If the equilibrium constant for the dissociation of lactic acid is 1.38 x 104, what is the AGO' for this reaction? A) 16.3kJ/mol B) -16.3 kJ/mol C) 16.96 kJ/mol D) -16.96 kJ/mol E) 27.5 kJ/mol

Answers

Answer 1

The AGO' (standard free energy change) can be calculated using the equation:
ΔG° = -RT ln(K)
where R is the gas constant (8.314 J/mol·K), T is the temperature in Kelvin, and K is the equilibrium constant.

Since the question does not specify a temperature, we cannot calculate an exact value for ΔG°. However, we can use the given equilibrium constant and some approximations to find the closest answer choice.

Using the given equilibrium constant of 1.38 x 10^4, we can take the natural logarithm of both sides to get:
ln(K) = ln(1.38 x 10^4)

Using a calculator, we find that ln(K) ≈ 9.53.

Assuming a temperature of 298 K (standard conditions), we can substitute the values into the equation above to get:
ΔG° = -RT ln(K) = -(8.314 J/mol·K)(298 K)(9.53) ≈ -19,870 J/mol ≈ -19.9 kJ/mol

Therefore, the closest answer choice is D) -16.96 kJ/mol.

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Answer 2

The standard free energy change (∆G°) can be calculated using the equilibrium constant (K) by the equation: ∆G° = -RT ln(K), where R is the gas constant (8.314 J/mol K) and T is the temperature in Kelvin. The Correct option is B -16.3 kJ/mol.

Given: K = 1.38 x [tex]10^4[/tex]

We don't have the temperature, so we cannot calculate the exact value of ∆G°. However, we can determine the sign of ∆G° based on the value of K.

If K > 1, then ln(K) > 0 and ∆G° < 0 (exergonic reaction).

If K < 1, then ln(K) < 0 and ∆G° > 0 (endergonic reaction).

Since K = 1.38 x [tex]10^4[/tex] > 1, we know that the reaction is exergonic and ∆G° is negative.

Therefore, the answer is (B) -16.3 kJ/mol.

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Related Questions

What statements about the possible hazards of sodium borohydride are correct?

Answers

Sodium borohydride (NaBH4) is a versatile reducing agent used in various chemical reactions. Regarding the possible hazards associated with sodium borohydride, the following statements are correct:

1. Sodium borohydride is a flammable solid and can ignite upon contact with air or moisture.
2. It is a strong reducing agent and can produce flammable hydrogen gas when in contact with water or acids.
3. Sodium borohydride may cause severe skin and eye irritation or burns due to its corrosive nature.
4. Ingestion or inhalation of sodium borohydride may lead to respiratory irritation and digestive issues.

When handling sodium borohydride, it's essential to follow proper safety precautions, such as wearing appropriate personal protective equipment and working in a well-ventilated area.

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What condition does a carbonyl compound have to fulfill in order to form an enolate

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In order for a carbonyl compound to form an enolate, it must be in a basic condition.

This is because the formation of an enolate involves the deprotonation of the α-carbon adjacent to the carbonyl group, and a basic environment is necessary to facilitate this deprotonation. Once deprotonated, the α-carbon becomes a negatively charged nucleophile that can then attack the carbonyl carbon, resulting in the formation of an enolate. This acidic hydrogen can be deprotonated under basic conditions, leading to the formation of the enolate anion, which is stabilized by resonance with the carbonyl group.

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What was the pH of fresh whole milk? At what pH did thickening begin? At what pH was curd formation apparent?

Answers

The addition of acid, such as vinegar or lemon juice, can also cause curd formation by lowering the pH of the milk.

Why will be pH of fresh whole milk thickening begin?

The pH of fresh whole milk is typically around 6.5-6.7, although this can vary depending on the breed of the cow, its diet, and other factors. Milk is considered to be slightly acidic, with a pH below 7.

Thickening of milk can begin at a pH of around 6.2-6.4. This is due to the natural acidity of milk causing the casein proteins to start clumping together and forming aggregates, which can make the milk thicker and more viscous. This process is known as renneting, and is an important step in the production of cheese and other dairy products.

Curd formation becomes apparent at a pH of around 4.6-4.7. As the [tex]pH[/tex] of the milk decreases, the casein proteins continue to clump together and form larger aggregates. At this [tex]pH[/tex], the aggregates become large enough to be visible as curds, which can be separated from the liquid whey to produce cheese.

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Find the area of the shaded region shown below and choose the appropriate result.

Answers

The area of the shaded region shown in the image is 92 in². Option C is correct.

To find the area of the shaded region, we need to subtract the area of the smaller circle from the area of the larger circle. The radius of the larger circle is 6 inches, so its area is πr² = π(6²) = 36π square inches. The radius of the smaller circle is half of the larger circle's radius, which is 3 inches. So, its area is πr² = π(3²) = 9π square inches.

Subtracting the area of the smaller circle from the area of the larger circle gives us:

36π - 9π = 27π square inches.

This is the area of the shaded region. Using the approximate value of π = 3.14, we get:

27π = 27 × 3.14 = 84.78 square inches

Therefore, the closest answer is 92 in². Option C is correct.

The complete question is

Find the area of the shaded region shown below and choose the appropriate result.

A 48 in²

B 96 in²

C 92 in²

D 144 in²

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What free radical is most is likely to be formed from bromination?

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The most likely free radical to be formed from bromination is the bromine radical Br•. This is because during bromination, a bromine molecule Br2 is broken down into two bromine radicals, which then react with the substrate to form the final product.

The bromine radical is highly reactive and plays a key role in the overall mechanism of bromination. In the context of free radical bromination, the most likely free radical to be formed is the bromine radical Br•.Here's a step-by-step explanation Free radical bromination is a reaction in which a bromine molecule Br2 is added to an alkane, replacing one of the hydrogen atoms with a bromine atom.The reaction starts by the homolytic cleavage of the bromine molecule Br2 under UV light or heat, which generates two bromine radicals Br•. These bromine radicals Br• are highly reactive species with unpaired electrons, seeking to form a bond with another atom to achieve a stable electron configuration. A bromine radical Br• reacts with an alkane by abstracting a hydrogen atom, forming a new bond and creating an alkyl radical.The alkyl radical then reacts with another bromine molecule Br2 to generate the brominated alkane and a new bromine radical Br•, continuing the chain reaction. So, the most likely free radical to be formed from bromination is the bromine radical Br•.

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A Downs cell is run for 1.00 hour with a current of 20 amps. how many coulombs of charge would be produced in the cell?

Answers

The calculate the coulombs of charge inorganic produced in the Downs cell, we can use the formula charge in coulombs = current in amps x time in seconds. Therefore, the Downs cell would produce 72,000 coulombs of charge when run for 1.00 hour with a current of 20 amps.



The happy to help you with this question. To calculate the amount of charge in coulombs organic produced in the Downs cell, you can use the formula Charge coulombs = Current amps × Time seconds First, let's convert the time given in hours to seconds1 hour = 60 minutes × 60 seconds = 3600 seconds Now, you can plug in the values for current and time Charge coulombs = 20 amps × 3600 seconds Charge coulombs = 72000 coulombs So, in the Downs cell, 72,000 coulombs of charge would be produced when calculate running for 1 hour with a current of 20 amps.

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What acid is formed when SO3 is added to water?
A) hydrosulfuric
B) hydrosulfurous
C) sulfuric
D) sulfurous

Answers

When [tex]SO_{3}[/tex] is added to water, sulfuric acid ([tex]H_{2} SO_{4}[/tex]) is formed.

The reaction between [tex]SO_{3}[/tex] and water is highly exothermic and can produce a lot of heat. The reaction proceeds as follows:

[tex]SO_{3}[/tex] + [tex]H_{2}O[/tex] → [tex]H_{2} SO_{4}[/tex]

Sulfuric acid is a strong acid that is widely used in industry for a variety of applications, including the production of fertilizers, detergents, and dyes. It is also used in the production of batteries, as well as in the refining of petroleum and other raw materials. Sulfuric acid is highly corrosive and can cause severe burns, so it must be handled with care.

Sulfuric acid is a strong, highly corrosive acid with the chemical formula [tex]H_{2} SO_{4}[/tex]. It is a dense, oily liquid that is soluble in water, and it is often used in industry as a catalyst or as a reactant in the production of other chemicals. Sulfuric acid is also commonly used in the production of fertilizers, detergents, and pigments.

When [tex]SO_{3}[/tex] is added to water, it reacts with the water molecules to form sulfuric acid. This is an exothermic reaction, which means that it releases heat. The reaction proceeds as follows:

[tex]SO_{3}[/tex] + [tex]H_{2}O[/tex] → [tex]H_{2} SO_{4}[/tex]

In this reaction, the [tex]SO_{3}[/tex] molecule combines with a water molecule ([tex]H_{2}O[/tex]) to form a molecule of sulfuric acid ([tex]H_{2} SO_{4}[/tex]). The reaction is highly exothermic, releasing a large amount of heat. This heat can be dangerous if not properly controlled, as it can cause the solution to boil or even explode.

The reaction between [tex]SO_{3}[/tex] and water to form sulfuric acid is used in a number of industrial processes, including the production of sulfuric acid itself. In this process, [tex]SO_{3}[/tex] gas is dissolved in water to form sulfuric acid, which can then be purified and concentrated to the desired strength. The reaction can also be used in the production of other chemicals, such as oleum, which is a mixture of sulfuric acid and [tex]SO_{3}[/tex] that is used as a catalyst in a variety of chemical reactions.

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For chemical reactions, we define the possible arrangements of atoms or molecules (positions or energy levles) by _____

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For chemical reactions, we define the possible arrangements of atoms or molecules (positions or energy levels) by "chemical bonding."

Chemical bonding is the process by which atoms or molecules combine to form larger, more complex compounds. It involves the sharing or transfer of electrons between atoms, resulting in the formation of new chemical bonds. The type of bonding that occurs depends on the electronegativity of the atoms involved, as well as other factors such as their size and shape. Understanding chemical bonding is important in predicting the properties and behavior of chemical substances, as well as in developing new materials and drugs.

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Question 3 Marks: 1 Swimming pool water clarity is measured in terms ofChoose one answer. a. NTU b. Secchi disk readings c. ORP d. both A and B

Answers

Swimming pool water clarity is an important factor to consider for the safety and enjoyment of swimmers. It is measured in terms of NTU (Nephelometric Turbidity Units) and Secchi disk readings.

NTU is a measure of the number of suspended particles in the water, such as dirt and debris, which can cause the water to appear cloudy or murky. The lower the NTU value, the clearer the water is. Secchi disk readings, on the other hand, involve lowering a white and black disk into the water to measure the depth at which it is no longer visible.

This measurement indicates the clarity of the water and can help identify if there are any issues with algae growth or other contaminants. Both NTU and Secchi disk readings are commonly used to assess water quality in swimming pools and can help ensure that the water is safe and enjoyable for all swimmers.

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In the dibenzalacetone synthesis rxn, why is it imp to remove OH- by washing the crystals in water?

Answers

In the dibenzalacetone synthesis reaction, it is important to remove OH- by washing the crystals in water because the presence of OH- can interfere with the formation of the desired crystals.

OH- can react with the dibenzalacetone and lead to the formation of unwanted byproducts, reducing the yield and purity of the final product. By washing the crystals in water, any remaining OH- is removed, ensuring the purity and quality of the crystals. This is important because the purity of the crystals affects the accuracy of any subsequent analysis or applications.


In the synthesis of dibenzalacetone, it is important to remove the OH- ions by washing the crystals in water because it helps in purifying the product. Washing the crystals in water removes any unreacted starting materials, byproducts, or residual base (OH-) that could affect the purity and yield of the dibenzalacetone. This ensures a cleaner and more accurate result for your reaction.

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Describe the symport process by which cells lining the small intestine import glucose. What ion is responsible for the transport, and what two particular features facilitate the energetically favored movement of this ion across the plasma membrane?

Answers

 The energetically favored movement of Na+ ions across the plasma membrane is facilitated by the sodium-potassium ATPase pumps and the SGLT1 transporter.

The process by which cells lining the small intestine import glucose is called symport. Symport is a type of transport process in which two or more different molecules are transported simultaneously across the plasma membrane in the same direction. In the case of glucose absorption in the small intestine, the symport process involves the co-transport of glucose and sodium ions (Na+) into the intestinal cells.

The process works as follows: Sodium-potassium ATPase pumps: The basolateral side of the intestinal cells contains sodium-potassium ATPase pumps that pump Na+ out of the cell and into the extracellular space. This creates a concentration gradient, with a higher concentration of Na+ outside the cell than inside.

SGLT1 transporters: The apical side of the intestinal cells contains a sodium-glucose linked transporter (SGLT1) that binds both glucose and Na+. As Na+ moves down its concentration gradient from outside to inside the cell, it carries glucose molecules with it into the cell.

GLUT2 transporters: Once inside the cell, glucose molecules are transported across the basolateral membrane into the blood by glucose transporter type 2 (GLUT2) transporters.

The transport of glucose and sodium ions is energetically favored because the concentration gradient of Na+ provides the energy required for glucose to be transported against its concentration gradient. The Na+ ion is responsible for the transport, and two particular features facilitate its movement across the plasma membrane. These features are:

Sodium-potassium ATPase pumps: These pumps maintain a concentration gradient of Na+ ions across the plasma membrane, with a higher concentration outside the cell than inside.

Sodium-glucose linked transporter (SGLT1): This transporter binds both glucose and Na+ ions and uses the energy of the Na+ gradient to transport glucose molecules against their concentration gradient.

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Which two conditions can cause water or liquids to backflow into a water system?
a) Valvue maintenance and Pump Maintenance
b) Service Leak and Water Hammer
c) Backsiphonage and Cross-Connection
d) Backsiphonage and Backpressure

Answers

The two conditions that can cause water or liquids to backflow into a water system are back siphonage and back pressure. Option (d) is the correct answer.

Back siphonage occurs when there is a sudden decrease in water pressure in the water supply system, causing the water to flow in the opposite direction, leading to backflow. This can happen when there is a break in the main water supply line, or when there is a sudden high demand for water, such as during firefighting activities. Backpressure, on the other hand, occurs when the pressure in the downstream water system is higher than the pressure in the upstream water system.

This can happen when a pump is connected directly to a potable water system without proper backflow prevention devices or when a boiler or other heating device is connected to a water system without proper safety valves. Both of these conditions can result in contaminated or unsafe water entering the potable water supply, leading to health hazards and water quality issues. It is important to have proper backflow prevention devices installed and regularly maintained to prevent such occurrences.

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In the acid-base reaction H3O+ + OH- → 2H2O, the H3O+ ion transfers a(n)______ to the OH- ion.

Answers

In the acid-base reaction H3O+ + OH- → 2H2O, the H3O+ ion transfers a proton (H+). This is a classic example of a neutralization reaction where the acidic H3O+ ion and the basic OH- ion combine to form water (H2O) molecules. The transfer of a proton from the H3O+ ion to the OH- ion results in the formation of two water molecules, which are neutral in nature.

1. H3O+ (hydronium ion) acts as an acid, while OH- (hydroxide ion) acts as a base.
2. The acid (H3O+) donates a proton (H+) to the base (OH-).
3. OH- accepts the proton (H+) and forms a water molecule (H2O).
4. The reaction results in the formation of 2 water molecules, as shown in the balanced equation: H3O+ + OH- → 2H2O.

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6.8. Compared to glass, plastic sheet substitutes are generally less A. durable.
C. transparent.
B. fire-resistant.
D. expensive.

Answers

Compared to glass, plastic sheet substitutes are generally less durable.

Glass is a very strong and durable material that is much more resistant to scratches and other types of wear and tear than plastic. Plastic sheets are often used as a substitute for glass because they are often cheaper and lighter, but they are not as strong or as durable.Plastic sheeting is generally not as durable as glass, as it is more prone to cracking, scratching, and other damage. Plastic can also be affected by extreme temperatures, whereas glass is more heat-resistant. Additionally, plastic is much more susceptible to UV radiation damage, which can cause it to become brittle and break over time. Glass, on the other hand, is highly durable and can withstand extreme temperatures and pressure without cracking or breaking.

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Check valves are used to?
a) Permit air to escape from the pipe
b) Regulate Velocity
c) Permit flow in only one direction
d) Stop flow in both directions

Answers

Answer:

C permit flow in only one direction

Question 14
The chemical used as a measure of the oxidant level of the atmosphere at any given time is:
a. Nitrogen dioxide
b. Carbon dioxide
c. Ozone
d. Sulfur dioxide

Answers

The chemical used as a measure of the oxidant level of the atmosphere at any given time is ozone (c).

Ozone is a powerful oxidizing agent and is used as an indicator of the overall oxidant level in the atmosphere.Ozone is a highly reactive gas that is formed by the action of sunlight on oxygen molecules. It is a powerful oxidant and is often used as a measure of the oxidant level of the atmosphere. High levels of ozone in the atmosphere can cause respiratory problems, especially in people with asthma or other respiratory illnesses. Nitrogen dioxide (a), carbon dioxide (b), and sulfur dioxide (d) are not used as measures of the oxidant level of the atmosphere.

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Question 3
All of the following are criteria pollutants except:
a. Carbon monoxide
b. Sulfur dioxide
c. Carbon dioxide
d. Nitrogen oxides

Answers

c. Carbon dioxide is not a criteria pollutant. The criteria pollutants are a group of six common air pollutants that are regulated by the United States Environmental Protection Agency (EPA) because of their potential harm to human health and the environment.

The six criteria pollutants are: Carbon monoxide (CO)

Sulfur dioxide (SO2)

Nitrogen oxides (NOx)

Ozone (O3)

Particulate matter (PM)

Lead (Pb)

Carbon dioxide (CO2) is not considered a criteria pollutant because it is not directly harmful to human health at typical ambient concentrations. However, CO2 is a greenhouse gas and contributes to climate change, which is a significant environmental concern. The EPA regulates CO2 emissions from certain sources, such as power plants and vehicles, but it is not considered a criteria pollutant.

The six criteria pollutants were identified by the EPA as being common in outdoor air and having the potential to harm human health and the environment. Here is a brief description of each of the criteria pollutants:

Carbon monoxide (CO): This is a colorless, odorless gas that is produced by the incomplete combustion of fuels such as gasoline, oil, and wood. High levels of CO can be harmful to human health, causing headaches, dizziness, nausea, and even death.

Sulfur dioxide (SO2): This is a gas that is produced by the burning of fossil fuels that contain sulfur, such as coal and oil. SO2 can cause respiratory problems in humans, particularly in people with asthma or other lung conditions. It can also harm plants and animals, and contribute to acid rain.

Nitrogen oxides (NOx): These are gases that are produced by combustion, particularly in vehicles and power plants. NOx can cause respiratory problems and contribute to the formation of ground-level ozone (smog), which can harm human health and the environment.

Ozone (O3): This is a gas that is formed when NOx and volatile organic compounds (VOCs) react in the presence of sunlight. Ozone can cause respiratory problems, particularly in people with asthma or other lung conditions. It can also harm plants and animals, and contribute to acid rain.

Particulate matter (PM): This refers to tiny particles that are suspended in the air, such as dust, dirt, and soot. PM can cause respiratory problems, particularly in people with asthma or other lung conditions. It can also harm the cardiovascular system and contribute to premature death.

Lead (Pb): This is a toxic metal that was once widely used in gasoline and other products. Lead can harm the nervous system and cause developmental problems, particularly in children.

The EPA regulates emissions of these pollutants from a variety of sources, such as power plants, vehicles, and industrial facilities. The goal is to reduce levels of these pollutants in the air to protect human health and the environment. The EPA sets National Ambient Air Quality Standards (NAAQS) for each of the criteria pollutants, which are the maximum allowable concentrations in the air. States are responsible for implementing plans to meet these standards.

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If the pressure exerted by a gas at 25ºC in a volume of 0.044L is 3.81atm, how many moles of gas are present?

Answers

Answer: 0.00176 moles of gas present.

Explanation:

We can use the Ideal Gas Law to solve for the number of moles of gas present:

PV = nRT

where:

P = pressure (in atm)

V = volume (in L)

n = number of moles

R = ideal gas constant (0.08206 L·atm/mol·K)

T = temperature (in Kelvin)

First, we need to convert the temperature from Celsius to Kelvin:

T = 25ºC + 273.15 = 298.15K

Plugging in the given values, we get:

(3.81 atm) (0.044 L) = n (0.08206 L·atm/mol·K) (298.15 K)

Solving for n, we get:

n = (3.81 atm x 0.044 L) / (0.08206 L·atm/mol·K x 298.15 K)

n = 0.00176 mol

Therefore, there are 0.00176 moles of gas present.

The temperature of a gas in a rigid steel container is increased from 100 K to
200 K. Which of the following is the most likely effect of this change on the other
three variables used to describe the behavior of a gas?

Answers

The gas loses half of its mass and volume while maintaining constant pressure.

With an example, define volume in chemistry?

A substance or object's volume is how much 3D space it takes up. The amount of water in each beaker in the image above is the same (50 mL). As you may have seen, each beaker's 50 mL has a completely distinct appearance.

How do mass and volume compare?

The volume of a three-dimensional item, which is measured in cubic units, is the amount of space it occupies. Examples include the cubic units cm3 and in3. However, mass is a measurement of the substance content of an object. Mass is frequently determined by weighing an object.

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The correct Question is

The temperature of a gas in a rigid steel container is increased from 100 K to 200 K. Which of the following is the most likely effect of this change on the other three variables used to describe the behavior of a gas?

An oxidation number is the _____ an atom would have if all bonds involved the _____ of electrons. The oxidation number can be used to determine whether a species is oxidized or reduced in a chemical reaction.

Answers

An oxidation number is the hypothetical charge an atom would have if all bonds involved the transfer of electrons. This number is assigned to atoms in a chemical compound based on a set of rules.

The oxidation number can be used to determine whether a species is oxidized or reduced in a chemical reaction. Oxidation is a process in which an atom loses electrons, whereas reduction is a process in which an atom gains electrons. By tracking the changes in oxidation number of each species in a reaction, we can determine whether oxidation or reduction has occurred.
An oxidation number is the charge an atom would have if all bonds involved the transfer of electrons. The oxidation number can be used to determine whether a species is oxidized or reduced in a chemical reaction. In this context, "oxidation" refers to the process of losing electrons, while "reduction" refers to gaining electrons. A detailed chemical explanation of a reaction would involve analyzing the changes in oxidation numbers for each element involved in the reaction.

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. ___________ makes magnets, but adding neodymium makes magnets on steroids.

Answers

Iron make magnets, but adding neodymium to the mix creates magnets with significantly enhanced magnetic properties, making them commonly referred to as "magnets on steroids."

Magnets are materials that exhibit magnetic properties, which are the result of the alignment of the spins of electrons in the atoms or ions that make up the material. Iron is a common element that is known for its magnetic properties, and it is widely used in the production of magnets. Neodymium is a rare earth element, specifically a lanthanide, that is known for its extremely strong magnetic properties. Neodymium magnets, also known as neodymium-iron-boron (NdFeB) magnets, are the most powerful type of permanent magnets commercially available today.

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Which ONE of the following statements is INCORRECT?
Photosynthesis in plants occurs in two stages. The first uses water to reduce CO2 to carbohydrates. The second uses NADPH to convert ADP into ATP.
Some organisms use hydrogen gas instead of water as a reducing agent.
The so-called "dark-reactions" are accelerated by light.
Both atoms of oxygen in the O2 produced by photosynthesis come from water.

Answers

The statement "The so-called 'dark-reactions' are accelerated by light" is INCORRECT. The dark reactions, also known as the Calvin cycle, do not require light and are instead powered by the ATP and NADPH produced during the light-dependent reactions.


Your answer: The INCORRECT statement is: "Photosynthesis in plants occurs in two stages. The first uses water to reduce CO2 to carbohydrates. The second uses NADPH to convert ADP into ATP." In reality, the first stage is the light-dependent reactions, which convert light energy into chemical energy (ATP and NADPH) using water, and the second stage is the light-independent reactions (Calvin cycle), which use CO2, ATP, and NADPH to produce carbohydrates.

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The statement that is INCORRECT among the given options is: "Photosynthesis in plants occurs in two stages. The first uses water to reduce CO2 to carbohydrates. The second uses NADPH to convert ADP into ATP."

a). Photosynthesis in plants occurs in two stages. The first uses water to reduce CO2 to carbohydrates. The second uses NADPH to convert ADP into ATP.

b). Some organisms use hydrogen gas instead of water as a reducing agent.

c). The so-called "dark-reactions" are accelerated by light.

d). Both atoms of oxygen in the O2 produced by photosynthesis come from water.

The two stages of photosynthesis is:
1. The light-dependent reactions: These reactions occur in the thylakoid membrane and involve the conversion of light energy into chemical energy in the form of ATP and NADPH. Water is split, releasing oxygen gas as a byproduct.
2. The light-independent reactions (Calvin cycle): These reactions occur in the stroma of the chloroplast and use the ATP and NADPH generated in the first stage to convert CO2 into carbohydrates.

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How does the spectrophotometer measure absorbance? Why does the dye absorb light (electron transitions)? What color light does Blue #1 dye absorb? What is the lambda max of the dye? What is Beer’s law and how can it be used to calculate the desired concentrations for your solutions? Considering Beer’s law, is it possible to look up the molar absorptivity coefficient of Blue #1 dye? How will you estimate what concentrations of dye will be required for an absorbance of 1. 0 AU given a path length of 1. 46cm? How would you dilute a 2. 0 mM dye solution to make 100mL of this 1. 0 AU solution? How can the 1. 0 AU solution be diluted to form a point on the calibration curve at 0. 25 AU?

Answers

The spectrophotometer measures absorbance by passing light through a sample and measuring the amount absorbed. Dyes absorb light due to electron transitions, and Blue #1 dye specifically absorbs 630 nm orange light.

The spectrophotometer measures absorbance by shining a beam of light of a specific wavelength through a sample and measuring how much light is absorbed by the sample. The amount of light absorbed is directly proportional to the concentration of the absorbing substance in the sample.

The dye absorbs light due to the presence of chromophores, which are groups of atoms with delocalized electrons that can undergo electron transitions when light is absorbed. The Blue #1 dye absorbs orange/yellow light (around 480 nm) due to the presence of a sulfonate group in the molecule. The lambda max of the dye is around 630 nm, which is the wavelength at which the dye absorbs the most light.

Beer’s law states that the absorbance of a solution is directly proportional to the concentration of the absorbing substance and the path length of the light through the solution. It can be used to calculate the desired concentrations for solutions by measuring the absorbance of known concentrations and using the equation A = εcl, where A is absorbance, ε is the molar absorptivity coefficient, c is concentration, and l is the path length.

It is possible to look up the molar absorptivity coefficient of Blue #1 dye in literature sources or online databases. To estimate what concentrations of dye will be required for an absorbance of 1.0 AU given a path length of 1.46 cm, you would need to use Beer’s law and the molar absorptivity coefficient of the dye. Rearranging the equation to solve for concentration gives c = A/εl.

To dilute a 2.0 mM dye solution to make 100 mL of a 1.0 AU solution, you would need to use the formula c1v1 = c2v2, where c1 is the initial concentration, v1 is the initial volume, c2 is the final concentration, and v2 is the final volume. Solving for v1 gives v1 = c2v2/c1 = (1.0 AU)(0.1 L)/(2.0 mM) = 0.005 L or 5 mL. So, you would need to take 5 mL of the 2.0 mM dye solution and add enough solvent (usually water) to make a total volume of 100 mL.

To dilute the 1.0 AU solution to form a point on the calibration curve at 0.25 AU, you would need to dilute the solution four times, since 1.0 AU is four times larger than 0.25 AU. This could be done by adding three parts solvent (e.g. water) to one part of the 1.0 AU solution.

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Calculate the Ecell value at 298K for the cell based on the reaction:

Cu(s) + 2Ag+(aq) ----> Cu+2 (aq) + 2Ag(s)

where [Ag+]= 0. 00475 M and [Cu+2]=0. 000900 M

Answers

The value of the Ecell at 298K for the cell based reaction Cu(s) + 2Ag⁺(aq) → Cu⁺²(aq) + 2Ag(s) is 0.495 V.

To calculate the Ecell value at 298K for the given cell, we need to use the Nernst equation,

Ecell = E°cell - (RT/nF) ln(Q), Ecell is the cell potential Ecell, he standard cell potential E°cell, gas constant (8.314 J/mol·K) is R, temperature in Kelvin (298 K) is T, number of electrons transferred in the reaction (2 in this case) is n, Faraday constant (96,485 C/mol) is F and reaction quotient is Q.

First, let's find the value of Q. The reaction quotient for this cell is,

Q = [Cu²⁺][Ag]² / [Ag⁺]²

Substituting the given concentrations,

Q = (0.000900)(0.00475)² / (0.00475)²

Q = 0.000900

Next, let's find the standard cell potential, E°cell. We can look this up in a table of standard reduction potentials. The half-reactions for this cell are,

Cu²⁺(aq) + 2e⁻ → Cu(s) E°red = +0.34 V

Ag⁺(aq) + e⁻ → Ag(s) E°red = +0.80 V

To get the overall reaction, we need to reverse the first half-reaction and multiply it by 2,

Cu(s) → Cu²⁺(aq) + 2e⁻ E°red = -0.34 V

2Ag⁺(aq) + 2e⁻ → 2Ag(s) E°red = +0.80 V

Adding these two half-reactions gives the overall reaction,

Cu(s) + 2Ag⁺(aq) → Cu²⁺(aq) + 2Ag(s) E°cell = +0.46 V

Now we can use the Nernst equation to calculate the cell potential at 298K,

Ecell = E°cell - (RT/nF) ln(Q)

Ecell = 0.46 - (8.314 × 298 / (2 × 96,485)) ln(0.000900)

Ecell = 0.46 - (0.0257) ln(0.000900)

Ecell = 0.46 - (-0.0349)

Ecell = 0.495 V

Therefore, the Ecell value at 298K for the given cell is 0.495 V.

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Complete question - Calculate the Ecell value at 298K for the cell based on the reaction:

Cu(s) + 2Ag⁺(aq) → Cu⁺²(aq) + 2Ag(s)

where [Ag⁺]= 0. 00475 M and [Cu⁺²]=0. 000900 M

How could be track GFP during purification

Answers

During purification, GFP can be tracked using a variety of methods, such as fluorescence microscopy or fluorometry.

One popular method is to add a purification tag to the GFP protein, such as a His-tag or FLAG-tag, which can be easily detected using specific antibodies or binding proteins. Alternatively, the GFP gene can be fused to a gene encoding a different protein that is easily detectable during purification, such as a fluorescent protein or an enzyme. By monitoring the levels of the tag or fusion protein during the purification process, the presence and purity of the GFP can be accurately tracked.

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Question 65
Concentrations of less than __ pollen grains/m3 of air in a 24-hour period usually do not produce allergic reactions
a. 25
b. 33
c. 100
d. 1000

Answers

The concentration of pollen in the air can have a significant impact on individuals with allergies. Pollen counts are typically measured in the number of pollen grains per cubic meter of air (pollen grains/m3). The concentration at which allergic reactions occur can vary depending on the individual's sensitivity, the type of pollen, and other environmental factors.

According to the American Academy of Allergy, Asthma, and Immunology (AAAAI), concentrations of less than 100 pollen grains/m3 of air in a 24-hour period usually do not produce allergic reactions in most individuals. However, for highly sensitive individuals, even lower concentrations may trigger symptoms.

It's important to note that pollen counts can vary widely depending on the time of day, weather conditions, and other factors. Pollen counts are often highest in the early morning and on warm, dry, and windy days. It's recommended that individuals with allergies monitor pollen counts and take precautions, such as staying indoors during peak pollen hours or wearing a mask when outdoors, to minimize exposure to pollen.

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What doesn't a nucleophile play a role in the rate of an Sn1 reaction?

Answers

A nucleophile does not play a role in the rate of an SN1 reaction because the rate-determining step is independent of the nucleophile's involvement.

In an SN1 reaction, the rate-determining step is the first step, where the leaving group departs from the substrate molecule, forming a carbocation intermediate. This step determines the reaction rate since it has the highest energy barrier. The nucleophile, which is an electron-rich species that can donate electrons, participates in the second step, where it attacks the carbocation intermediate, forming a new bond.
Since the nucleophile is not involved in the rate-determining step of an SN1 reaction, its presence or concentration does not affect the reaction rate.

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Question 103
To prepare a solution of 100 mg per liter available chlorine, __ of 5.25 percent bleach with one gallon of water should be used.
a. 0.5 oz
b. 1.0 oz
c. 0.33 oz
d. 0.25 oz

Answers

To prepare a solution of 100 mg per liter of available chlorine, 0.33 oz of 5.25 percent bleach with one gallon of water should be used.

The concentration of available chlorine in household bleach is typically expressed as a percentage, which represents the amount of sodium hypochlorite in the bleach. For example, 5.25 percent bleach contains 52,500 mg of sodium hypochlorite per liter of solution. To calculate the amount of bleach needed to prepare a solution with a desired concentration of available chlorine, the following formula can be used: (amount of bleach in oz) = (desired concentration of available chlorine in mg/L) x (volume of water in liters) x (100) / (% of available chlorine in the bleach) In this case, the desired concentration of available chlorine is 100 mg/L, the volume of water is one gallon (which is approximately 3.785 L), and the percentage of available chlorine in the bleach is 5.25 percent. Plugging these values into the formula yields: (amount of bleach in oz) = (100 mg/L) x (3.785 L) x (100) / (5.25%) = 0.33 oz

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1 stomach mass unit is the approximate weight of one _______ but is
Formerly defined as 1 / ____ the mass of a neutral _________ atom

Answers

1 atomic mass unit (amu) is the approximate weight of one proton or one neutron, but is formerly defined as 1/16 the mass of a neutral oxygen-16 atom.

Atomic mass unit (amu) is the unit of mass which is used to express atomic and molecular weights. One atomic mass unit is defined as one-twelfth of the mass of an unbound atom of carbon-12, which is approximately 1.66054 × 10⁻²⁷ kg.

Neutral oxygen-16 is the most common isotope of oxygen, with 8 protons, 8 neutrons, and 8 electrons. Its atomic mass is 15.994915 amu, which means that one neutral oxygen-16 atom weighs approximately 15.994915 times the mass of one atomic mass unit (amu).

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--The given question is incorrect, the correct question is

"1 atomic mass unit is the approximate weight of one _______ but is Formerly defined as 1 / ____ the mass of a neutral _________ atom."--

What are the common units for reaction rate?
1. 1/s
2. moles per liter
3. molarity per second
4. moles per second
5. seconds per mole

Answers

The common units for reaction rate are:  moles per second or molarity per second. The correct options are 3 and 4.

The common units for reaction rate depend on the type of reaction being studied.

For example, if the reaction involves the consumption of a reactant, the units may be in moles per second or molarity per second, since these measure the rate of change of the concentration of the reactant over time.

On the other hand, if the reaction involves the production of a product, the units may be in moles per second or molarity per second, but with a positive sign, indicating the rate of change of the concentration of the product over time. Another unit that may be used is 1/s, which simply measures the change in concentration of the reactant or product per second, regardless of the volume of the solution.

Overall, the most common units for reaction rate are moles per second or molarity per second, since these directly relate to the concentration of the reactants and products involved in the reaction. However, it is important to pay attention to the sign and the type of substance being measured in order to accurately interpret the results.

Therefore, options 3 and 4 are correct.

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