to the cabbage indicator in the club or clear soda? Why?
Explain the connection between your observations and data and the pH of the oceans.
Give at least one example from real life where the principles demonstrated in this lab are evident.
The word summary paragraph discussing this experiment and the results are given below
In the experiment, a vegetable indicator was used to test the pH levels of various liquids. When break was bubbled into the water, the vegetable indicator curve from a purple color to yellow-green, displaying that the pH level had become more sour.
Cabbage indicator turned red in acidic club soda due to carbonic acid formation from dissolved carbon dioxide.
This lab shows the connection between pH and that of carbon dioxide levels in the air/water. More carbon dioxide in the air can lead to greater absorption in the ocean, leading to ocean acidification and lower pH.
An example of the principles shown in this lab is the effect of carbon emissions on ocean acidification. Lab shows how carbon emissions impact ocean acidification as more CO2 is absorbed causing pH levels to decrease. This harms marine life by disrupting shell formation and reducing food availability.
What is the summary?The above occurred cause carbon dioxide from the respite argue the water to form carbonic acid, that lowered the pH level. Within the clear refreshment, the cabbage sign turned pink, meaning a tall pH level, as these drinks hold carbonates and other shots for weaponry that raise the pH level.
The experiment shown in this put lab are clear in everyday growth, such as within the utilize of solvent base to neutralize richness stomach corrosive. The comes about of the test highlight the affect that human conduct can have on the environment and the have to be make tolerable determinations in our day by day lives.
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A carboxylic acid reacts with water to form a carboxylate ion and H3O+ . Complete the reaction.reaction:C6H5COOH+H2Oâ½ââWrite the IUPAC name of the carboxylate ion formed in the reaction.IUPAC name:
The carboxylate ion formed in the reaction is known as the acetate ion, with the chemical formula C₂H₃O₂-. Its IUPAC name is ethanoate.
What is chemical formula?A chemical formula is an expression that states the number and type of atoms present in a molecule of a substance. It consists of symbols representing elements in the periodic table, and subscripts to indicate the number of atoms of each element present in the molecule. For example, the chemical formula for water is H₂O, which indicates that there are two hydrogen atoms and one oxygen atom in each molecule of water. Chemical formulas are essential for understanding the chemical makeup of substances and the reactions they undergo.
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How many moles of H2O would be produced if 10.0 mol of iron hydroxide react completely?
10.0 moles of [tex]H_2O[/tex] would be produced if 10.0 mol of iron hydroxide reacts completely
To answer this question, we need to know the balanced chemical equation for the reaction in which iron hydroxide[tex](Fe(OH)_2)[/tex] is converted to water (H2O):
[tex]Fe(OH)_2[/tex] → [tex]FeO + H_2O[/tex]
From the equation, we can see that for every molecule of iron hydroxide that reacts, one molecule of water is produced.
Therefore, the number of moles of water produced will be equal to the number of moles of iron hydroxide used.
If 10.0 mol of iron hydroxide reacts completely, then 10.0 mol of water will be produced.
Therefore, the answer is 10.0 moles of Water.
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If ∆G is ____, reactants will convert to products. If ∆G is ____, products will convert to reactants.
Gibbs Free Energy (∆G) which helps predict the spontaneity of a reaction. If ∆G is negative, reactants will convert to products. If ∆G is positive, products will convert to reactants.
If ∆G (Gibbs free energy change) is negative (∆G < 0), reactants will spontaneously convert to products, indicating a thermodynamically favorable process. A negative ∆G indicates that the products have lower free energy than the reactants, and the reaction is spontaneous and exergonic.
If ∆G is positive (∆G > 0), products will not spontaneously convert to reactants, indicating a thermodynamically unfavorable process. A positive ∆G indicates that the products have higher free energy than the reactants, and the reaction is non-spontaneous and endergonic.
If ∆G is exactly zero (∆G = 0), the system is at equilibrium, and the reaction is in a state of dynamic balance where the forward and reverse reactions occur at equal rates, with no net change in the concentrations of reactants and products over time.
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5. A first-order reaction has a rate constant of 3.00 x 10-3 s-1. The time required for
the reaction to be 75% complete is:
A. 95.8 s B. 201 s C. 231 s D. 462 s E. 41.7 s
The time required for the reaction to be 75% complete is approximately 231 seconds, which is option C.
A first-order reaction follows the rate law:
rate = k[A], where k is the rate constant and [A] is the concentration of the reactant. The integrated rate law for a first-order reaction is given by:
ln([A]t/[A]0) = -kt
where [A]t is the concentration of the reactant at time t, [A]0 is the initial concentration, and k is the rate constant.
We are given that the rate constant is 3.00 x 10^-3 s^-1. We can use the integrated rate law to determine the time required for the reaction to be 75% complete.
Let [A]t/[A]0 = 0.25, since the reaction is 75% complete. Substituting this value and the given rate constant into the integrated rate law, we get:
ln(0.25) = -3.00 x 10^-3 t
Solving for t, we get:
t = -ln(0.25)/3.00 x 10^-3 ≈ 231 s.
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Convert 564 grams of copper to moles.
Answer:
5.64 of copper
Explanation:
Given: 564 grams of copper
To find: in copper
Solution: If 1 grams Copper = 0.01 mole,
Then, 564 grams = multiply 564 and 0.01 mole
564 × 0.01 = 5.64
Therefore, there are 5.64 of copper in 564 grams
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A ___________ pair of valence electrons that are not shared between atoms are called _________. (covalent, unshared pairs, shared, stable electron, single)
A pair of valence electrons that are not shared between atoms are called unshared pairs.
These unshared pairs are also sometimes referred to as lone pairs or non-bonding pairs. They are important in determining the shape and properties of molecules, as they can influence the molecule's polarity and reactivity. For example, in a water molecule, the two unshared pairs of electrons on the oxygen atom give it a bent shape and make it a polar molecule. In organic chemistry, unshared pairs on nitrogen, oxygen, and sulfur atoms can participate in various reactions such as nucleophilic substitution and acid-base reactions. Covalent bonds involve the sharing of electrons between atoms, but unshared pairs remain associated with a single atom and contribute to the stability of the electron arrangement in that atom.
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3.7. Which type of manufactured panel would be most appropriate to use for perimeter foundation wall insulation? A. Beadboard B. Fiberboard C. Flakeboard D. Hardboard
The most appropriate type of manufactured panel to use for perimeter foundation wall insulation is A. Beadboard.
Beadboard is made of expanded polystyrene or extruded polystyrene, which provides excellent insulation properties and is suitable for foundation wall insulation applications. Beadboard is a type of manufactured panel that is most appropriate to use for perimeter foundation wall insulation. It is installed on the outside of the foundation walls, and acts as a barrier to stop cold air from entering the home and to help keep the home warm. Beadboard is made of a durable material, such as PVC, that is resistant to moisture, which provides an additional layer of protection against moisture damage. Beadboard can also be painted to match the exterior of the home and is easy to install.
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what is the change in concentration (umol/ml/min) for nadph if the change in absolute absorbance per second from your dhfr functional assay analysis was 0.0035? group of answer choices 0.034 0.000034 0.56 0.00056
we need to use the Beer-Lambert law, which states that the change in absorbance is proportional to the concentration of the absorbing species and the path length of the sample.
The equation for the Beer-Lambert law is: A = εcl.
where A is the absorbance, ε is the molar absorptivity (a constant for a given absorbing species), c is the concentration, and l is the path length. We can rearrange this equation to solve for the concentration: c = A/(εl).
In this case, we are looking for the change in concentration of NADPH (c), given the change in absolute absorbance per second (A) from the DHFR functional assay analysis. We don't have the value of ε or l, but we can assume that they are constant throughout the experiment.
So, we can plug in the values we do have and solve for c: c = A/(εl) = 0.0035/(εl), We are not given the values of ε or l, but we don't need them to answer the question. We are looking for the change in concentration (Δc) of NADPH, so we can rewrite the equation as: Δc = ΔA/(εl), where ΔA is the change in absorbance per second. Plugging in the values we have: Δc = 0.0035/(εl).
We don't know the value of ε or l, but we can use the answer choices to eliminate some possibilities. We know that the change in concentration will be in units of micromoles per milliliter per minute (umol/ml/min). The only answer choice that has the correct units is: Δc = 0.000034 umol/ml/min.
Therefore, the change in concentration of NADPH is 0.000034 umol/ml/min if the change in absolute absorbance per second from the DHFR functional assay analysis was 0.0035.
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Question 54
Which one of the following areas of the United States would be most sensitive to acid precipaitation?
a. Rocky Mountain states
b. Southeast
c. New England
d. Great Plains
The area of the United States that would be most sensitive to acid precipitation is c. New England.
This is because the region has a higher susceptibility to acid rain due to its proximity to major industrial and urban areas that emit high levels of pollutants, as well as its naturally acidic soil and water systems. The acidity of precipitation increases as plants and trees take it up, making the forests of this region particularly susceptible. Additionally, the region's lakes and streams are especially sensitive to acidification, which can damage aquatic life and water quality. Acid precipitation is caused by industrial emissions and car exhaust, which are more concentrated in this region due to its high population density.
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Question 14
The most common problem associated with the disposal of hazardous waste is:
a. leaching from landfills and dumps
b. breeding ground for insects
c. groundwater contamination
d. unauthorized dumping
The most common problem associated with the disposal of hazardous waste is leaching from landfills and dumps.
This can lead to groundwater contamination and create a hazardous environment for both human and animal life. Additionally, hazardous waste sites can become breeding grounds for insects and other pests, exacerbating the problem. Unauthorized dumping can also contribute to the problem of hazardous waste disposal, as it can lead to contamination of the environment in unexpected areas.
The most common problem associated with the disposal of hazardous waste is:
c. groundwater contamination.
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Why do anticyclones make UHIs stronger?
Anticyclones are associated with high pressure and subsiding air, which leads to stable atmospheric conditions. This stability can lead to the accumulation of air pollutants, such as particulate matter and nitrogen oxides, within the urban area, resulting in a stronger urban heat island (UHI) effect.
In addition, the subsiding air in anticyclones can cause a reduction in wind speed, which can limit the mixing of air between urban and rural areas, further enhancing the UHI effect.
Finally, clear skies and sunshine associated with anticyclones can lead to more solar radiation being absorbed by urban surfaces, increasing their temperatures and contributing to the UHI effect.
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The space between the inner or protective casing and the outer casing or drill hole should be filled with cement grout to a minimum of how many feet?
a.) 10 feet
b.) 15 feet
c.) 20 feet
d.) 35 feet
The space between the inner or protective casing and the outer casing or drill hole should be filled with cement grout to a minimum of 20 feet. Therefore, the correct answer is c.) 20 feet.
Grouting is the process of adding a sealing substance, such as bentonite or plain cement, to the gap between a well casing and the borehole made during well construction.
The protection of public health and the quality of ground water can be achieved using grouting, which is both effective and essential. The DNRE has documented a number of instances where inadequate grouting or a lack of grouting in both consolidated and unconsolidated formations is suspected of being the cause of contaminants leaking into potable water aquifers along the well casing. Hence, The space between the inner or protective casing and the outer casing or drill hole should be filled with cement grout to a minimum of 20 feet. Therefore, the correct answer is c.) 20 feet.
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PLEASE ANSWER!!!!! 35 POINTS!!
How many moles of P2O3 are required to fully react with 108 H2O? (H2O; 18 g/mol)
P2O3 + 3H2O --> 2H3PO3
108 gH2O ---> mol P2O3
HOW WOULD YOU SOLVE FOR THIS PLEASE??!!
Pb(NO3)2 (aq) + 2 KBr (aq) --> PbBr2 (s) + 2 KNO3 (aq)
part 1: If this reaction starts with 32.5g lead (II) nitrate and 38.75g potassium bromide, how many grams of the precipitate will be produced? (use the limiting reactant to calculate the amount of precipitate formed)
By limiting reactant , 35.94 grams of precipitate will be created.
Enumerate the limiting reactant?The reactant that is entirely consumed in a chemical reaction is known as a limiting reactant. The volume of product that can be created is constrained.
In other terms, the reactant that is consumed first in a chemical reaction is the limiting reactant. The reaction ceases when it is consumed, and no more product can be produced.
Excess reactants are the additional reactant(s) that are not entirely utilized. After the reaction is finished, they remain
We must first draw out the balanced chemical equation in order to address this issue:
PbBr2 (s) + 2 KNO3 (aq) = Pb(NO3)² (aq) + 2 KBr (aq)
The mole ratio of each reactant and product is represented by the coefficients in the balanced equation, as can be seen.
We must determine the moles of each reactant in order to determine which one is the limiting reactant. By dividing the mass of each reactant by its molar mass, we can accomplish this:
Pb(NO3)² moles are equal to 32.5 g / 331.21 g/mol, or 0.098 moles.
The formula for KBr's moles is 38.75 g/119.01 g/mol, or 0.325 moles.
We can now identify the reactant that is limiting by using the mole ratio from the balanced equation:
2 moles KBr per mole of Pb(NO3)²
The limiting reactant is Pb(NO3)² since we have fewer moles of it than KBr.
The mole ratio of Pb(NO3)² to PbBr2 must be used to determine how much precipitate was produced:
Pb(NO3)² = 1 mole PbBr2
Therefore, we make 1 mole of PbBr2 for every reaction of 1 mole of Pb(NO3)².
PbBr2 has a molar mass of 367.01 g/mol. The mass of PbBr2 produced can therefore be calculated as follows:
Number of PbBr2 moles divided by molar mass gives the PbBr2 mass.
PbBr2 mass equals 0.098 moles times 367.01 g/mol.
PbBr2 has a mass of 35.94 g.
As a result, 35.94 grams of precipitate will be created.
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In an experiment, 1.201 g of charcoal reacts with 6.414 g of powdered sulfur. What is the mass of product?C(s) + 2 S(s) ® CS2(g)
The mass of product when 1.201 g of charcoal reacts with 6.414 g of powdered sulfur is 7.60 g.
To find the mass of product, we need to first calculate the limiting reactant. We do this by finding the number of moles of each reactant using their respective molar masses.
Molar mass of charcoal (C): 12.01 g/mol
Molar mass of sulfur (S): 32.06 g/mol
Number of moles of charcoal = 1.201 g / 12.01 g/mol = 0.0999 mol
Number of moles of sulfur = 6.414 g / 32.06 g/mol = 0.2002 mol
According to the balanced chemical equation, the reaction requires 1 mole of charcoal and 2 moles of sulfur to produce 1 mole of CS₂. Since there are not enough moles of charcoal to react with all the sulfur, charcoal is the limiting reactant.
The number of moles of CS₂ produced is equal to the number of moles of charcoal used (0.0999 mol). To find the mass of CS₂ produced, we use its molar mass:
Molar mass of CS₂: 76.14 g/mol
Mass of CS₂ produced = number of moles of CS₂ x molar mass of CS₂
Mass of CS₂ produced = 0.0999 mol x 76.14 g/mol = 7.60 g
Therefore, the mass of CS₂ produced is 7.60 g.
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#24. What additional substance is necessary for reaction 2 to take place?A. FADB. NADHC. H2OD. Acetyl-CoA
The additional substance necessary for reaction 2 to take place is B. NADH.
Reaction 2 refers to the second step of cellular respiration, which is the Krebs cycle (also known as the citric acid cycle or the TCA cycle). This cycle is a crucial part of the process that generates energy in the form of ATP (adenosine triphosphate) within the cell.
During the Krebs cycle, Acetyl-CoA, a product of the previous stage (glycolysis), is further broken down to produce [tex]CO_{2}[/tex], NADH, FAD[tex]H_{2}[/tex], and ATP. NADH is essential for reaction 2 because it serves as an electron carrier, transferring electrons from the Krebs cycle to the electron transport chain in the next stage (oxidative phosphorylation).
This transfer of electrons allows for the production of ATP, which is the main energy source for the cell. In summary, NADH is the additional substance necessary for reaction 2 (Krebs cycle) to take place, as it plays a vital role in transferring electrons and ultimately generating ATP to fuel the cell's activities. The correct answer is b.
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1 A is an alcohol that has the following percentage composition by mass: carbon 60.0%, hydrogen 13.3% and oxygen 26.7%.
[Ar values: C = 12.0, H = 1.0, O = 16.0]
a i Calculate the empirical formula of A. [2]
ii The molecular mass of A is 60. Calculate its molecular formula. [1]
b Give the structural formulae of the isomers of A. [2]
c If A is heated with a mixture of sulfuric acid and potassium dichromate(VI), there is
a colour change and propan2one is formed. Identify A and explain your answer. [2]
d Give the structural formulae for the organic products from the reaction of A with the following reagents:
i heated pumice or concentrated sulfuric acid [1]
ii ethanoic acid in the presence of an acid catalyst. [1]
2 B and C are isomeric alcohols with the molecular formula C4H10O.
a Draw the four skeletal formulae for the isomeric alcohols with this molecular formula. [4]
b When B is heated with a mixture of sulfuric acid and potassium dichromate(VI), there
is no change in colour.
i Identify B and explain your answer. [2]
ii Give the name, and the structural and skeletal formulae, of the alkene formed
when B is dehydrated. [3]
c When C is passed over heated pumice, it gives the same alkene as B does.
i Give the structural formula and name of C. [2]
ii What is formed when C is refluxed with an excess of acidified potassium
dichromate(VI) mixture? [1]
iii Explain the term reflux. [1]
3 D has the following percentage composition by mass: 53.3% carbon, 11.1% hydrogen and 35.6% oxygen.
[Ar values: C = 12.0, H = 1.0, O = 16.0]
a i Calculate the empirical formula of D. [2] ii The relative molecular mass of D is 90. What is its molecular formula?
Show your working.
b D is a diol. What does the term diol mean?
[2] [1]
An organic thiol compound is 38.66% C, 9.73% H, and 51.61% S by mass. What is theempirical formula of this compound?A) C2H6S B) C3H8S C) C4H10S D) C4H12S E) C5H14S
C: Percentage of atomic mass ≈ 3.22 mol and the mole ratio ≈ 2
H: Percentage of atomic mass ≈ 9.66 mol and mole ratio ≈ 6
S: Percentage of atomic mass ≈ 1.61 mol and mole ratio ≈ 1
The empirical formula is therefore C2H6S, which corresponds to option A.
To find the empirical formula of the organic thiol compound, we need to determine the simplest whole-number ratio of atomic mass present in the compound. We can assume a 100g sample of the compound, which means we have:
38.66g C
9.73g H
51.61g S
Next, we need to convert these masses to moles by dividing them by their respective molar masses:
38.66g C / 12.01 g/mol = 3.219 mol C
9.73g H / 1.01 g/mol = 9.633 mol H
51.61g S / 32.06 g/mol = 1.608 mol S
We then divide each of these mole values by the smallest value (in this case, 1.608 mol S) to get the mole ratio of the elements:
C: 3.219 mol / 1.608 mol = 2.00
H: 9.633 mol / 1.608 mol = 5.99 (approx. 6)
S: 1.608 mol / 1.608 mol = 1.00
Now we need to express this ratio in whole numbers by dividing each value by the smallest value (in this case, 1.00):
C: 2.00 / 1.00 = 2
H: 6 / 1.00 = 6
S: 1.00 / 1.00 = 1
Therefore, the empirical formula of the organic thiol compound is C2H6S, which corresponds to answer choice A.
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Who was credited with developing the concept of the atomic number?
(A) Dimitri Mendeleev
(B) Lothar Meyer
(C) Ernest Rutherford
(D) Henry Moseley
(E) Michael Faraday
The answer is (D) Henry Moseley. He conducted X-ray experiments on various elements and determined that each element had a unique number of protons in its nucleus, which he called the atomic number.
The atomic number or nuclear charge number of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number or the number of protons found in the nucleus of every atom of that element. The atomic number can be used to uniquely identify ordinary chemical elements.
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List the 3 steps (in sequence) that you would have to carry out if dibenzalacetone separates as an oil.
If dibenzalacetone separates as an oil, you can follow this sequence of 3 steps to recover it: Cooling; Filtration; Washing and drying.
1. Cooling: First, cool down the reaction mixture to promote the solidification of the dibenzalacetone oil. This can be done by placing the container in an ice bath or allowing it to reach room temperature.
2. Filtration: Next, use a vacuum filtration setup to separate the solid dibenzalacetone from the liquid solution. Place a filter paper on a Buchner funnel, and apply a vacuum to draw the liquid through the filter, leaving the solid dibenzalacetone on the filter paper.
3. Washing and drying: Finally, wash the solid dibenzalacetone with a suitable solvent, such as cold ethanol or hexane, to remove any impurities. Then, allow the washed dibenzalacetone to air dry on the filter paper, or use a gentle stream of air to speed up the drying process.
By following these steps in sequence, you can successfully recover dibenzalacetone if it separates as an oil.
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