Many metabolites are maintained at steady-state concentrations that are far from equilibrium. A comparison of K' and Q, the mass-action ratio, can determine whether a metabolic reaction is far from equilibrium.
The equation for this equilibrium is,
fructose 6-phosphate + ATP ⇄ fructose 1,6-bisphosphate + ADP
Calculate K' for this reaction at T=25.0°C
Δ G'=-14.2 kJ/mol
K'=
Calculate the mass-action ratio, Q, from the approximate physiological concentrations for rat heart tissue shown in the table.
Q=

Many Metabolites Are Maintained At Steady-state Concentrations That Are Far From Equilibrium. A Comparison

Answers

Answer 1

The reaction quotient (Q) is 0.032 while the equilibrium constant (K'eq) is 3.1 * 10^2 .  

What is the equilibrium constant?

We know that the equilibrium constant has to do with a value that shows the extent to which the reactants have been converted into products. If the equilibrium constant is high, then a lot of the reactants would be seen to be converted into products.

In this case we are first required to obtain the reaction quotient Q and this can be done by the use of the formula;

Q = [fructose 1,6-bisphosphate] [ADP]/[fructose 6-phosphate] [ ATP]

Q = [25] [1340]/[84] [12500]

Q = 33500/ 1050000

Q = 0.032

ΔG = -RTlnQ

ΔG = change in free energy

R = gas constant

T = temperature

Q = reaction quotient

We also know that;

ΔG' = -RTlnK'eq

-14.2 * 10^3 = -(8.314 * 298)lnK'eq

lnK'eq = -14.2 * 10^3/-(8.314 * 298)

lnK'eq = 5.73

K'eq = e^5.73

K'eq =  3.1 * 10^2

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Related Questions

air oxidations of aldehydes is used commercially to produce the corresponding carboxylic acids in very good yields for most compounds

Answers

When carboxylic acids deprotonate, a sulfonic anion only with general formula R-COO- is produced. This anion may be used to create a number of beneficial salts, including soaps.

What purposes serve carboxylic acids?

In the creation of polymers, bioplastics, coatings, adhesives, and medicinal medicines, carboxylic acids and their equivalents are employed. They can also be utilized as flavorings, food additives, solvents, and antimicrobials.

Is carboxylic acid bad for people?

The screening evaluation resulted in the conclusion that none of four chemicals with in carboxylic acid group are hazardous to either the environment or human health at the present exposure levels.

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Draw circle models to show how potassium iodide (KI) and hydrogen peroxide (H₂O₂) could
create water and oxygen (O₂). Label your circle models with molecular formulas and draw
box around the atoms that are left over.

Answers

To calculate the atoms of an element in a given molecule, we need to multiply stoichiometry by the number that is written on the foot of that element. Therefore, the balanced equation can be written as

H[tex]_2[/tex]O[tex]_2[/tex] + 2KI  [tex]\rightarrow[/tex]  I[tex]_2[/tex] + 2KOH

What is Balanced equation?

Balanced equation is the one in which the total number of atoms of a species on reactant side is equal to the total number of atoms on product side. The mass of the overall reaction should be conserved. There are so many types of chemical reaction reaction like combination reaction, displacement reaction.

The other characteristic of balanced reaction is that physical state should be written with each compound or molecule on reactant and product side. Physical state should be written in brackets. s means solid, l means liquid, g means gas. The balanced equation for the given reaction can be given as

H[tex]_2[/tex]O[tex]_2[/tex] + 2KI  [tex]\rightarrow[/tex]  I[tex]_2[/tex] + 2KOH

Therefore, the balanced equation can be written as

H[tex]_2[/tex]O[tex]_2[/tex] + 2KI  [tex]\rightarrow[/tex]  I[tex]_2[/tex] + 2KOH

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The two chemicals that were in the 1st unknown solution where...
Sodium Chloride
Potassium Chloride
Barium Chloride
Strontium Chloride
Copper Chloride
Lithium Chloride
Calcium Chloride

Answers

The first undiscovered remedy is barium chloride.

Option b is correct.

When tested in a metals lab using a flame, what color did the potassium solution burn?

Explanation and Response: The flame of potassium, often known as a lilac flame, is violet or light purple in color. Remember that different elements can create similar colors, thus flame tests are not always reliable.

What should I avoid with respect to cucl2 and LiCl?

Avoid contact with mucous membranes, eyes, and skin as copper(II) chloride is mildly poisonous. Body tissue irritant lithium chloride is used. In order to prevent trashcan fires, rinse the wooden splints before throwing them in the trash. Put on chemical-resistant gloves, an apron, splash goggles, and other protective gear.

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If the reaction of CO + NO2 <--> CO2 + NO which of following changes would result in formation of more products at equlibrium. a.removing Co from the reaction b. adding NO2 to the reaction c. increasing the pressure d. adding CO2 to the reaction

Answers

Adding CO to the reaction would result in formation of more products at equilibrium.

What is chemical equilibrium?

Chemical equilibrium, the state in which there is no net change in the amounts of reactants and products in the course of a reversible chemical reaction. A reversible chemical reaction is one in which products that is once formed react to form the original reactants. The types of balances are:

Stable equilibrium.Unstable equilibrium.Neutral equilibrium.

As additional reactants are added, the equilibrium shifts in order to produce more product. Adding more reactants shifts the equilibrium towards the products. Therefore the equilibrium shifts to the right.

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The complete question is follows:

If a star has an absolute magnitude of 10 and a temperature of 20,000 K, under which spectral class would the star be classified?

A

O

B

F

Answers

From the Herszsprung -Russel Diagram presented it is to be noted that if a star has an absolute magnitude of 10 and a temperature of 20,000 K, the spectral class under which the star would be classified is; O-Types. (Option B).

What are O-Types Stars?

These stars have a blue-white appearance and are characterized by strong emission lines in their spectra, which are caused by the high temperatures in their atmospheres.

The absolute magnitude of a star is not directly related to its spectral class, but it can be used to estimate the distance of a star from Earth. A star with an absolute magnitude of 10 would be relatively faint if it were close to Earth, but it could be much brighter if it were farther away.

Hence, if a star has an absolute magnitude of 10 and a temperature of 20,000 K, it would be classified as an O-type star.

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Lab: Making Sparklers

Fuel Fe, Al or Mg
Oxidizer KNO₃ KCLO₃
Colorant
Total Mass 1.0g

Answers

The mass of the materials used in making sparklers is determined by the mole ratio of the reactants in the chemical reactions that occur.

What are sparklers?

Sparklers are a kind of fireworks that do not explode but rather sparkle when they are lit.

The materials used in sparklers include materials such as:

Fuels such as iron, (Fe), aluminum (Al), or magnesium (Mg).

Oxidizers such as potassium nitrate( KNO₃) and potassium chlorate (KCLO₃).

Colorants that imbue color to the sparklers.

The reaction that occurs in sparklers is a chemical reaction. In sparklers, magnesium, aluminum, and iron each react with oxygen gas. The heat released from the reactions of the metal with oxygen causes the decomposition of the oxidizers such as potassium chlorate to potassium chloride and oxygen gas which is then used for further oxidation of the metals.

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Your lab has a 10 X TAE stock solution. You are asked to prepare 30.0 mL of a 1X working solution. How many milliliters of the 10 X stock solution do you need to mix with deionized water to make 30.0 mL of a 1X solution.
What volume of water is needed?
amount of TAE stock solution?

Answers

The volume of water needed is: 27 ml.Amount of TAE stock solution is: 3 ml.What is a stock solution?

A stock solution can best be described as a concentrated solution of known exact concentration that is diluted for future use in the laboratory. You can choose not to prepare a stock solution, but doing so can streamline your operations while saving significant time and resources in the process.

A 10X stock solution contains 10-fold concentrations of all solutes compared to the working solution, which is considered a 1X solution. Therefore, the 10x solution should be diluted 10x to get the final working solution.

C₁V₁ = C₂V₂

Where,

C₁ = 10 X

C₂ = 1 X

V₁ = Amount of TAE stock solution

V₂ = 30.0 mL

Now, substitute the values:

10 V₁ = 1 × 30.0V₁ = 30/10

V₁ = 3 ml

Hence, for a 30 ml 1 X solution; 3 ml of 10 X TAE solution and 27 ml of deionized water are mixed.

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Convert 9.8 x 1023 nanoliters to liters.

Round your answer to the proper number of sig figs.

Do not enter a unit, just the number.

Enter your answer using scientific notation.

x 10^ liters

Blank 1: Put only the coefficient.

Blank 2: Put only the exponent on the power of 10.

Answers

I am sorry I am not sure how to do it wish I could help you

For the majority of exercisers, adding excess protein or amino acid supplements to an adequate diet will stimulate muscle buildingA. TrueB. False

Answers

False , For the most of exercisers, supplementing an appropriate diet with extra protein or amino blends will not promote muscle growth.

What is an example of an amino acid?

The basic amino group (NH2), an acetoxy group (COOH), as well as an organic Aromatic rings (or carbonyl group) that really is specific to each amino acid make up an amino acid, an organic molecule. Alpha-amino [alpha-amino] carboxylic acid is referred to as an amino acid informally.

What amino acid is milk?

Due to their comprehensive amino acid profiles, milk and eggs are excellent for those looking to increase lean muscle mass and strength, reduce body fat, or hasten their rate of training recovery. Lysine, histidine, hcl, valine,

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What causes the colorful images seen in the art

Answers

Answer:

Explanation:

Color is caused by the way light bounces off of objects. Certain objects only reflect certain frequencies of light, which is what makes up color. For example, when the sun shines on earth (which, the sun shines white light, which is made of all colors), lets say it reflects off of an apple tree in a field. The tree's leaves will reflect green light because of the chloraphyll inside its cells. However, if the light reflects off of one of the apples on the tree, red light is seen because of the nutrients inside of the skin of the apple. In art, color is very important, so people have found ways to use paint (which is in all colors) to essentially mimic the effect that light has on the real world.

hope this helps!!! :3

Please Help!

In the image below, there are eight samples of different ELEMENTS. Each sample
is exactly 1 mol. Why are the masses of each sample different? The mass of 1
mole of each unique sample is different because the
of the
individual
are different.
O volume, atoms
O masses, atoms
O volumes, molecules
O masses, molecules

Answers

There is variation in the masses of 1.0-mole samples of different substances.

Does each substance's one mole possess the same mass?

To have enough of the particles for chemists to work with in the lab, a lot (6.02 1023) of them are needed. A mole of the any particle will not weigh or have the same mass as a mole of another particle, just as a dozen donuts, flowers, and eggs did not have the same mass or weight.

What causes a difference in molar mass?

Additionally, molar mass provides the mass of the a mole of a specific substance, which is the primary distinction between the two. Molecular weight, on the other hand, refers to a substance's molecule's mass. Although the terms "molar mass" and "molar mass units" are not the same

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consider the following element combinations. classify the bonds formed between each pair as ionic, polar covalent, or nonpolar covalent qualitatively based solely on each element's position on the periodic table. do not conduct calculations.

Answers

Using the elements' positions on the periodic table is a general tool to predict probable bond type.  The exact prediction of bond type can be made using electronegativity values.

Is s and F ionic or covalent?

The bond between S and F is polar covalent. The electronegativity of S is 2.58 while the electronegativity of F is 3.98. The electronegativity difference between the two atoms is 1.40. When the electronegativity difference is between 0.5 to 1.6, we can say that, the bond formed between the two atoms as polar covalent.

Which of the following elements would form a non polar covalent bond?

Cl and Cl. A non-polar covalent bond , where the two atoms sharing electrons have very similar electronegativities so that the electrons are equally shared.

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Holt Chemistry Textbook Pg. 014: #01-03
1. Convert each of the following masses to the units requested.
a. 0.765 g to kilograms
b. 1.34 g to milligrams
c. 34.2 mg to grams
d. 23 745 kg to milligrams (Hint: Use two conversion factors.)
2. Convert each of the following lengths to the units requested.
a. 17.3 m to centimeters
b. 2.56 m to kilometers
c. 567 dm to meters
d. 5.13 m to millimeters
3. Which of the following lengths is the shortest, and which is the longest:
1583 cm, 0.0128 km, 17 931 mm, and 14 m?

Answers

The given unit conversions for the mass and length are as follows:

a. 0.765 g = 0.000765 kg

b. 1.34 g = 1340

c. 34.2 mg = 0.0342 g

d. 23 745 kg = 2.3745 * 10⁹ mg

2. a. 17.3 m = 17300 cm

b. 2.56 m = 0.00256 km

c. 567 dm = 56.7 m

d. 5.13 m = 5130 m

3. The shortest length is 0.0128 km and the longest length is 1583 cm

What is the mass of an object?

The mass of an object is the amount of matter present in the substance.

The mass of objects is measured using a chemical balance, the unit of measurement is kilograms.

The various units can be interconverted.

To convert each of the following masses to the units requested, the conversion factor is used;

a. 0.765 g to kilograms

0.765 g = 0.765/ 1000

0.765 g = 0.000765 kg

b. 1.34 g to milligrams

1.34 g = 1.34 * 1000

1.34 g = 1340

c. 34.2 mg to grams

34.2 mg = 34.2 / 1000

34.2 mg = 0.0342 g

d. 23 745 kg to milligrams

23 745 kg = 23 745 * 10⁶

23 745 kg = 2.3745 * 10⁹ mg

2. To convert each of the following lengths to the units requested, the steps are as follows:

a. 17.3 m to centimeters

17.3 * 100 cm

17.3 m = 17300 cm

b. 2.56 m to kilometers

2.56 m = 2.56/ 1000

2.56 m = 0.00256 km

c. 567 dm to meters

567 dm = 567 / 10

567 dm = 56.7 m

d. 5.13 m to millimeters

5.13 m = 5.13 * 1000

5.13 m = 5130 m

3. Converting the following lengths to meters:

1583 cm = 15.83 m

0.0128 km = 12.8 m

17 931 mm = 17.931 m

14 m

The shortest length is 0.0128 km and the longest length is 1583 cm

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An acetylene tank is fully charged at 250 psi, the pressure gauge is not reading acetylene pressure, but actually reading acetone pressure. a. Trueb. False

Answers

False, Acetylene is extremely flammable when under pressure and ignites spontaneously in air when pressures are more than 15 psi. Since acetylene cylinders are devoid of oxygen, they pose a risk of asphyxiation when released.

How much pressure should an acetylene bottle be under while it is full?

The acetylene equipment's working pressure is crucial: A maximum acetylene pressure of 0.62 bar (9 psi) is permitted only with specially constructed equipment.

Is propane hotter than acetylene?

Even though acetylene is hotter, it emits less heat. The most common preheating method uses oxygen and propane. This is true. Propane has more heat that is readily available.

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acetylcholine (ach) is released ____
A. calcium diffuses into the sarcoplasm
B. the troponin-tropomyosin complex changes shape
B. cross-bridges form.

Answers

Acetylcholine is released from the vesicles and into the synaptic cleft upon stimulation of the presynaptic terminal, where it is free to connect with receptors.

The release of ACh by motor neurons?

The central nervous system's output neurons are known as motor neurons (MNs). Muscle contraction is a direct result of their activity. At the neuromuscular junction, MNs release acetylcholine (ACh), which was widely acknowledged by the 1940s.

What is acetylcholine's (ACh) function?

Acetylcholine (ACh) is an organic chemical that serves as a neurotransmitter in the bodies and brains of numerous animal species, including humans. It is an ester of acetic acid and choline, which is how its name was derived from its chemical composition.

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write the symbol or formula (including charges) for each ion.a) ammonium ionb) chromate ionc) tin (II) iond) nitrate ion

Answers

The symbol or formula:
a)  ammonium ion = [NH₄] ⁺

B) chromate ion = [CrO₄] ⁻²

c) tin (II) =Sn ⁺²

d) nitrate ion = [ NO₃] ⁻¹

How to represent the ions?

Ions are atoms or molecules that have a net electric charge due to the loss or gain of electrons. They can be represented by either a dot notation or a Lewis structure. In the dot notation, the number of valence electrons around the atom is indicated with dots located around the symbol representing the element. If the atom has a negative charge, a superscript minus sign is placed next to the element symbol. If the atom has a positive charge, a superscript plus sign is placed next to the symbol. In the Lewis structure, a line is used to represent an electron pair and a pair of dots is used to represent a single electron. The element symbol is placed in the center and the surrounding electrons are drawn in the shape of a circle around it.

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Based on your knowledge of the compounds and the visible light spectra, label the
compounds in increasing energy order of energy of the light that was emitted.
Lowest Energy
Lithium
Copper
Highest Energy
Calcium
Potassium
Barium
Sodium
Strontium

Answers

Lowest Energy: Lithium, Sodium, Strontium, Potassium, Copper, Calcium.
Highest Energy: Barium.

What is Energy?

Energy is the capacity to cause change. It is the ability of a system to do work, and can take a variety of forms, such as kinetic, potential, electrical, chemical, thermal, and nuclear. Energy can be transformed from one form to another, but the total amount of energy in the universe is constant. Energy powers all living organisms, and is the driving force behind physical and chemical changes. Examples of energy transformations include light energy converted to heat energy, and chemical energy in food converted to mechanical energy in muscles. Through the use of renewable sources of energy, such as solar, wind and water, humans are able to use energy sustainably and reduce their impact on the environment.

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Which of the following statements best describes the type of bond formed
between sodium and chlorine in sodium chloride?
0-a
Na
P:11
N:12
00
Na
66
00
Cl
P:17
N:18
00
00
Sodium Chloride
Sodium and chlorine form a ionic bond because they are sharing their valence
electrons.
Sodium and chlorine form an lonic bond because chlorine transfers its seven
valence electrons to sodium.
4
Sodium and chlorine form an ionic bond because chlorine takes sodium's only
valence electron

Answers

Positively charged sodium ions (Na+) and negative ion ions (Cl ) combine to generate sodium chloride (NaCl). Chemical bond is the form of bonding that exists between these ions.

What is the purpose of sodium chloride?

As an electrolyte particularly, sodium chloride is used to assist reduce heat cramps brought on by excessive perspiration. The production of a typical isotonic solution of sodium chloride also uses this medication. There is no need for a license to get this medication.

Why is sodium chloride given to patients?

To replace salt and water that have lost from your body as a result of certain conditions, sodium chloride 23.4% injection is employed (eg, hyponatremia or low salt syndrome). Furthermore, it is added to IV fluids that contain carbohydrates and parenteral nutrition total (TPN).

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Which of the following best explains the entropy of an isolated system as it is taken through an irreversible thermodynamic process?

Answers

The entropy increases because the system becomes more disorderly.

What is thermodynamic process?

A system goes through several quasi-static states to reach a final state f, which is represented by a pressure , a volume , and a temperature , starting from an initial state  that is described by a pressure pi, a volume , and a temperature . Energy can be transported from or into the system during this process, either by the system itself or on it. Increasing gas pressure while keeping temperature constant is an illustration of a thermodynamic process. Examples of thermodynamic processes are discussed in detail in the section that follows since they are crucial to the design of heat engines.

Hence, The entropy increases because the system becomes more disorderly.

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The laboratory assistant prepared two solutions of sodium carbonate of different concentrations.
If mix 100 g of the first solution and 150 g of the second solution (mixture 1), then the effect of excess of sulfuric acid on the resulting mixture will lead to the release of 5.82 L of gas.
If mix 150 g of the first solution and 100 g of the second solution (mixture 2), in a reaction with excess sulfuric acid will release 4.70 L of gas.
1. What is the mass fraction of sodium carbonate in mixtures 1 and 2?
2. Determine the mass fraction of sodium sulfate in the solution that will be formed when an equimolar amount of a 20% sulfuric acid solution reacts with a sodium carbonate solution.
3. Give the reaction equation of the interaction between the strontium chloride solution and: a) the original solution of sodium carbonate; b) the solution obtained in the reaction between sodium carbonate and sulfuric acid.

Answers

1. The mass fraction of sodium carbonate in solution A and solution B are  0.05 and 0.15 respectively.

2. The mass fraction of sodium sulfate is 0.696

3. The equations of the interaction between the strontium chloride and the given solutions are:

SrCl₂ + Na₂CO₃ ----> 2 NaCl (aq) + SrCO₃SrCl₂ + Na₂SO₄ ---> SrSO₄ + NaCl

What mass of sodium carbonate will release 5.82 L and 4.70 L of carbon dioxide gas when reacted with sulfuric acid?

The mass of sodium carbonate that will release 5.82 L and 4.70 L of carbon dioxide gas when reacted with sulfuric acid is determined from the equation of reaction below:

Na₂CO₃ + H₂SO₄ ---> Na₂SO₄ + H₂O + CO₂

1 mole or 106 g of Na₂CO₃ produces 1 mole or 22.4 L of CO₂

5.82 L of CO₂ will be produced by 5.82/22.4 * 106 g = 27.54 g

4.70 L of CO₂ will be produced by 4.70/22.4 * 106 g = 22.24 g

The mass fractions are calculated as follows:

Let the mass fraction of sodium carbonate in solution A and solution B be x and y respectively

x * 100 g + y * 150 = 27.54 g

100x + 150 y = 27.54 g --- (1)

x + 1.5 y = 0.2754

x * 150 + y * 100 = 22.24 g

150x + 100y = 22.24 ---- (2)

1.5x + y = 0.2224

solving for y in Eqn 1;

x = 0.2754 - 1.5y --- (3)

substitute (3) in (2)

1.5(0.2754 - 1.5y) + y = 0.2224

0.4131 - 2.25y + y = 0.2224

-1.25y = -0.1907

y = 0.15

x = 0.2754 - 1.50 * 0.15

x = 0.05

2. The molarity of 20% (W/W) solution of sulphuric acid is 2.55 M.

From the equation of the reaction, 1 mole sulfuric acid solution reacts with 1 mole sodium carbonate solution to form 1 mole sodium sulfate

Molar mass of sodium sulfate = 142 g/mol

Molar mass of H₂O = 18 g/mol

Molar mass of CO₂ = 44 g/mol

Total mass = 204 g

Mass fraction of sodium sulfate = 142/204

Mass fraction of sodium sulfate = 0.696

3. The equation of the interaction between the strontium chloride solution and the original solution of sodium carbonate is:

SrCl₂ + Na₂CO₃ ----> 2 NaCl (aq) + SrCO₃

The equation of the interaction between the strontium chloride solution and the solution obtained in the reaction between sodium carbonate and sulfuric acid is:

SrCl₂ + Na₂SO₄ ---> SrSO₄ + NaCl

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1. Which of the following is the best example of a qualitative research question?
What factors predict higher leadership skills?
What aspects of the leadership retreat were high quality?
Does the leadership retreat improve leadership skills?
What meaning do individuals make from a leadership retreat?

Answers

"The goal of this study is to compare the grades of students who attend office hours and those who do not," is an example of a qualitative research question.

What is qualitative research question ?

In order to examine or characterize occurrences rather than offer a clean nomothetic explanation, qualitative research questions are frequently more wide and imprecisely phrased. Although many of them do, they may just include one concept. Example: ''What is it like to grow up in a rural setting with only one parent?''

What is quantitative research question ?

Typically, a study's or an industry report's quantitative research questions serve as the introduction. It is crucial that the research questions employed in quantitative business research enable respondents to provide clear responses. Example: ''How many texts do you send per day?''

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the bond enthalpy of the bond in the amide group of proteins can be treated as an average of and bonds. calculate the maximum wavelength of light needed to break the amide bond. be sure your answer has the correct number of significant digits.

Answers

The maximum wavelength of light needed to break the amide bond is 268 nm



First' permit's calculate the average bond power:
(276 + 615)/2 = 445.5 kJ/mol

with the aid of Avogadro's no 1 mol = 6.02x10²³ molecule, then the electricity important to break the amide bond in 1 molecule is:

E = 445.5/6.02x10²³ = 7.4x10⁻²² kJ = 7.4x10⁻¹⁹ J

So, the wavelength of light (λ) can be calculated by means of:

E= h*c/λ

wherein h is the Planck's constant ent (6.626x10⁻³⁴ J.s), and c is the mild velocity (three.0x10⁸ m/s).

7.4x10⁻¹⁹ = 6.626x10⁻³⁴ * three.0x10⁸/λ

λ = 2.68x10⁻⁷ m

λ = 268 nm

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Which two elements are in the same period?
Onitrogen and bismuth
O silver and calcium
fluorine and chlorine
O Potassium and Bromine

Answers

Answer:

Explanation:

O Potassium and Bromine are in the same period.

The periodic table is a chart of all the known elements arranged according to their atomic structure. Elements in the same period are in the same row of the periodic table and have similar chemical properties because they have the same number of electron shells.

O Nitrogen and Bismuth are not in the same period. Nitrogen is in period 2 and bismuth is in period 6.

O Silver and Calcium are not in the same period. Silver is in period 5 and calcium is in period 4.

O Fluorine and Chlorine are in the same period. They are both in period 2.

structure of selective and nonselective dicopper (ii) sites in cumfi for methane oxidation to methanol

Answers

The only-step valorization of natural gas stays a task. Methane conversion to methanol thru chemical looping over copper-containing zeolites is a promising route, and CuMFI is most of the earliest efficaciously implemented.

But, the structure of the lively web sites in CuMFI, in addition to the effect of copper loading and Si/Al ratio on the copper speciation, are but to be understood. We observed that for CuMFI, the Cu/Al ratio determines the selectivity of methane conversion by way of governing the shape of the lively dicopper sites. At a Cu/Al ratio beneath 0.3, copper-containing MFI substances host dimeric centers with a Cu–Cu separation of two.nine Å and a UV/vis absorption band at 27 two hundred cm–1 able to selective oxidation of methane to methanol in a wide temperature range (450–550 k). A higher Cu/Al ratio results in the formation of mono-μ-oxo dicopper sites with Cu–Cu = three.2 Å, which exhibit a feature band at 21 900 cm–1 and react with methane at lower temperatures (<450 k), yielding overoxidation products. identifying differences in the structure of selective and nonselective copper sites will aid inside the layout of higher-performing substances.

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Which of the following exhibits sp3 hybridization? Select the correct answer below: A. BH3 B. CH2O C. Ccl4
D. all of the above

Answers

The electron pairs in (C.)Ccl4 are arranged in a tetrahedral pattern around the carbon, necessitating sp3 hybridization. The four bonds between carbon and chlorine are formed by four sp3 hybrid orbitals.

Describe SP3 hybridization using an example.

One's' orbital and three 'p' orbitals of equal energy are mixed in this process to create a new hybrid orbital known as sp3. Tetrahedral symmetry and a combination of s and p orbitals are preserved at 109.280. Ethane is an example of sp3 hybridization (C2H6).

What was the purpose of hybridization?

The hybridization theory was created by chemist Linus Pauling in 1931 to use atomic orbitals to describe the structure of basic molecules like methane (CH4).

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(Atomic masses used are C = 12.0 g mol–1, O = 16.0 g mol–1, H = 1.01 g mol–1, Cu = 63.5 g mol–1,)

1. How many moles are there in 5.0 g of methanol (CH3OH)?
How many molecules of CuCO3 would weigh 9.0 g?
How many moles would 3.0 g of cyclohexane (C6H12) contain?
How much would 4.00 moles of benzene weigh?
What is the mass of 1000 atoms of calcium?

Answers

Question 1

The formula mass of methanol is [tex]12.0+3(1.01)+16.0+1.01=32.04[/tex] g/mol.

Therefore, in 5.0 grams of methanol, there are [tex]5.0/32.04=\boxed{0.16}[/tex] moles.

Question 2

The formula mass of copper(II) carbonate is [tex]63.5+12.0+3(16.0)=123.5[/tex] g/mol.

This means that in 9.0 grams of copper(II) carbonate, there are [tex]9.0/123.5=0.072874493927126[/tex] moles.

Using Avogradro's number, there are [tex](0.072874493927126)(6.022 \times 10^{23})=\boxed{4.4 \times 10^{22}}[/tex] molecules.

Question 3

The formula mass of cyclohexane is [tex]12.0(6)+1.01(12)=84.12[/tex] g/mol.

So, 3.0 grams of cyclohexane is the same as [tex]3.0/84.12=\boxed{0.036}[/tex] moles.

Question 4

The formula mass of benzene is [tex]12.0(6)+1.01(6)=78.06[/tex] g/mol.

This means that 4.00 moles of benzene has a mass of [tex](78.06)(4.00)=\boxed{312}[/tex] grams.

Question 5

1000 atoms of calcium is the same as [tex]\frac{1.000}{6.022 \times 10^{23}}[/tex] moles.

This is equal to [tex]\frac{1000}{6.022 \times 10^{23}} \cdot 40.078=\boxed{6.7 \times 10^{-20}}[/tex] grams.

The OH⁻ concentration in an aqueous solution at 25 °C is 9.7 × 10⁻³. What is [H⁺]?

Answers

The pH of the given solution is 11.98. Thus the concentration of H+ ions is 1.0 × 10⁻¹² M.

What is pH ?

pH of a solution is the negative logarithm of its H+ ions concentration. Similarly pOH is the negative logarithm of its OH- ion concentration. The sum of pH and pOH of an aqueous solution is always 14.

Given that [OH-] = 9.7 × 10⁻³ M

pOH = - log (9.7 × 10⁻³ M) = 2.01.

pH = 14 - POH = 14 -2.01 = 11.98.

From the pH value, the H+ concentration can be calculated as follows:

pH = -log [H+]

[H+] = antilog (-pH)

       = 1.04 × 10⁻¹² M

Therefore, the H+ ion concentration of the solution is 1.04 × 10⁻¹² M.

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A chemist measures the temperature of a solution in °C. The measurement is denoted C, and is normally distributed with mean 40°C and standard deviation 1°C. The measurement is 1.8C32. What is the distribution of F? a) F N(104,3.24) b) F N(104,1.80) c) F N(40,3.24) d) F N(40,1.80)

Answers

Measurement of temperature by Chemist involving Mean and SD:

The distribution of F is (a) F = N(104, 3.24).

What is Mean and Standard deviation?

A  mean is calculated by dividing the total number of values by the sum of all the values. The term "average" is frequently used to describe this measure of central tendency.

In statistics, the measurement of variability known as the standard deviation (SD) is frequently utilized. It demonstrates how different things are from the norm (mean). While a high SD shows that the data are dispersed throughout a wide range of values, a low SD suggests that the data points tend to be close to the mean.

Calculation:

As,E[ax+b]=aE(x)+b

Var(ax+b)=a∧2(Var(x))

Now, F=1.8C+32

E(F)=1.8×E(C)+32=1.8×40+32

E(F)=104

Var(F)=1.82×1=3.24

std_dev(F)=√(3.24)=1.8

So, F ≈ N(104,3.24).

Measurement of temperature by Chemist involving Mean and SD:

The distribution of F is (a) F = N(104, 3.24).

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How much energy is required to heat 100g of ice at -25°C to water at 75°C?

Answers

The heat energy required to change 100g of ice at -25°C to water at 75°C is 45.36KJ

What is specific latent heat of fusion?

Specific latent heat if fusion of a substance is the quantity of heat required to covert unit mass of the substance at melting point to its liquid form without change in temperature. The specific latent heat of fusion of ice is 336000J/kg. The heat required is given as H= ml

Specific heat capacity of a substance is the heat required to raise the temperature of a unit mass substance by 1°C. The specific heat capacity of water is 4200J/kg/°C

Therefore the ice will change to water and it's temperature will now increase. This means that the heat required to change ice if -25°C to water of 75°c is H = ml + mc∆T

H = (0.1×33600)+0.1×4200×75-(-25)

H= 3360+42000

H= 45360J = 45.36KJ

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TRUE/FALSE. carbon-14 is constantly being produced in the upper atmosphere, and the amount is in equilibrium. as long as an organism is alive, it keeps its carbon isotopes in balance with the atmosphere, but at soon as it dies, it stops taking up new 14c, and so the geologic clock starts.

Answers

True. The amount of carbon-14 remains constant in equilibrium and is produced in the upper atmosphere.

Carbon-14 is a long-lived radioactive carbon isotope formed by the collision of neutrons and nitrogen atoms in the atmosphere when cosmic radiation occurs.

Organisms during their lifetime will absorb carbon-14, carbon-14 is a carbon that easily bonds with other atoms to help process reactions in the body. As in plants, carbon-14 acts as carbon dioxide, which is the raw material for photosynthesis. Carbon-14 is also decaying and the amount will be replaced when living things breathe and eat. The process of absorption of carbon-14 in living things will stop when these living things die, and the amount of carbon-14 in their bodies will decrease.

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