In substitution reactions, (CH3)3C-I reacts at the same rate with Br- and Cl- even though Br- is a more reactive nucleophile than Cl-. Why?A. (CH3)3C-Br reacts by SN1 mechanism whose rate is independent of nucleophile reactivity. B. (CH3)3C-Br reacts by SN2 mechanism and therefore all nucleophiles react at the same rate regardless of their reactivity. C. The t-butyl carbocation is so reactive, the measurable rate of it's reaction with different nucleophiles is imperceptible. D. The t-butyl group sterically hinders nucleophiles, making different nucleophiles appear to react at the same rate.

Answers

Answer 1

Answer:

A. (CH3)3C-I reacts by SN1 mechanism whose rate is independent of nucleophile reactivity.

Explanation:

We must recall that (CH3)3C-I is a tertiary alkyl halide. Tertiary alkyl halides preferentially undergo substitution reaction via SN1 mechanism.

In SN1 mechanism, the rate of reaction depends solely on the concentration of the alkyl halide (unimolecular mechanism) and is independent of the concentration of the nucleophile. As a result of this, both Br^- and Cl^- react at the same rate.


Related Questions

At what temperature does water freeze in Celsius

Answers

Answer:

32°c

Explanation:

Because in F it would be 0°f

PLZ HELP PLZ
NO WRONG ANSWERS

Answers

The answer to the question is D

Answer:

it is C

Explanation:

because Potassium iodide (KI) is an ionic compound which is made of the following ions: K+I−

Consider a monoprotic weak acid ( HAHA ) that is titrated with a strong base. What is the relationship between the strength of the weak acid and the pH of the solution at the equivalence point?A. There is no relationship between the strength of the acid and the pH at the equivalence point. B. The pH at the equivalence point is always 7 in an acid base titration. C. The weaker the acid, the higher the pH at the equivalence point. D. The stronger the acid, the higher the pH at the equivalence point.

Answers

Answer:

C. The weaker the acid, the higher the pH at the equivalence point.

Explanation:

In a titration, a solution which concentration is known is added gradually to another solution of unknown concentration, until the chemical reaction between the two solutions is complete.

The pH in the equivalence point is equal to 7.00 only if both the acid and base are strong. When one or both reactants are weak, the pH in the equivalence point is not equal to 7.00.

In the equivalence point, the amount of strong base (like NaOH) added is just enough to react stoichiometrically with the weak acid. The resulting solution "only" contains the conjugated base A⁻. A solution of Na⁺A⁻ is the solution of a weak base:

A⁻ + H₂O ⇄ HA + OH⁻              Kb=Kw/Ka

In the equivalence point of the titration of a weak base with a strong base, the pH is higher than 7.00 because at this point the acid is transformed into its conjugate base.

Is iron man made or natural

Answers

Answer:

Iron is natural. Paper is man-made

Explanation:

Answer:

iron

Explanation:

An element has 4 protons, 5 neutrons, and 4 electrons. Choose the correct answer. *

Answers

Answer:

4

Explanation:

[tex]\int\limits^a_b {x} \, dwetjernjtnx[/tex]

Look at the picture below. Name the isotope.

Answers

Answer:

carbon-13

Explanation:

how could you tell what element it is if only a model was present?​

Answers

You can look at the number of valence electrons and look at the size of the molecule itself to determine which element in this certain group is shown on the model.
the number of valence electrons and the number of molecules

chlorine monobromide ionic or molecular

Answers

Chlorine mono bromide ionic

Please i really need help it's due today

Answers

Answer:

there is your answer hope it helped :3

Calculate the amount of heat (in J) needed to raise the temperature of 3.50 g of water from 22.4oC to 98.8oC.

Answers

Answer:

76.4oC or 169.52oF

Explanation:

That's the amount of heat needed

The heat capacity is the heat amount lost or gained by the object in a thermodynamic system. The heat needed to raise the temperature of the water is 1117.7 Joules.

What is heat capacity?

Heat capacity (q) is the heat an object loses or gains to alter the temperature of the thermodynamic system by a difference of a degree Celsius. The heat capacity is given by the mass, specific heat capacity, and temperature change.

Given,

Mass of water (m) = 3.50 gm

Specific heat (c) = 4.18 J/ g°C

The temperature change (∆T) = T₂ - T₁

= 98.8 °C - 22.4 °C

= 76.4 °C

The heat capacity is given as,

q = mc∆T

Substituting values above:

q = 3.50 gm × 4.18 J/ g °C × 76.4 °C

q = 1117.7 J

Therefore, 3.50 g of water has a heat capacity of 1117.7 Joules.

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The sample of 15.0 g of KCl is dissolved into a solution with a total volume of 250.0 mL. What is the molarity of KCl in the solution?

Answers

Answer:

0.805 M.

Explanation:

Hello!

In this case, since the molarity of a solution is computing by dividing the moles of solute over the volume of solution in liters (M=n/V), for 15.0 g of potassium chloride (74.55 g/mol) we compute the corresponding moles:

[tex]n=15.0gKCl*\frac{1molKCl}{74.55gKCl}=0.201molKCl[/tex]

Next, since the volume is 0.2500 in liters, the molarity turns out:

[tex]M=\frac{0.201mol}{0.2500L} \\\\M=0.805M[/tex]

Best regards!

a solution is dilute when?

A. it has a lot of solute
B. has little solvent
C. it has a lot of solvent
D. has maximum solute

Answers

The answer to your equation is C. Hope this Helps!
C. It has more solvent
To dilute a solution means to add more solvent without the addition of more solute

Calculate the pH of a buffer solution when 32.0 mL of a 0.25 M H2CO3 is mixed with 20.0 mL of a 0.15 M NaHCO3​

Answers

pH of buffer solution : 4.32

Further explanation

A buffer solution is a solution that can maintain a good pH value due to the addition of a little acid or a little base or dilution.

The buffer solution can be acidic or basic

Acid buffer solutions consist of weak acids(H₂CO₃) and their salts.(NaHCO₃)

mol H₂CO₃

[tex]\tt 0.032\times 0.25=0.008[/tex]

mol NaHCO₃

[tex]\tt 0.02\times 0.15=0.003[/tex]

[tex]\tt [H^+]=Ka\dfrac{mole~weak~acid}{mole~salt}\\\\(H^+]=1.8\times 10^{-5}\dfrac{0.008}{0.003}=4.8\times 10^{-5}\\\\pH=5-log~4.8=4.32[/tex]

Liquid hexane CH3CH24CH3 will react with gaseous oxygen O2 to produce gaseous carbon dioxide CO2 and gaseous water H2O. Suppose 5.2 g of hexane is mixed with 33.0 g of oxygen. Calculate the minimum mass of hexane that could be left over by the chemical reaction. Be sure your answer has the correct number of significant digits.

Answers

Answer:

The leftover is 15 g of oxygen rather than liquid hexane as the fuel limits the reaction.

Explanation:

Hello!

In this case, since the described combustion reaction is:

[tex]C_6H_{14}(l)+\frac{19}{2} O_2(g)\rightarrow 6CO_2(g)+7H_2O(g)[/tex]

Thus, since 5.2 g of hexane (86.2 g/mol) is reacted with 33.0 g of oxygen (32.0 g/mol) we can compute the mass of hexane that was actually consumed via stoichiometry with oxygen (1:19/2 mole ratio):

[tex]m_{C_6H_{14}}^{consumed \ by\ O_2}=33.0gO_2*\frac{1molO_2}{32.0gO_2}*\frac{1molC_6H_{14}}{\frac{19}{2}gO_2 } *\frac{86.2gC_6H_{14}}{1molC_6H_{14}} \\\\m_{C_6H_{14}}^{consumed \ by\ O_2}=9.36gC_6H_{14}[/tex]

It is proved then than the hexane won't have any leftover but oxygen does, as shown below:

[tex]m_{O_2}^{consumed \ by\ C_6H_{14}}=5.2gC_6H_{14}*\frac{1molC_6H_{14}}{86.2gC_6H_{14}} *\frac{\frac{19}{2}molO_2 }{1molC_6H_{14}} *\frac{32.0gO_2}{1molO_2} \\\\m_{O_2}^{consumed \ by\ C_6H_{14}}=18g[/tex]

It means the leftover of oxygen is:

[tex]m_{O_2}^{leftover}=33g-18g\\\\m_{O_2}^{leftover}=15g[/tex]

Regards!

A gas has a volume of 6.00 liters at a temperature of 27° C and a pressure of 1,00 atm. What is the volume of the gas, in liters, at a temperature of 327°C and a
pressure of 3.00 atm?

Answers

We are given:

P1 = 1 atm                 P2 = 3 atm

T1 = 300 K               T2 = 600 K

V1 = 6 L                    V2 = v L

Finding the final Volume:

From the ideal gas equation:

PV = nRT

since in the given scenario, the universal gas constant (R) and number of moles(n) are constant

So, for both the cases, the value of n*R will be a constant k

Hence, we can write that:

PV / T = k        [where k is a constant]

Since the constant 'k' is the same for both the cases, we can write that:

P1V1 / T1 = P2V2 / T2

replacing the variables

1 * 6 / 300 = 3 * v / 600

1/50 = v / 200

v = 200/50

v = 4 L

Therefore, the volume of the gas at 600K and 3 atm will have a volume of 4 L

the difference in energy between the n=1 and n=2 energy levels in a hydrogen atom is 1.64x10^-18 J. what happens when an electron in a hydrogen atom transitions from n=2 to n=1?

Answers

Answer:

It emits 1.64 x 10⁻¹⁸J of energy

Explanation:

The n = 1 is a lower quantum level compared to n = 2.

When a hydrogen atom moves from a higher level to a lower one, it simply emits the energy difference between the two levels.

If a hydrogen atom moves from a lower energy level to a higher one such as from 1 to 2, they absorb the energy difference to attain the new excited state. So, for an electron in the hydrogen atom to move from a higher energy level to a lower one, it must emit 1.64 x 10⁻¹⁸J of energy.

How does evidence of chemical
reactions indicate that new substances
with different properties are formed?

Answers

Answer:

Changes in Properties Changes in properties result when new substances form. For instance, gas production, formation of a precipitate, and a color change are all possible evidence that a chemical reaction has taken place. ... Change in Color A color change can signal that a new substance has formed.

Explanation:

The chemical reaction indicate the formation of new substance by change in nature of original compound and shows chemical changes in the reaction.

What is chemical reaction?

Chemical reaction is defined as  process in which two or more molecules collide with the proper orientation and enough force to produce a new product.

It is also defined as a procedure in which one or more compounds, known as reactants, are changed into one or more distinct substances, known as products.

There are mainly seven types of reaction.

Synthesis reactionDecomposition reactionDisplacement reactionDouble displacement reactionCombustion reactionRedox reactionAcid-Base reaction

Thus, the chemical reaction indicate the formation of new substance by change in nature of original compound and shows chemical changes in the reaction.

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which type of energy change causes a
leaf to grow

Answers

Electromagnetic energy

Explanation:

Growth is one of the characteristics of living things. It refers to the increase of an organism. A leaf is part of a plant, which is a photosynthetic organism i.e. an organism capable of producing its own food using energy from sunlight. Light energy is a part of the ELECTROMAGNETIC ENERGY.

This light energy is used to synthesize glucose (food) via photosynthesis. The glucose, which stores chemical energy in its bond is then broken down to yield ATP used for growth. Hence, the transformation of electromagnetic energy to light energy is how a leaf grow.

How do you think energy flows in and out of the earth's atmosphere ?

Answers

As air is heated by surfaces or solar radiation, it triggers convection currents, sometimes called thermals. Other absorbed solar radiation is emitted from surfaces as infrared radiation and then eventually moves back out into space via the atmosphere.

Once a rate law is determined from trials with concentration and rate data, what is the minimum number of additional trials that will have to be done to gather sufficient initial rates data to be able to find the rate constant for the reaction? a. 0b. 1c. 2d. 3

Answers

Answer:

A is probably ur answer

Explanation:

but if I'm wrong My bad and at least I tried

If 49.0 g of O2 is mixed with 49.0 g of H2 and the mixture is ignited, what is the maximum mass of water that may be produced?

Answers

Answer:

[tex]55.2gH_2O[/tex]

Explanation:

Hello!

In this case, since the reaction between hydrogen and oxygen to produce water is:

[tex]2H_2+O_2\rightarrow 2H_2O[/tex]

When equal masses of each reactant go in contact to carry out the reaction, we can identify the maximum mass of yielded water as the fewest mass yielded by each reactant, just as shown below:

[tex]m_{water}^{by\ H_2}=49.0gH_2*\frac{1molH_2}{2.02gH_2}*\frac{2molH_2O}{2molH_2}*\frac{18.02gH_2O}{1molH_2O} =170gH_2O\\\\m_{water}^{by\ O_2}=49.0gO_2*\frac{1molO_2}{32.0gO_2}*\frac{2molH_2O}{1molO_2}*\frac{18.02gH_2O}{1molH_2O} =55.2gH_2O[/tex]

Thus, since hydrogen yields more water than real, we limit the maximum mass of water to those 55.2 g yielded by oxygen as hydrogen would be in excess.

Best regards!

A river and all of its tributaries make up a(n) _________.

Answers

Answer:

A river and its tributaries make up a watershed (aka river system or drainage basin)

Pls mark me as brainliest

Answer:

river system

Explanation:

a river and all its tributaries make up a river system

According to the following reaction, how many moles of hydrobromic acid are necessary to form 0.274 moles bromine?
hydrobromic acid (aq) —>hydrogen (g) + bromine (1)
moles hydrobromic acid

Answers

Answer:

0.548 moles of HBr are required

Explanation:

Given data:

Number of moles of  hydrobromic acid = ?

Moles of bromine formed = 0.274 mol

Solution:

Chemical equation:

2HBr     →   H₂  + Br₂

Now we will compare the moles of HBr with Br₂.

               Br₂           :           HBr

               1               :            2

               0.274       :           2×0.274=0.548

Thus, 0.548 moles of HBr are required.

A solution containing molecular nonpolar molecules will conduct electricity
True or False?

Answers

Answer:

true

Explanation:

It is true, like an electrolyte is any salt or ionizable molecule that, when dissolved in solution, will give that solution the ability to conduct electricity. This is because when a salt dissolves, its dissociated ions can move freely in solution, allowing a charge to flow.

I hope I helped

I need help, due in 30 mins

Answers

Answer:

1.Reaction rate is how fast a chemical reaction proceeds.

2.Nature of the reaction, Pressure factor

, Solvent, Catalyst and inhibitors.

3.Physical change is a temporary change. A chemical change is a permanent change. A Physical change affects only physical properties i.e. shape, size, etc.

4. One example of the effect of temperature is the use of lightsticks or glowsticks.

5.When the particle size of a fixed mass of a solid reactant becomes smaller, the total exposed surface area becomes larger, the rate of reaction increases. an example could be ice and water when the atoms are stuck together a solid but all over the place as a liquid.

6. Sometimes a reaction depends on catalysts to do their job. In that case, changing the concentration of the catalyst can speed up or slow down the reaction. For example, enzymes speed up biological reactions, and their concentration affects the rate of reaction.

7.A catalyst is a chemical substance that affects the rate of a chemical reaction by altering the activation energy required for the reaction to proceed. For example, a catalyst could cause a reaction between reactants to happen at a faster rate or at a lower temperature than would be possible without the catalyst.

Explanation:

I hope this helps have a great day! :)

Name something that has zero thermal energy.

Answers

Absolute zero is the point at which the fundamental particles of nature have minimal vibrational motion, retaining only quantum mechanical, zero-point energy-induced particle motion.
Hope this helped! c:

Answer:

When all molecules in a system stop moving completely, there is zero thermal energy

Explanation:

It is impossible to reach though

Weathering is the process that takes place as rocks, and other parts of the geosphere, are??

Answers

Breaking down that’s why they make land slides

a sample of lead had a mass of 150 g. The molar mass of lead is 207.19 g. How many moles of lead does the sample contain?

Answers

Answer:

Explanation:

no of moles=given mass/molar mass

no of moles=150 g/207.19

no of moles=0.72

Answer:

We will use dimensional analysis to answer this question.

[tex]150 g * \frac{1 g}{207.19 mol} = 0.724 mol[/tex]

The answer is 0.724 mol.

an ionic bond is a force of _____between anions and ______when combined make _____compounds that are electrically_____

Answers

Ionic bonds are formed between cations and anions. A cation is formed when a metal ion loses a valence electron while an anion is formed when a non-metal gains a valence electron. They both achieve a more stable electronic configuration through this exchange.


an ionic bond forms when atoms blank electrons

Answers

Answer:

An ionic bond forms when atoms transfer electrons.

Explanation:

Ionic bonds are formed when atoms transfer electrons. (In contrast, covalent bonds are formed when atoms share electrons.)

There's a distinction between the two: when two atoms react to form an ionic bond, one atom would completely lose one electron, while the other would completely gain that electron. The atom that loses the electron becomes a positively-charged ion called a cation, whereas the atom that gains the electron becomes a negatively-charged ion called an anion.

For example, consider the reaction between a sodium [tex]\rm Na[/tex] atom and a chlorine [tex]\rm Cl[/tex] atom: [tex]\rm Na + Cl \to NaCl[/tex].

When the sodium atom and the chlorine atom encounter, the sodium atom would lose one electron to form a positively-charged sodium ion, [tex]\rm Na^{+}[/tex]. The chlorine atom would gain that electron to form a negatively-charged chlorine ion [tex]\rm Cl^{-}[/tex].

These two ions will readily attract each other because of the opposite electrostatic charges on them. This electrostatic attraction (between two ions of opposite charges) is an ionic bond.

Overall, it would appear as if the sodium [tex]\rm Na[/tex] atom transferred an electron to the chlorine [tex]\rm Cl[/tex] atom to form an ionic bond.

In contrast, when two atoms react to form a covalent bond, they share electrons without giving any away completely. Therefore, it is possible to break certain covalent bonds apart (using a beam of laser, for example) and obtain neutral atoms.

On the other hand, when an ionic bond was broken, the result would be two charged ions- not necessarily two neutral atoms. The electron transfer could not be reversed by simply breaking the bond.

For example, when table salt [tex]\rm NaCl[/tex] is melted (at a very high temperature,) the ionic bond between the sodium ions and chloride ions would (mostly) be broken. However, doing so would only generate a mixture of [tex]\rm Na^{+}[/tex] and [tex]\rm Cl^{-}[/tex] ions- not sodium and chlorine atoms.

Answer:yea it’s transfer

Explanation:

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