The absorption of infrared (IR) radiation results in vibrations in the molecules or ions that make up a chemical sample. Vibrations cause bond lengths or angles to expand and contract. The energy of infrared radiation (i.e., frequency) required for a vibration depends on the type of bond and the mass of the atoms involved. Typically, the higher the bond order, the stronger the bond, and therefore, the more energy (i.e., higher frequency) required to make the bond vibrate. Also, lighter atoms vibrate at higher frequencies than heavier atoms. The order of vibrational frequencies (from largest to smallest) of the given carbon-nitrogen and carbon-sulfur bonds is

Answers

Answer 1

Answer:

the order of vibrational frequency is:

C ≡ N > C=N > C=S > S-C

Explanation:

The bond's vibration frequency is determined using the following equation:

[tex]\zeta = \dfrac{1}{2 \pi c}\sqrt{\dfrac{k}{\mu}}[/tex]

where;

reduced mass[tex]\mu = \dfrac{m_1m_2}{m_1+m_2}[/tex]

velcoity of light = c

force constant = k

The frequency of vibration, on the other hand, is inversely proportional to the atom's mass, because the heavier the atom, the lower the frequency.

In addition, the value of a bond's stretching frequency rises as the bond's intensity rises. As a result, the frequency is as follows:

triple > double > single

The reduced mass [tex](\mu)[/tex] of C-N bond.

[tex]\mu = \dfrac{m_1m_2}{m_1+m_2}[/tex]

[tex]\mu = \dfrac{12*14}{12+14} \\ \\ \mu = 6.46[/tex]

The reduced mass of C-S bond;

[tex]\mu = \dfrac{m_1m_2}{m_1+m_2}[/tex]

[tex]\mu = \dfrac{12\times 32}{12+32} \\ \\ \mu = 8.72[/tex]

Thus, the order of vibrational frequency is:

C ≡ N > C=N > C=S > S-C


Related Questions

A sample of polonium-210 has an initial mass of 390 milligrams (mg). If the half-life of polonium-210 is 36 days, how many mg of the sample remains after 72 days?

A.
392 mg

B.
195 mg

C.
97.5 mg

D.
48.75 mg

Answers

Answer: D. 48.75

Explanation: just took the test

Answer:

D

Explanation:

I got this question right on my test.

ii) Sodium thiosulphate dissolves in dilute nitric acid at a steady rate. Copy out which
of the following changes would quicken up the reaction- 3
a. Cooling the reacting vessel to drop the temperature.
b. Breaking the reactants into smaller pieces.
c. Adding more concentrated acid.
d. Using more sodium thiosulphate.

Answers

Answer:

d

Explanation:

       

You tested the rocket with three mixtures of fuel having different masses of oxygen
and hydrogen. What is the relationship between the masses of oxygen and hydrogen in
each of the tests?

Answers

Answer:

As the oxygen is only transferred from the copper oxide to form water inside the apparatus, any gain in mass is due to hydrogen combined with the oxygen to form water. The ratio of the two masses enables the mass of oxygen combining with 1 g of hydrogen to be calculated.

Hydrogen and oxygen are the elements used as fuels in rockets as they are propellants. In each of the tests, the ratio of the mass of hydrogen to oxygen is 1:8.

What is the combustion of rocket fuel?

Combustion has been the chemical reaction that involves reactants combining and reacting with oxygen resulting in heat and light formation. They are majorly used in propelling engines and in rocket fuels.

In a rocket engine oxygen acts as the oxidizer that reacts with hydrogen atoms to derive the heat and energy so that the engine can move and produce thrust. It uses Newton's third law to create energy and accelerate upwards.

The mixtures of fuel contain various masses that are present in a ratio of 1:8 (hydrogen: oxygen) as masses of hydrogen are 1, 2, and 5 mg, whereas oxygen is 8, 16, and 40 mg. It can be concluded that 1 part of hydrogen reacts with 8 parts of oxygen in the rocket fuel mixture.

Therefore, the rocket fuel mixtures contain a 1:8 ratio of the masses of hydrogen: oxygen that undergoes combustion reaction.

Learn more about combustion, here:

https://brainly.com/question/14335621

#SPJ2

How does nitrogen in the atmosphere become beneficial to plants and eventually animals?
O Nitrogen must be mixed in the soil by earthworms,
O Nitrogen must be converted into a useful form by bacteria,
O Nitrogen must come in contact with decaying organic material,
O Nitrogen must come in contact with the ground through rainfall

Answers

Answer:

O Nitrogen must be converted into a useful form by bacteria.

This bacteria is called the nitrogen fixing bacteria such as the Rhizobium bacteria.

Name the part in red:
H2 + O2 -> H2O

Answers

Answer:subscript

Explanation:

Select the correct answer.
What quantity might be measured in units of kilograms?

A.
the brightness of a candle
B.
the volume of a bottle
C.
the mass of a marble
D.
the electric current in a wire

Answers

Answer:

The mass of a marble.

Explanation:

Units of the other answers:

A: Light - Lumen (lm)

B: Volume - cm^3

D: Electric current - Ampere

What is the empirical formula for a compound if a 2.50g sample contains 0.900g of calcium and 1.60g
of chlorine? (3pts]

Answers

Answer:

CaCl₂

Explanation:

First we convert the given masses of elements into moles, using their respective molar masses:

0.900 g Ca ÷ 40 g/mol = 0.0225 mol Ca1.60 g Cl ÷ 35.45 g/mol = 0.045 mol Cl

Now we divide those numbers of moles by the lowest value among them:

0.0225 mol Ca / 0.0225 mol = 10.045 mol Cl / 0.0225 mol = 2

Meaning the empirical formula for the compound is CaCl₂.

At a pressure of 1 atm, the temperature 115.9 K is called the fill in the blank 1 of Kr . The normal boiling point for Kr is at K The triple point pressure for Kr is atm The critical pressure for Kr is 54.3 atm. At temperatures above 209.4 K and pressures above 54.3 atm, Kr is a _________ . Kr is a _________ at 50.3 atm and 105 K. Kr is a _________ at 0.720 atm and 131 K. Kr is a _________ at 1.00 atm and 118 K.

Answers

Answer:

melting point, 119.8 K, 0.72 atm, supercritical fluid, solid, gas, liquid.

Explanation:

Let's refer to the phase diagram (not to scale) for krypton.

At a pressure of 1 atm, the temperature 115.9 K is called the melting point of Kr, and it is the temperature at which it passes from solid to liquid.

The normal boiling point for Kr is at 119.8 K, which is, at 1 atm, the limit between the liquid and the gas state.

The triple point pressure for Kr is 0.72 atm, as can be seen in point C.

The critical pressure for Kr is 54.3 atm.

At temperatures above 209.4 K and pressures above 54.3 atm, Kr is a supercritical fluid, according to the region it is in the phase diagram.

Kr is a solid at 50.3 atm and 105 K, according to the region it is in the phase diagram.

Kr is a gas at 0.720 atm and 131 K, according to the region it is in the phase diagram.

Kr is a liquid at 1.00 atm and 118 K, according to the region it is in the phase diagram.

A___
is a
small, rocky object
that orbits the sun
and has broken
off from a comet
or asteroid.
(Fill in the blank)

Answers

meteoroid i’m pretty sure

Answer:

I think it is a rock...

Explanation:

maybe idrk tho

Approximately what percent of the landmass on earth receives
very little or no rainfall?

Answers

Answer:

the desert (33% of the worlds surface)

Explanation:

Most of the world's surface is covered in water, in the form of oceans. The remaining landmass of Earth amounts to approximately 29 per cent of the surface. Of this remaining 29 per cent, deserts of all types constitute an estimated 33 per cent, or one-third, of the Earth's total landmass.

What is the percentage of water to land on Earth?

In simplest terms, water makes up about 71% of the Earth's surface, while the other 29% consists of continents and islands.

Which percentage of the total area of the earth is covered by soil?

Only about 7.5% of the Earth's surface provides the agricultural soil on which we depend for the world's food supply and this fragment competes, sometimes unsuccessfully, with all other needs: housing, cities, schools, hospitals, shopping centres, landfills, etc.

Learn more about the percentage of water to land on Earth here:  https://brainly.com/question/21459960

#SPJ2

what is the chemical equation for aq nitrate ion reacts with s arsenic trihydride and produces s arsenic and g ammonia?

Answers

Answer:

Explanation:

I need the correct answers

Answers

Answer:

Acids: Tastes Sour

Has a ph less than 7

Base: Bitter

Has a ph greater than 7

slippery

Acid&Base: Conducts electricity

Acid
Tastes sour
Has a ph less than 7




Bases
Tastes bitter
Has a ph more than 7
Feels slippery


Acids and bases
Conducts electricity

When elemental sodium reacts with water, sodium hydroxide and hydrogen will form. What mass of sodium (in grams) must be reacted with excess water to produce 325 mL of hydrogen gas at 25.0oC and 1.15 atm?

Answers

Answer:

0.703g Na must reacted

Explanation:

The reaction of Sodium, Na, With water, H₂O is:

2Na(s) + 2H₂O(l) → 2NaOH(aq) + H₂(g)

Where 2 moles of sodium reacts with an excess of water to produce 1 mole of hydrogen

To solve this question we have to use PV = nTR to solve the moles of the gas. With the moles of hydrogen we can find the moles of sodium that reacted and its mass:

Moles H₂:

PV = nRT

PV /RT = n

Where P is pressure = 1.15atm

V is volume in liters = 0.325L

R is gas constant = 0.082atmL/molK

T is absolute temperature = 25°C + 273 = 298.0K

1.15atm*0.325L / 0.082atmL/molK*298.0K = n

0.0153 moles of hydrogen are produced

Moles Na:

0.0153 moles H₂ * (2moles Na / 1mol H₂) = 0.0306 moles Na

Mass Na -Molar mass: 22.99g/mol-:

0.0306 moles Na * (22.99g / mol) =

0.703g Na must reacted

Which of the following is a characteristic shared by all living things?
A. They have tissues and organs,
B. They take in oxygen.
C. They make more individuals of the same kind.
D. They move.​

Answers

Answer; it’s either d or a. If it was be I would pick A. Not sure

The half-life for a 400-gram sample of radioactive element X is 3 days. How much of element X remains after 15 days have passed?

A.
12.5 g

B.
25 g

C.
50 g

D.
100 g

Answers

Answer:

The correct answer is - A. 12.5 gram.

Explanation:

Given:

The initial amount of sample = 400 gram

the half-life cycle = 3 days

after 15 days remain value = ?

Solution:

The number of half-lives in 15 days = 15/3

= 5 half-lives

the remaining amount of sample after one half-life 3 days = 400/2 = 200

the remaining amount of sample after 2nd half-life or 6 days= 200/2 = 100

the remaining amount of sample after 3rd half-life or 9 days= 100/2 = 50

the remaining amount of sample after 4th half-life or 12 days= 50/2 = 25

the remaining amount of sample after 5th half-life or 15 days= 25/2 = 12.5 gram

Thus, the correct answer is = 12.5 g.

Which statement best explains the genetic variation that results from sexual
reproduction?
A. Each chromosome contains many different genes.
B. Offspring receive a mix of genes from two different parents.
c. Offspring receive genes that are exactly the same as one parent's
genes.
O D. Each chromosome contains many copies of the same gene.

Answers

Answer:

Each chromosome contains many copies of the same gene

Answer:

Offspring receive a mix of genes from two different parents

Good luck!

In a reaction, the actual yield is always at least as large as the theoretical yield.

True or false.
give short explanation on answer

Answers

False

Actual yield in a reaction is almost always less than the theoretical yield, primarily because losses of the substances involved may occur anywhere in an experiment. Otherwise, there can be so many possibilities that can be reasoned out depending on the reaction.

Limestone has a density of 2.72 g/cm3. What is the mass of 8.92 cm3 of limestone?

Answers

it should be 24.2624 because if there’s 2.72g in every cm3 and there are 8.92 cm3, then you simply multiply the two numbers
hope this helped :)

Answer:

[tex]\boxed {\boxed {\sf 24.2624 \ g}}}[/tex]

Explanation:

Density measures mass per volume. The volume is

[tex]\rho=\frac{m}{v}[/tex]

The density of limestone is 2.72 grams per cubic centimeter. We have a piece of limestone with a volume of 8.92 cubic centimeters.

ρ= 2.72 g/cm³v= 8.92 cm₃

Substitute the values into the formula.

[tex]2.72 \ g/cm^3=\frac{m}{8.92 \ cm^3}[/tex]

Now we solve for m, the mass, by isolating the variable.

m is being divided by 8.92 cubic centimeters. The inverse of division is multiplication, so we multiply both sides by 8.92 cubic centimeters.

[tex]8.92 \ cm^3 * 2.72 \ g/cm^3=\frac{m}{8.92 \ cm^3}* 8.92 \ cm^2[/tex]

[tex]8.92 \ cm^3 * 2.72 \ g/cm^3=m[/tex]

The units of cubic centimeters cancel out.

[tex]24.2624 \ g =m[/tex]

The mass of this piece of limestone is 24.2624 grams.

How many moles are in 9.83 x 1021 atoms of Na

Answers

Answer:

0.016 moles

Explanation:

To find the number of moles in a substance given it's number of entities we use the formula

[tex]n = \frac{N}{L} \\[/tex]

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

We have

[tex]n = \frac{9.83 \times {10}^{21} }{6.02 \times {10}^{23} } \\ = 0.01632...[/tex]

We have the final answer as

0.016 moles

Hope this helps you

131.39 g/mol C2HCl3
find the molecular formulas

Answers

Answer:

Find the mass of 1 mole.

mass of

1

mole of

131.39

g

m

o

l

C

2

H

C

I

3

=

37.04000067

g

Explanation:

hope it helps make brainlliest ty

What is the pOH for a solution whose pH is 2?

Answers

Answer:

12

Explanation:

Because it is pH and pOH, you can use the relationship of 14-pH=pOH, or 14-pOH=pH. Using this you should get the pOH to be 12.

12 hope this helps you

The number of atoms in a 158.4 g sample of CO2 gas at STP is:

1.277 x 1025 atoms

2.167 x 1024 atoms

6.502 x 1024 atoms

6.651 x 1024 atoms

Answers

Answer:

Option B, 2.167 x 1024 atoms

Explanation:

1 mole of CO2 = 44.01 grams

Number of moles of CO2 in 158.4 gram sample

[tex]\frac{158.4}{44.01} \\3.95[/tex]moles

Number of atoms in one mole is [tex]6.02*10^{23}[/tex]

Number of atoms in 3.95 moles [tex]2.167 *10^{24}[/tex]

Hence, option B is correct

Please someone answer this asap

Answers

Answer:

b or c but I would just pick c

Answer:

C

Explanation:

Sun is an energy source not a matter.


What is the name for the compound with a chemical formula B6Si.

Answers

The chemical formula B₆Si belongs to the compound silicon hexaboride.

_____ is the process of linking smaller molecules to form long chains of higher molecular weight.

Answers

what is “Polymerization” is your answer

Consider the oxidation of sodium metal to sodium oxide described by the balanced equation:
4 Na + O2 → 2 Na2O. What is the theoretical yield of Na2O in grams from 9.0 mol of O2?


show steps

Answers

Answer:

1116 g.

Explanation:

The balanced equation for the reaction is given below:

4Na + O₂ —> 2Na₂O

From the balanced equation above,

1 mole of O₂ reacted to produce 2 moles of Na₂O.

Next, we shall determine the theoretical yield of Na₂O. This can be obtained as follow:

From the balanced equation above,

1 mole of O₂ reacted to produce 2 moles of Na₂O.

Therefore, 9 moles of O₂ will react to produce = 9 × 2 = 18 moles of Na₂O.

Finally, we shall determine the mass in 18 moles of Na₂O. This can be obtained as follow:

Mole of Na₂O = 18 moles

Molar mass of Na₂O = (23×2) + 16

= 46 + 16

= 62 g/mol

Mass of Na₂O =?

Mass = mole × molar mass

Mass of Na₂O = 18 × 62

Mass of Na₂O = 1116 g

Thus, the theoretical yield of Na₂O is 1116 g.

2 Which of the gases in air are elements? Explain how you can tell.​

Answers

Answer:

I'll explain.

Explanation:

The molecules of two different elements, nitrogen and oxygen, make up about 99 percent of the air. The rest includes small amounts of argon and carbon dioxide. Oxygen is the life-giving element in the air. You can tell because they're on the periodic table which is a table for elements.

Explanation:

nitrogen and oxygen are the gases in the air which are elements you can simply say it by looking the periodic table

Write out and balance the chemical equation:
A solution of nickel (II) chloride reacts with a solution of potassium hydroxide
to produce solid nickel (II) hydroxide and a solution of potassium chloride.

Answers

Explanation:

NiCl2 + KOH = NiOH + KCl

since nickel is the primary element in nickel ii chloride, find the oxidation no of nickel in the compound and chlorine should have 2 as a subscription since the ii in the compound represents that nickel has an oxidation no of 2

Determine the number of electrons in an Cl ion with a charge of -3

Answers

Answer:

There are 20 electrons.

Explanation:

Chlorine has 17 electrons in its atom to begin with (you can tell from the proton number in the periodic table).

A charge of -3 means that the chlorine atom gained 3 electrons, and now needs to lose 3 electrons to return to its atom configuration.

Which of the two Lewis/electron dot structure representations, which is
the correct one for oxygen gas? PICTURE BELOW

Answers

Answer:

A

Explanation:

Other Questions
The cattle are being fed by the farmer. (into active voice) how would you describe gravity? Based on the geography of the Great Plains, what advantages did people setting in the area have? A recipe calls for 3 cups of flour to make 3 dozen cookies. Use the proportion to calculate how (1 point much flour is needed to make 9 dozen cookies. 3 cups 1 cups 9 dozen 3 dozen cups 3.5 cups 9 cups 0 12 cups point 4. Chase sold 48 tickets to the school dance, and Justine sold 14 tickets. What is the rato, in simplest form of the number of tickets Justine sold to the number of tickets Chase sold? 7. 24 24 7 write a definition for cell, tissue, organ, and organ system. Give an example of each of these in your body. Cules fueron los principales Estados coloniales y con qu objetivo emprendan la ocupacin de territorios de ultramar? again hellllllp meeee What is the value of the x-coordinate of the vertex of the function shownbelow?f(x) = (x+6)(x - 2) Why do tectonic plates move? Use the terms asthenosphere, lithosphere and convection in your answer. Marginal revenue,graphically is:_________ a. the slope of a line from the origin to a point on the total revenue curve. b. the slope of a line from the origin to the end of the total revenue curve. c. the slope of the total revenue curve at a given point. d. the vertical intercept of a line tangent to the total revenue curve at a given point. e. the horizontal intercept of a line tangent to the total revenue curve at a given point. An architect built a scale model of asports stadium using a scale in which 3inches represents 45 feet. The height ofthe sports stadium is 180 feet. What is theheight of the scale model in inches?FOR BRAINLIST!! Which of the following statements about university and community college libraries is true? A These libraries will allow you to borrow as many books as you wish without charge. B. Most of these libraries don't provide any research or book lending services to nonstudents. c. Some of these libraries will open their services to nonstudents for a small yearly fee. D. These libraries are all unavailable to the general public. also the answer is not D at all I took the test again it is not D but I need help PLEASE HELPThe photo shows a plant that prefers very little water andnutrient-poor soil.Which type of ecosystem is most likely to have a large number of theseplants?A. GrasslandB. DesertC. Rain forestD. Deciduous forest What is the perimeter of the triangle?units En qu momento histrico se escribi el manifiesto comunista? x=5 so what is (x+3) = Mr. Dash recorded the odometerreadings in his car for a business trip.Before the trip, the odometer read23,125.6. At the end of the trip it read23,219.1. If Mr. Dash is reimbursed$0.51 for every mile, then about howmuch will he be reimbursed?PLEASE HELP ASAP Plz help this is due today AND NO LINKS OR GROSS PICTURES OR I REPORT Explain the oxygen cycle. Im in the 6th grade I need a answer please During the Tang Dynasty, a person who passed the exam for government positions could become a an emperor b a government poet c a scholar-official d a Buddhist monk