Select all the substances tested (not the reagents or the substances formed) in the qualitative analysis group I scheme nitric acid hot water silver ammonia complex silver ions lead(ll) iodide lead(ll) chloride ammonia hydrochloric acid ammonium nitrate silver chloride potassium iodide Silver iodide lead(II)ions

Answers

Answer 1

Here is the list of substances tested:
1. Silver ions (Ag+)
2. Lead(II) ions (Pb2+)

These ions are the primary cations tested in Group I of the qualitative analysis scheme.

The other substances mentioned in the question, such as nitric acid, hot water, ammonia, silver ammonia complex, lead(II) iodide, lead(II) chloride, hydrochloric acid, ammonium nitrate, silver chloride, potassium iodide, and silver iodide, are either reagents used in the testing process or substances formed as a result of the tests.

Group I cations are the first group of cations tested for in qualitative analysis, a laboratory technique used to identify the presence of specific ions in a sample. The presence of silver and lead ions is tested for in this group. The other substances mentioned in the question are used in the testing process or produced as a result of the tests.

For example, nitric acid is used to dissolve the sample being tested, while ammonia is used to make the solution basic for subsequent tests. The silver ammonia complex, lead(II) iodide, lead(II) chloride, silver chloride, potassium iodide, and silver iodide are all formed as a result of specific tests for the presence of silver and lead ions.

The specific tests and reagents used in qualitative analysis depend on the cations being tested for and the desired level of specificity and accuracy.

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Related Questions

An unknown substance has a mass of 2.50 grams. When the substance was
placed in a graduated cylinder that contains 50.00 mL of water, the water level
rose to 75.00 mL Calculate the density of this unknown substance.

Answers

An unknown substance has a mass of 2.50 grams. When the substance was placed in a graduated cylinder that contains 50.00 mL of water, the water level rose to 75.00 mL. 0.1g/  mL is  the density of this unknown substance.

The actual content's mass per cubic centimetre of volume is known as its density (volumetric density of mass and specific mass). While the Latin letter D may also be used, the sign most frequently used for density is (the upper case Greek letter rho). Density is mathematically defined simply mass divided by volume.

Density = mass / volume

volume =75.00-50

            = 25ml

Density =2.50  / 25=0.1g/  mL

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a compound called vinyl chloride has a composition of 38.43% carbon, 4.838% hydrogen, and 56.72% chlorine. when vinyl chloride is polymerized (many single units linked together to form a long chain) under certain conditions, a white solid called polyvinyl chloride is formed with molecular mass of 23875. what is the molecular formula of polyvinyl chloride ?

Answers

The molecular formula of polyvinyl chloride is (C₂H₃Cl)ₙ, where n is the number of repeating units in the polymer chain.

The given composition of vinyl chloride can be used to determine the empirical formula of the compound. To do this, we assume that we have 100g of the compound, which means we have 38.43g of carbon, 4.838g of hydrogen, and 56.72g of chlorine.

We then convert these masses to moles using the molar masses of each element:

- Moles of carbon = 38.43 g / 12.01 g/mol = 3.201 mol

- Moles of hydrogen = 4.838 g / 1.008 g/mol = 4.802 mol

- Moles of chlorine = 56.72 g / 35.45 g/mol = 1.599 mol

Next, we divide each of these mole values by the smallest mole value to get the mole ratio of the elements in the compound:

- Carbon: 3.201 mol / 1.599 mol = 2

- Hydrogen: 4.802 mol / 1.599 mol = 3

- Chlorine: 1.599 mol / 1.599 mol = 1

This gives us the empirical formula of vinyl chloride, which is C₂H₃Cl.

Polyvinyl chloride is formed by polymerizing vinyl chloride molecules to form a long chain of repeating units. The molecular mass of polyvinyl chloride is given as 23875 g/mol. To find the number of repeating units in the polymer chain, we divide the molecular mass by the molar mass of the empirical formula:

- Molar mass of C₂H₃Cl = 2(12.01 g/mol) + 3(1.008 g/mol) + 35.45 g/mol = 62.5 g/mol

- Number of repeating units = 23875 g/mol / 62.5 g/mol ≈ 382

Therefore, the molecular formula of polyvinyl chloride is (C₂H₃Cl)₃₈₂, which represents a long chain of 382 repeating units of vinyl chloride.

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A 1.00-L solution saturated at 25 ∘C with calcium oxalate (CaC2O4) contains 0.0061 g of CaC2O4.
Part A
Calculate the solubility-product constant for this salt at 25 ∘C.
Express your answer using two significant figures.

Answers

The solubility-product constant for CaC2O4 at 25 ∘C is 3.7 × 10^-11, expressed with two significant figures.

The solubility-product constant (Ksp) for CaC2O4 can be calculated using the formula:

Ksp = [Ca2+][C2O42-]

Where [Ca2+] and [C2O42-] represent the molar concentrations of the ions in solution. Since the solution is saturated, the concentration of CaC2O4 in the solution is equal to its solubility, which can be calculated as:

solubility = 0.0061 g / 1.00 L = 6.1 × 10^-6 g/L

Since CaC2O4 dissociates into one Ca2+ ion and one C2O42- ion in solution, their concentrations can be expressed as:

[Ca2+] = solubility
[C2O42-] = solubility

Substituting these values into the Ksp expression, we get:

Ksp = (solubility)(solubility) = solubility^2

Ksp = (6.1 × 10^-6 g/L)^2 = 3.7 × 10^-11

Therefore, the solubility-product constant for CaC2O4 at 25 ∘C is 3.7 × 10^-11, expressed with two significant figures.

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The solubility product constant for calcium oxalate at 25 ∘C is [tex]2.31 × 10^-8,[/tex] expressed in two significant figures. The units for Ksp are [tex](M)^2.[/tex]

The solubility product constant (Ksp) for calcium oxalate [tex]CaC_{2}O_{4}[/tex] can be calculated using the given information as follows:

[tex]CaC_{2}O_{4}(s) \rightleftharpoons Ca^{2+}(aq) + C_{2}O_{4}^{2-}(aq)[/tex]

The equilibrium expression for the dissociation of calcium oxalate is:

Ksp = [[tex]Ca^{2+[/tex]][[tex]C2O4^2[/tex]-]

We can use the given mass of [tex]CaC_{2}O_{4}[/tex] and the volume of the solution to calculate the molar solubility of [tex]CaC_{2}O_{4}[/tex]

molar solubility = (0.0061 g) / (40.08 g/mol) / (1.00 L) = 0.000152 M

The molar solubility represents the concentration of the ions in the saturated solution at equilibrium.

Since calcium oxalate dissociates in a 1:1 ratio, the concentration of both [tex]Ca^{2+[/tex] and [tex]C2O4^2[/tex]- ions in the saturated solution is also 0.000152 M.

Substituting these values into the equilibrium expression, we get:

Ksp = [[tex]Ca^{2+[/tex]][[tex]CaC_{2}O_{4}[/tex]] = (0.000152 M)(0.000152 M) = 2.31 × [tex]10^-8[/tex]

Therefore, the solubility product constant for calcium oxalate at 25 ∘C is [tex]2.31 × 10^-8,[/tex] expressed to two significant figures. The units for Ksp are [tex](M)^2.[/tex]

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1. if 200 g of mgcl2 is required to saturate 1.5 l of solution at 20 oc, calculate the ksp.

Answers

The balanced chemical equation for the dissociation of MgCl2 is:

MgCl2(s) ⇌ Mg2+(aq) + 2Cl-(aq)

The equilibrium expression for the dissociation reaction is:

Ksp = [Mg2+][Cl-]^2

where Ksp is the solubility product constant, [Mg2+] is the concentration of Mg2+ ions in solution, and [Cl-] is the concentration of Cl- ions in solution.

To calculate the Ksp of MgCl2, we need to first determine the concentration of Mg2+ and Cl- ions in the saturated solution. We can do this by using the given information that 200 g of MgCl2 is required to saturate 1.5 L of solution at 20°C.

The molar mass of MgCl2 is:

MgCl2 = 24.31 + 2(35.45) = 95.21 g/mol

So, the number of moles of MgCl2 in 200 g is:

n = mass / molar mass = 200 g / 95.21 g/mol = 2.10 mol

Since MgCl2 dissociates into one Mg2+ ion and two Cl- ions, the number of moles of Mg2+ ions in the solution is equal to the number of moles of MgCl2:

[Mg2+] = 2.10 mol / 1.5 L = 1.40 M

[Cl-] is twice the concentration of Mg2+ ions:

[Cl-] = 2 × [Mg2+] = 2.80 M

Now we can substitute these values into the Ksp expression to calculate the Ksp:

Ksp = [Mg2+][Cl-]^2 = (1.40 M)(2.80 M)^2 = 11.4

Therefore, the Ksp of MgCl2 at 20°C is 11.4. The units for Ksp depend on the units used for the concentrations. In this case, the units for Ksp are (M) x (M)^2 = M^3.

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One compound under investigation for use as a lightweight rocket fuel is dimethylhydrazine (60.10 g'mol). It reacts with dinitrogen tetroxide (92.01 g/mol) according to the following reaction: (CH3), N2H4の+ N2o,の→ 3 N2 (g) + 4 H2O(g) + 2 CO2(g) If 150 g of (CH3)2N2H4 react with excess N204 at 473 K and 760 torr, what volume of CO2 gas will form? a. 97 L d. 82 L e. 220 L 41 L 190 L

Answers

The volume of CO₂ gas that will be formed when 150 g of (CH₃)₂N₂H₄ react with excess N₂O₄ at 473 K and 760 torr is 190 L.

To find the volume of CO₂ gas formed, we need to convert the mass of dimethylhydrazine to moles, use the stoichiometry of the balanced reaction to find the moles of CO₂ formed, and use the Ideal Gas Law (PV=nRT) to find the volume of CO₂ gas.

1. Moles of dimethylhydrazine:
moles = mass / molar mass = 150 g / 60.10 g/mol = 2.50 moles

2. From the balanced reaction: 1 mole of (CH₃)₂N₂H₄ produces 2 moles of CO₂
moles of CO₂ = 2.50 moles (CH₃)₂N₂H₄ × (2 moles CO₂ / 1 mole (CH₃)₂N₂H₄) = 5.00 moles CO₂

3. Ideal Gas Law: PV=nRT
Given: P = 760 torr = 1 atm (as 760 torr = 1 atm), T = 473 K, n = 5.00 moles, R = 0.0821 L*atm/mol*K
V = nRT / P = (5.00 moles) × (0.0821 L*atm/mol*K) × (473 K) / (1 atm) = 193.55 L

The closest answer to 193.55 L is 190 L. Therefore, the correct answer is 190 L.

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The volume of CO₂ gas that will be formed when 150 g of (CH₃)₂N₂H₄ react with excess N₂O₄ at 473 K and 760 torr is 190 L.

To find the volume of CO₂ gas formed, we need to convert the mass of dimethylhydrazine to moles, use the stoichiometry of the balanced reaction to find the moles of CO₂ formed, and use the Ideal Gas Law (PV=nRT) to find the volume of CO₂ gas.

1. Moles of dimethylhydrazine:
moles = mass / molar mass = 150 g / 60.10 g/mol = 2.50 moles

2. From the balanced reaction: 1 mole of (CH₃)₂N₂H₄ produces 2 moles of CO₂
moles of CO₂ = 2.50 moles (CH₃)₂N₂H₄ × (2 moles CO₂ / 1 mole (CH₃)₂N₂H₄) = 5.00 moles CO₂

3. Ideal Gas Law: PV=nRT
Given: P = 760 torr = 1 atm (as 760 torr = 1 atm), T = 473 K, n = 5.00 moles, R = 0.0821 L*atm/mol*K
V = nRT / P = (5.00 moles) × (0.0821 L*atm/mol*K) × (473 K) / (1 atm) = 193.55 L

The closest answer to 193.55 L is 190 L. Therefore, the correct answer is 190 L.

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Below is the electron configuration of calcium: Ca 1s^22s^22p^63s^23p^64s^2In its reactions, calcium tends to form the Ca2+ ion. Which electrons are lost upon ionization? a. the 4s electrons b. the 1s electronsc. the 3s electrons d. two of the 3p electrons

Answers

The correct answer is a. the 4s electrons.

When Calcium undergoes ionization, it loses two electrons to become a cation with a 2+ charge. These electrons are removed from the highest energy level, which is the 4s orbital. The electrons in the 4s orbital are more loosely held by the nucleus compared to the electrons in the lower energy orbitals, such as 1s, 2s, and 2p. This is because the 4s orbital is farther away from the nucleus and experiences less effective nuclear charge. Thus, the 4s electrons are easier to remove, and they are lost first during ionization. The remaining electron configuration of the Ca2+ ion is [Ar] 3s^23p^6, which corresponds to a noble gas configuration of Argon. This stable configuration is achieved by losing the two 4s electrons, which is energetically favorable for Calcium. Overall, understanding electron configuration and ionization helps explain the chemical behavior of elements and their tendency to form ions.

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What general conclusions can you draw concerning the acidity or basicity of the hydroxides of the elements of the third period? Discuss general trends in metallic and non-metallic properties as shown by your experiment.

Answers

The hydroxides of the elements in the third period show a general trend in which basicity decreases and acidity increases from left to right, with metallic hydroxides being more basic and non-metallic hydroxides being more acidic. This trend is in line with the observed changes in metallic and non-metallic properties across the period.

The general conclusions that can be drawn concerning the acidity or basicity of the hydroxides of the elements of the third period are as follows:
1. As we move from left to right across the third period, the basicity of the hydroxides generally decreases.
2. Metallic hydroxides are generally basic in nature, while non-metallic hydroxides tend to be acidic.
3. There is a clear trend in metallic and non-metallic properties as shown by the experiment: elements on the left side of the period are more metallic, while elements on the right side are more non-metallic.

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Which contains more atoms, a pound of lithium (Li) or a pound of lead (Pb)?

Answers

A pound of lithium contains more atoms than a pound of lead due to its lower atomic mass. Lithium has an atomic mass that is almost 30 times less than lead, so it takes a larger number of lithium atoms to make up the same mass as lead atoms.

The number of atoms in a substance is determined by its atomic mass, which is the sum of the masses of all the protons, neutrons, and electrons in an atom. Lithium has an atomic mass of 6.941 atomic mass units (amu), while lead has an atomic mass of 207.2 amu. Therefore, one pound of lithium will contain more atoms than one pound of lead.
To calculate the number of atoms in a pound of each substance, we need to use Avogadro's number, which is 6.022 * 10^{23} atoms per mole. One mole of lithium weighs 6.941 grams, while one mole of lead weighs 207.2 grams. Therefore, one pound of lithium (453.59 grams) is equivalent to 65.33 moles, or 3.93 * 10^{25} atoms. On the other hand, one pound of lead is equivalent to 2.43 moles, or 1.46 * 10^24 atoms.

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a certain reaction has an activation energy of 61.25 kj/mol. at what kelvin temperature will the reaction proceed 5.50 times faster than it did at 363 k?Calculate the rate constant, k, for a reaction at 71.0 °C that has an activation energy of 87.7 kJ/mol and a frequency factor of 9.18×10^11 s-1.

Answers

For the first question, we can use the Arrhenius equation: the reaction will proceed 5.50 times faster at 439 K or 166°C than it did at 363 K. the rate constant for the reaction at 71.0°C is 2.10×[tex]10^3 s^{-1}[/tex]

[tex]k2/k1 = exp[(Ea/R)((1/T1)-(1/T2))][/tex]

where k1 and T1 are the rate constant and temperature at which the reaction proceeds at a certain rate, k2 is the desired rate constant, Ea is the activation energy, R is the gas constant, and T2 is the temperature at which we want the reaction to proceed faster.

Let's plug in the given values and solve for T2:

[tex]5.50 = exp[(61.25 kJ/mol)/(8.314 J/(molK))((1/363 K)-(1/T2))][/tex]

T2 = 439 K or 166°C

Therefore, the reaction will proceed 5.50 times faster at 439 K or 166°C than it did at 363 K.

For the second question, we can use the Arrhenius equation to calculate the rate constant, k:  the rate constant for the reaction at

   71.0°C is 2.10×[tex]10^3 s^{-1}[/tex]

[tex]k = A*exp(-Ea/RT)[/tex]

where A is the frequency factor, Ea is the activation energy, R is the gas constant, and T is the temperature in Kelvin.

Let's plug in the given values:

T = (71.0 + 273.15) K = 344.15 K

Ea = 87.7 kJ/mol = 87,700 J/mol

A = 9.18×[tex]10^1 s^{-1}[/tex]

R = 8.314 J/(mol*K)

k = (9.18×[tex]10^11 s^{-1}[/tex])exp(-((87,700 J/mol)/(8.314 J/(molK)*344.15 K)))\\k = 2.10×[tex]10^3 s^{-1}[/tex]

Therefore, the rate constant for the reaction at 71.0°C is 2.10×[tex]10^3 s^{-1}[/tex].

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In which of these substances are the atoms held together by metallic bonding?
A. Cr
B. Si
C. S8
D. CO2
E. Br2

Answers

The substance in which the atoms are held together by metallic bonding is A. Cr (Chromium).


In the given list of substances, the atoms are held together by metallic bonding in option A. Cr (Chromium). Metallic bonding is a characteristic of metals, and Chromium is a metal, while the other options consist of non-metals and covalent compounds.

The electrostatic attraction between positively charged metal ions and conduction electrons (in the form of an electron cloud of delocalized electrons) results in metallic bonding, a type of chemical bonding. A structure of positively charged ions (cations) may be thought of as sharing free electrons. Many of the physical characteristics of metals, including their strength, ductility, thermal and electrical resistivity and conductivity, opacity, and lustre, are explained by their metallic bonding.

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There are many organic acids and bases in our cells, and their presence modifies the pH of the cell media (cytosol). A solution of equal concentrations of lactic acid and sodium lactate was found to have pH = 3.08.
a) What are the values of pKa and Ka of lactic acid?
b) What would be the pH is the acid had twice the concentration of the salt?

Answers

a) The pKa of lactic acid is 3.86, and the Ka is 1.38 × 10^-4.

b) If the acid had twice the concentration of the salt, the pH would increase to 3.47.

a) The pH of a solution of equal concentrations of lactic acid and sodium lactate is equal to the pKa of lactic acid, which is 3.86. Using the relationship between Ka and pKa (pKa = -log(Ka)), the Ka of lactic acid can be calculated as 1.38 × 10^-4.

b) If the acid had twice the concentration of the salt, the initial concentration of lactic acid would be twice that of the original solution. Using the Henderson-Hasselbalch equation, pH = pKa + log([salt]/[acid]), the pH of the solution can be calculated.

Since the concentration of the salt remains the same, while the concentration of the acid doubles, the ratio of [salt]/[acid] becomes 0.5. Plugging in the values, pH = 3.86 + log(0.5) = 3.47. Therefore, the pH of the solution would increase to 3.47.

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reduction of acid chlorides with ______________ gives good yields of aldehydes.

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Reduction of acid chlorides with reducing agents such as lithium aluminum hydride or sodium borohydride gives good yields of aldehydes.

Reduction is a chemical reaction in which a molecule gains one or more electrons, resulting in a decrease in the oxidation state of one or more atoms in the molecule.

Reducing agents lithium aluminum hydride or sodium borohydride are strong enough to reduce acid chlorides to aldehydes but do not reduce the aldehyde further to primary alcohols. The hydrolysis step is important to remove any remaining reducing agent and to convert the intermediate aldehyde aluminum or boron complex to the corresponding aldehyde.

Therefore, the Reduction of acid chlorides with a mild reducing agent such as lithium aluminum hydride (LiAlH4) or sodium borohydride (NaBH4) followed by hydrolysis gives good yields of aldehydes.

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Reduction of acid chlorides with reducing agents such as lithium aluminum hydride or sodium borohydride gives good yields of aldehydes.

Reduction is a chemical reaction in which a molecule gains one or more electrons, resulting in a decrease in the oxidation state of one or more atoms in the molecule.

Reducing agents lithium aluminum hydride or sodium borohydride are strong enough to reduce acid chlorides to aldehydes but do not reduce the aldehyde further to primary alcohols. The hydrolysis step is important to remove any remaining reducing agent and to convert the intermediate aldehyde aluminum or boron complex to the corresponding aldehyde.

Therefore, the Reduction of acid chlorides with a mild reducing agent such as lithium aluminum hydride (LiAlH4) or sodium borohydride (NaBH4) followed by hydrolysis gives good yields of aldehydes.

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True or False? the initial amounts of reactants placed in the i row of the icf table for a reaction are dependent on the coefficients in the balanced chemical reaction.

Answers

The coefficients in the balanced chemical equation directly affect how much of each reactant is first added to the ICF (initial change final) table for a chemical reaction. True

The coefficients represent the mole ratios between the reactants and products in the reaction. Therefore, the amount of each reactant needed to completely react with the other reactants and produce the predicted amount of product can be determined based on these coefficients.

The ICF table is used to keep track of the amounts of each reactant and product at each stage of the reaction, from the initial amounts before the reaction takes place, to the changes that occur during the reaction, and finally to the amounts at equilibrium. The coefficients are essential for correctly predicting the stoichiometry of the reaction and determining the limiting reactant.

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Which indicator shows a color change at about the same pH as the equivalence point?

Answers

The indicator that shows a color change at about the same pH as the equivalence point is called the endpoint indicator. This indicator changes color when the amount of titrant added is stoichiometrically equivalent to the amount of analyte in the sample. Examples of endpoint indicators include phenolphthalein and bromocresol green.

An indicator that shows a color change at about the same pH as the equivalence point is called a suitable indicator. A suitable indicator has a pH range that matches the pH at the equivalence point of the specific titration being performed. For example, phenolphthalein is often used in acid-base titrations because its pH range (8.2-10.0) aligns well with the equivalence point of many titrations involving a strong acid and a strong base.

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Barium enema is a diagnostic medical procedure in which the inside of the large intestine is coated with an aqueous slurry of insoluble BaSO4 and imaged using X- ray. If you're a chemist, this probably rings all sorts of alarm bells because Ba is a heavy metal that's absorbed throughout the gastrointestinal tract and levels in drinking water as low as 10 mg/L (about 7 x 10-5 M) have been shown to result in an elevated risk of heart attack and stroke. If you ask the medical folks they'll say "Oh, that's not a problem because BaSO4 is completely insoluble in water." Of course you know that's questionable because your Quantitative Chemistry textbook lists a solubility product for BaSO4 so there's got to be a little Ba2+ in that solution.2 a. (4) What is the molar concentration of Ba2+ in a saturated solution of BaSO4 in deionized water?

Answers

Ba2+ has a molar concentration of 1.05 x 105 M in a saturated solution of BaSO4 in deionized water.

To find the molar concentration of Ba²⁺ in a saturated solution of BaSO₄ in deionized water, you'll need to use the solubility product constant (Kₛₚ) for BaSO₄.

1. Locate the Kₛₚ value for BaSO₄: For BaSO₄, the Kₛₚ value is 1.1 x 10⁻¹⁰.

2. Write the dissociation equation: BaSO₄ (s) ⇌ Ba²⁺ (aq) + SO₄²⁻ (aq)

3. Set up an expression for the Kₛₚ: Kₛₚ = [Ba²⁺][SO₄²⁻]

Since the stoichiometry of the dissociation is 1:1, the molar concentration of Ba²⁺ and SO₄²⁻ will be equal.

4. Substitute the Kₛₚ value and solve for the molar concentration of Ba²⁺:

1.1 x 10⁻¹⁰ = [Ba²⁺][SO₄²⁻] = [Ba²⁺]²

To find the concentration of Ba²⁺, take the square root of both sides:

[Ba²⁺] = √(1.1 x 10⁻¹⁰) ≈ 1.05 x 10⁻⁵ M

So, the molar concentration of Ba²⁺ in a saturated solution of BaSO₄ in deionized water is approximately 1.05 x 10⁻⁵ M.

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P₁
T₁ V₁
T₁
P₂
=
For each of the following situations, determine which
Gas Law equation you would use to answer the
question.
V₂
P₁V₁ = P₂V₂
Situation 1- Suppose we have a 2.37-L sample of gas at 298 K that
is then heated to 354 K with no change in pressure. What is the final
volume of the sample?
Situation 2 - If a gas originally at 750 torr is cooled from 323.0 K to
273 K and the volume is kept constant, what is final pressure of the
gas?
Situation 3-A snorkeler takes a syringe filled with 16 mL of air from
the surface, where the pressure is 1.0 atm, to an unknown depth.
The volume of the air in the syringe at this depth is 7.5 ML. What is
the pressure at this depth?
Gas Law Equation

Answers

Gases show great uniformity in their behaviour irrespective of their nature. Some useful generalizations have been deduced from the behaviour of gases which are known as gas laws. There are different gas laws like Boyle's law, Charles's law, Avogadros law, etc.

According to Charles's law, at constant pressure the volume of a given mass of gas is directly proportional to the temperature on Kelvin scale. Mathematically, the law is V = constant × T.

The equation for Charles's law is:

1) V₁ / T₁ = V₂ / T₂

V₂ = V₁T₂ / T₁

2.37 × 354 / 298 = 2.81 L

2) Gay-Lussac's law is:

P₁ / T₁ = P₂ / T₂

P₂ = P₁T₂  / T₁

750 × 273 / 323 = 633.90 torr

3) Boyles law is:

P₁V₁ = P₂V₂

P₂ = P₁V₁ / V₂

1.0 × 16  / 7.5 = 2.13 atm

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a sample of perchloryl fluoride, clo3f, contains 0.265 mol of the compound. what is the mass of the sample, in grams?

Answers

The mass of the perchloryl fluoride sample is approximately 27.15 grams.

To find the mass of the sample, you need to know the molar mass of perchloryl fluoride (ClO3F). The molar mass is calculated by adding the molar masses of its constituent elements:

Cl = 35.45 g/mol
O = 16.00 g/mol
F = 19.00 g/mol

Molar mass of ClO3F = 35.45 + (3 * 16.00) + 19.00 = 35.45 + 48.00 + 19.00 = 102.45 g/mol

Now, use the given moles of the compound (0.265 mol) to calculate the mass of the sample:

Mass = moles × molar mass
Mass = 0.265 mol × 102.45 g/mol ≈ 27.15 g

So, the mass of the perchloryl fluoride sample is approximately 27.15 grams.

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Methane reacts with oxygen according to a balanced equation CH4 + 202 -CO2 + 2H2O Determine whether each statement describing the reaction is true or false. One mole of methane reacts with two moles of oxygen to produce one mole of carbon dioxide and two moles of water. Choose... One molecule of methane reacts with two molecules of oxygen to produce one molecule of carbon dioxide and two Choose... molecules of water. One gram of methane reacts with two grams of oxygen to produce one gram of carbon dioxide and two grams of water. Choose.. CHECK

Answers

True - One mole of methane (16 g) reacts with two moles of oxygen (64 g) to produce one mole of carbon dioxide (44 g) and two moles of water (36 g).


False - One molecule of methane reacts with two molecules of oxygen to produce one molecule of carbon dioxide and two molecules of water. This is because the balanced equation uses moles, not molecules.


True - One gram of methane reacts with two grams of oxygen to produce one gram of carbon dioxide (44 g/mol) and two grams of water (18 g/mol).


1. True: One mole of methane (CH4) reacts with two moles of oxygen (O2) to produce one mole of carbon dioxide (CO2) and two moles of water (H2O).

2. True: One molecule of methane (CH4) reacts with two molecules of oxygen (O2) to produce one molecule of carbon dioxide (CO2) and two molecules of water (H2O).

3. False: One gram of methane reacts with a different mass of oxygen, not two grams, to produce different masses of carbon dioxide and water. This is because you need to consider the molar masses of each substance when discussing mass ratios.

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True - One mole of methane (16 g) reacts with two moles of oxygen (64 g) to produce one mole of carbon dioxide (44 g) and two moles of water (36 g).


False - One molecule of methane reacts with two molecules of oxygen to produce one molecule of carbon dioxide and two molecules of water. This is because the balanced equation uses moles, not molecules.


True - One gram of methane reacts with two grams of oxygen to produce one gram of carbon dioxide (44 g/mol) and two grams of water (18 g/mol).


1. True: One mole of methane (CH4) reacts with two moles of oxygen (O2) to produce one mole of carbon dioxide (CO2) and two moles of water (H2O).

2. True: One molecule of methane (CH4) reacts with two molecules of oxygen (O2) to produce one molecule of carbon dioxide (CO2) and two molecules of water (H2O).

3. False: One gram of methane reacts with a different mass of oxygen, not two grams, to produce different masses of carbon dioxide and water. This is because you need to consider the molar masses of each substance when discussing mass ratios.

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Compound Molar mass (g/mol)
NaCN
49.0
65.0
40.0
58.4
NaN3
NaOH
NaCl
Based on the information in the table, which of the following compounds
contains the greatest percentage of sodium by mass?

Answers

Answer:

Calculating the molar mass of each compound as well as the mass of the sodium in each compound will help us identify which compound has the highest mass percentage of sodium. After that, we can determine the salt content in mass.

Molar mass of NaCN = 49.0 g/mol

Mass of Na in NaCN = 23.0 g/mol

Percentage of Na by mass in NaCN = (23.0 g/mol / 49.0 g/mol) x 100% = 46.9%

Molar mass of NaN3 = 65.0 g/mol

Mass of Na in NaN3 = 23.0 g/mol

Percentage of Na by mass in NaN3 = (23.0 g/mol / 65.0 g/mol) x 100% = 35.4%

Molar mass of NaOH = 40.0 g/mol

Mass of Na in NaOH = 23.0 g/mol

Percentage of Na by mass in NaOH = (23.0 g/mol / 40.0 g/mol) x 100% = 57.5%

Molar mass of NaCl = 58.4 g/mol

Mass of Na in NaCl = 23.0 g/mol

Percentage of Na by mass in NaCl = (23.0 g/mol / 58.4 g/mol) x 100% = 39.4%

Therefore, NaOH contains the greatest percentage of sodium by mass, at 57.5%.

Based on the masses that react, we have 0.5 mol of [tex]NaOH[/tex] and 0.185 mol of FeCl₃, which react to form 0.185 mol of Fe(OH)₃.

To calculate the amount (mol) of each compound based on the masses that react, you first need to use the given molar masses to convert the mass of each compound to moles. This can be done using the formula:

moles = mass (in grams) / molar mass (in grams/mol)

For example, if we have 20 grams of NaOH, we can calculate the number of moles as:

moles[tex]NaOH[/tex] = 20 g / 40.00 g/mol = 0.5 mol

Similarly, if we have 30 grams of [tex]FeCl₃,[/tex] we can calculate the number of moles as:

moles FeCl₃ = 30 g / 162.21 g/mol = 0.185 mol

Therefore, we have 0.5 mol of NaOH and 0.185 mol of FeCl₃ reacting with each other. The balanced chemical equation for the reaction is:

[tex]3 NaOH + FeCl₃ → Fe(OH)₃ + 3 NaCl[/tex]

From the equation, we can see that 3 moles of NaOH react with 1 mole of FeCl₃ to produce 1 mole of Fe(OH)₃ and 3 moles of NaCl. Since we have excess NaOH in this case, we can use the amount of FeCl₃ to determine the limiting reactant and the amount of product formed.

Since we have 0.185 mol of FeCl₃ and it reacts with 3 moles of NaOH, the amount of NaOH required for complete reaction would be:

moles [tex]NaOH required = 0.185 mol FeCl₃ × (3 mol NaOH / 1 mol FeCl₃) = 0.555 mol[/tex]

Since we have 0.5 mol of NaOH, it is the limiting reactant and only 0.185 mol of FeCl₃ will react to form the product. The amount of Fe(OH)₃ formed can be calculated as:

[tex]moles EditCopy equationRemove formed = 0.185 mol FeCl₃ × (1 mol Fe(OH)₃ / 1 mol FeCl₃) = 0.185 mol[/tex]

Therefore, we have 0.5 mol of[tex]NaOH[/tex]and 0.185 mol of FeCl₃, which react to form 0.185 mol of Fe(OH)₃.

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Calculate the activity coefficient υag for 0.079 m AgNO3.

Answers

The activity coefficient (υag) for 0.079 m AgNO₃ can be calculated using the Debye-Hückel limiting law formulaυag = 10^(-Az√I)

where A is a constant, z is the charge of the ion, and I is the ionic strength.

To calculate the activity coefficient υag for 0.079 m AgNO₃, follow these steps:

1. Identify the ions and their charges: Ag⁺ (z = 1) and NO₃⁻ (z = -1).
2. Calculate the ionic strength (I): I = 1/2 * Σ(ci * zi²), where ci is the concentration of each ion and zi is its charge.
3. Plug the values into the Debye-Hückel formula and calculate υag.

In summary, the activity coefficient υag for 0.079 m AgNO₃ can be determined by identifying the ions and their charges, calculating the ionic strength, and then applying the Debye-Hückel limiting law formula.

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Draw the full mechanism of the crossed aldol condensation reaction of 4-chlorobenzaldehyde with acetone. (There are 2 equivalents of 4-chlorobenaldehde and 1 equivalent of acetone and the product is 1,5-bis(4-chlorophenyl)-1,4-pentadien-3-one).

Answers

The crossed aldol condensation reaction of 4-chlorobenzaldehyde with acetone produces 1,5-bis(4-chlorophenyl)-1,4-pentadien-3-one. The reaction involves enolate ion formation, nucleophilic attack, and dehydration steps.


Step 1: Enolate ion formation - Acetone (the less hindered carbonyl compound) reacts with a base, such as sodium hydroxide, to form an enolate ion.

Step 2: Nucleophilic attack - The enolate ion generated in Step 1 acts as a nucleophile and attacks one molecule of 4-chlorobenzaldehyde at the carbonyl carbon. This creates an alkoxide intermediate.

Step 3: Protonation - The alkoxide intermediate is protonated by water, resulting in an alcohol product, which is a β-hydroxyketone.

Step 4: Second nucleophilic attack - Another enolate ion (formed as in Step 1) attacks a second molecule of 4-chlorobenzaldehyde, creating another alkoxide intermediate.

Step 5: Second protonation - This second alkoxide intermediate is protonated by water, leading to a bis(4-chlorophenyl) β-hydroxyketone.

Step 6: Dehydration - The bis(4-chlorophenyl) β-hydroxyketone loses a water molecule to form the final product, 1,5-bis(4-chlorophenyl)-1,4-pentadien-3-one.

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draw the major organic product of the claisen condensation of ethyl 3,3-dimethylbutanoate in the presence of sodium ethoxide.

Answers

The major organic product of the Claisen condensation of ethyl 3,3-dimethylbutanoate in the presence of sodium ethoxide

is the dimer product of the ester, which is 3,3-dimethyl-2,2-bis(ethoxide y carbonyl)butanoate. During the reaction, the sodium ethoxide deprotonates the ethyl ester and then attacks the carbonyl carbon of another molecule of the same ester, resulting in the formation of an intermediate alkoxide. This intermediate then undergoes a rearrangement and subsequent elimination of ethoxide ion to yield the dimer product.
Hi! In the Claisen condensation of ethyl 3,3-dimethylbutanoate with sodium ethoxide, the major organic product will be the result of an ester molecule undergoing a nucleophilic acyl substitution. Sodium ethoxide acts as a strong base and nucleophile in this reaction.

Your answer: The major organic product will be the ethyl 3,3-dimethylglutarate, formed by the condensation between two molecules of ethyl 3,3-dimethylbutanoate in the presence of sodium ethoxide.

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The temperature of 2.50 moles of an ideal gas increases from 13.5 degrees Celsius to 55.1 degrees as the gas is compressed adiabatically. Calculate q, w, ?U, and ?H for this process assuming that Cvm = 3R/2 (the vi and m are subscripts for this).
q= 0 since its adiabatic. w=?U = 1.30x10 ^3J, ?H=2.16 x 10 ^ 3 J.

Answers

The values of q, w, ΔU, and ΔH for this process are:

q = 0

w = -1.30 × 10^3 J

ΔU = -1.30 × 10^3 J

ΔH = 2.16 × 10^3 J

What are the values of  q, w, ?U, and ?H?

Since the process is adiabatic, the heat transfer (q) is zero. Thus, all the energy transferred is in the form of work (w).

We can use the following equations to calculate the work done, change in internal energy, and change in enthalpy:

w = -nCvΔT

ΔU = q + w = w (since q = 0)

ΔH = ΔU + PΔV

where n is the number of moles of the gas, Cv is the molar specific heat at constant volume, ΔT is the change in temperature, P is the pressure, and ΔV is the change in volume.

Plugging in the given values, we get:

w = -2.50 mol × (3R/2) J/(mol K) × (55.1 - 13.5) K = -1.30 × 10^3 J

ΔU = w = -1.30 × 10^3 J

To calculate ΔH, we need to find ΔV. For an adiabatic process, we have:

PVγ = constant

where γ is the ratio of specific heats (Cp/Cv) for the gas. For an ideal gas, γ = Cp/Cv = 1 + 2/f, where f is the number of degrees of freedom of the gas molecules (f = 3 for a monoatomic gas like helium or neon).

We can use the ideal gas law to relate P, V, n, and T:

PV = nRT

Combining these two equations, we get:

Vγ-1 = constant

Taking the initial and final states to be state 1 and state 2, respectively, we can write:

P1V1γ = P2V2γ

P2/P1 = (V1/V2)γ = (T1/T2)γ/(γ-1)

Plugging in the given values, we get:

P2/P1 = (286.65 K/286.65 K)^1.5/(1.5) × (328.65 K/328.65 K)^1.5/(1.5) = 1.797

Since the process is adiabatic, the gas is compressed, and the final temperature is higher than the initial temperature, we know that P2 > P1. Thus, we can assume that P2 = 1.797P1. Using the ideal gas law, we can find the initial and final volumes:

V1 = nRT1/P1 = 2.50 mol × 8.314 J/(mol K) × 286.65 K/(1.000 atm) = 59.2 L

V2 = nRT2/P2 = 2.50 mol × 8.314 J/(mol K) × 328.65 K/(1.797 atm) = 40.7 L

Thus, ΔV = V2 - V1 = -18.5 L.

Finally, we can calculate ΔH:

ΔH = ΔU + PΔV = -1.30 × 10^3 J + (1.000 atm)(-18.5 L) × (101.325 J/L atm) = 2.16 × 10^3 J

Therefore, the values of q, w, ΔU, and ΔH for this process are:

q = 0

w = -1.30 × 10^3 J

ΔU = -1.30 × 10^3 J

ΔH = 2.16 × 10^3 J

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what is the oxidation number of re in mg(reo4)2?

Answers

The oxidation number of rhenium (Re) in Mg(ReO4)2 is +7.

Why is the oxidation number Mg(ReO4)2 is +7?

The oxidation number of rhenium (Re) in magnesium perrhenate, Mg(ReO4)2, can be determined by assigning oxidation numbers to the other atoms in the compound and using the overall charge of the compound.

The magnesium ion (Mg2+) has a known oxidation state of +2. Oxygen (O) atoms in a compound have a known oxidation state of -2, and there are a total of eight oxygen atoms in the compound (4 per ReO4). So the total oxidation state contributed by the oxygen atoms is:

-2 x 8 = -16

The overall charge of the compound is neutral, so the sum of the oxidation states of all the atoms must be zero:

x (oxidation state of Re) + 2 (+1 for each Mg2+) + (-16 from the oxygen atoms) = 0

Solving for x, we get:

x = +7

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tert-Butylbenzene can be prepared by alkylation of benzene using an alkene or an alcohol as the carbocation source. What alkene? What alcohol?

Answers

To prepare tert-Butylbenzene through alkylation of benzene, you can use isobutylene as the alkene and tert-butyl alcohol as the carbocation source.

How to conduct an alkylation reaction?


Step 1: Alkylation using isobutylene (alkene)
Benzene reacts with isobutylene in the presence of a strong acid catalyst (e.g., sulfuric acid) to form tert-butylbenzene.

Step 2: Alkylation using tert-butyl alcohol (carbocation source)
Benzene reacts with tert-butyl alcohol in the presence of a strong acid catalyst (e.g., sulfuric acid) to form tert-butylbenzene. The acid catalyst protonates the alcohol, forming a tert-butyl carbocation, which then reacts with benzene.

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To prepare tert-Butylbenzene through alkylation of benzene, you can use isobutylene as the alkene and tert-butyl alcohol as the carbocation source.

How to conduct an alkylation reaction?


Step 1: Alkylation using isobutylene (alkene)
Benzene reacts with isobutylene in the presence of a strong acid catalyst (e.g., sulfuric acid) to form tert-butylbenzene.

Step 2: Alkylation using tert-butyl alcohol (carbocation source)
Benzene reacts with tert-butyl alcohol in the presence of a strong acid catalyst (e.g., sulfuric acid) to form tert-butylbenzene. The acid catalyst protonates the alcohol, forming a tert-butyl carbocation, which then reacts with benzene.

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PLEASE HELP ASAP IM STUCK
1. Match the drawings of the following hydrocarbons with the correct names.

Answers

3 methyl 2 hept-yne is the first compound. 2,3- dimethyl- 2- heptene is the second compound. 2,3,4 trimethyl octane is third compound. 2-pentyne is fourth compound.

The first substance, 3-methyl-2-heptyne, contains a triple bond between the second and third carbon atoms and a chain of seven carbon atoms. The third carbon atom is joined to the methyl group.

The second substance, 2,3-dimethyl-2-heptene, has a double bond between the second and third carbon atoms and a chain of seven carbon atoms. The second carbon atom has two methyl groups bonded to it.

Eight carbon atoms make up the chain of the third chemical, 2,3,4-trimethyl-octane, which also has three methyl groups connected to its carbon atoms 2, 3, and 4.

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atmospheric pressure at sea level is equal to 101.32 kilopascals (kpa). why do you think water boils when the vapor pressure is equal to atmospheric pressure?

Answers

Water boils when the vapor pressure is equal to atmospheric pressure because at this point, the pressure of the water molecules pushing up against the atmosphere is the same as the pressure of the atmosphere pushing down on the water.

When the vapor pressure reaches this level, it means that enough energy has been added to the water to break the bonds between the water molecules and turn them into gas molecules. This is what causes the water to boil and turn into steam.

It is important to note that atmospheric pressure at sea level plays a critical role in this process, as it determines the boiling point of water and other liquids.

When water is heated, the vapor pressure increases until it matches atmospheric pressure. At this point, water molecules have enough kinetic energy to break free from their liquid state and transform into vapor. This causes water to boil, with bubbles of vapor forming and rising to the surface.

The boiling point varies with changes in atmospheric pressure, which is why water boils at lower temperatures at higher altitudes where the pressure is lower.

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how many moles of Ca(OH)2 are produced from 49 grams of H2O

Answers

The number of moles of Ca(OH)₂ produced from  from 49 grams of H₂O is 1.36 mole

How do i determine the number of mole of Ca(OH)₂ produced?

First, we shall determine the mole in 49 grams of water, H₂O. Details below:

Mass of H₂O = 49 grams Molar mass of H₂O = 18 g/mol Mole of H₂O =?

Mole = mass / molar mass

Mole of H₂O = 49 / 18

Mole of H₂O = 2.72 moles

Finally, we shall determine the number of mole of Ca(OH)₂ produced. This is illustrated below:

Ca + 2H₂O → Ca(OH)₂ + H₂

From the balanced equation above,

2 moles of H₂O reacted to produce  moles of Ca(OH)₂

Therefore,

2.72 mole of H₂O will react to produce = (2.72 × 1) / 2 = 1.36 mole of Ca(OH)₂

Thus, from the above calculation, we can conclude that the number of mole of Ca(OH)₂ produced is 1.36 mole

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b. if the volume of the reaction vessel was , what amount of (in moles) was formed during the first of the reaction?

Answers

The amount of Br² formed  is 0.0018 moles under the condition that the duration was 15 seconds and the reaction vessel was 1.50L.

The given balanced chemical equation for the reaction is

2HBr -> H2 + Br2

The concentration of HBr at t = 0 s is:

C(HBr) = n(HBr) / V

here

n(HBr) = number of moles of HBr

V = volume of the reaction vessel.

C(HBr) = (0.025 mol) / (1.50 L)

C(HBr) = 0.0167 M

The concentration of HBr at t = 15 s is:

C(HBr) = n(HBr) / V

here

n(HBr) = number of moles of HBr

V = volume of the reaction vessel.

C(HBr) = (0.0215 mol) / (1.50 L)

C(HBr) = 0.0143 M

The change in concentration of HBr over the first 15 seconds is

ΔC(HBr) = C(HBr)t=0 - C(HBr)t=15

ΔC(HBr) = 0.0167 M - 0.0143 M

ΔC(HBr) = 0.0024 M

Applying stoichiometry, it is  known that for every two moles of HBr that react, one mole of Br2 is formed.

Then, the number of moles of Br2 formed over the first 15 seconds is

n(Br2) = (ΔC(HBr) / 2) × V

n(Br2) = (0.0024 M / 2) × (1.50 L)

n(Br2) = 0.0018 mol

Hence, 0.0018 moles of Br² was formed during the first 15 seconds of the reaction in a 1.50L reaction vessel.

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The complete question is

If the volume of the reaction vessel in part (b) was 1.50L, what amount of Br2 (in moles) was formed during the first 15 seconds of the reaction? Consider the following reaction: 2HBr-> H2+Br2

sodium carbonate ( na2co3na2co3 ) is used to neutralize the sulfuric acid spill. how many kilograms of sodium carbonate must be added to neutralize 4.03×103 kgkg of sulfuric acid solution?

Answers

To neutralize the sulfuric acid spill, we need to use sodium carbonate, which will react with the acid to form water, carbon dioxide, and a salt.

The balanced chemical equation for this reaction is:

Na2CO3 + H2SO4 → 2NaHSO4 + H2O + CO2

From this equation, we can see that one mole of sodium carbonate (Na2CO3) reacts with one mole of sulfuric acid (H2SO4). We can use this relationship to calculate the amount of sodium carbonate needed to neutralize the given amount of sulfuric acid.

First, we need to convert the mass of sulfuric acid (4.03×10^3 kg) to moles. The molar mass of sulfuric acid is 98.08 g/mol, so:

4.03×10^3 kg × 1000 g/kg ÷ 98.08 g/mol = 41.10 × 10^3 mol H2SO4

Since each mole of H2SO4 requires one mole of Na2CO3 to neutralize it, we need the same number of moles of Na2CO3:

41.10 × 10^3 mol Na2CO3

Finally, we can convert the moles of Na2CO3 to kilograms, using the molar mass of Na2CO3 (105.99 g/mol):

41.10 × 10^3 mol × 105.99 g/mol ÷ 1000 g/kg = 4367 kg of Na2CO3

Therefore, we need to add 4367 kg of sodium carbonate to neutralize 4.03×10^3 kg of sulfuric acid solution.

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