Alkynes are reduced to trans alkenes by a process called dissolving metal reduction. The reaction uses sodium or lithium metal as the reducing agent and liquid ammonia as the solvent. The method is specific in the formation of trans alkenes from alkynes. The method involves two successive transfers of single electrons from the alkali metal to the triple bond, with abstraction of protons from the ammonia solvent.Draw curved arrows to show the movement of electrons in this step of the mechanism.Arrow-pushing Instructions
Answers
Answer:
Explanation:
The movement of the electrons is illustrated in the picture attached to this answer. It is a four-step reaction mechanism.
First STEP: The first step involves the transfer of an electron from sodium to form a radical anion.
Second STEP: This radical anion then removes a proton/hydrogen from ammonia in a bid to neutralize itself (hence the hydrogen becomes bonded to the anion).
Third STEP: The sodium (from NaNH₂ formed) transfers an electron again to produce a vinyl carbanion.
Fourth STEP: The carbanion then removes a proton/hydrogen from ammonia (like in the second step) to form a neutral trans-alkene.
NOTE: The circled numbers denote each step while the mechanism on the left represents the use of any alkyl group (R and R') while the mechanism on the right assumes both alkyl groups are methyl. Hence, 2-butyne started the reaction and the final product was trans-2-butene.
Related Questions
How many atoms are in one body-centered cubic unit cell of a metal?
A) 1.
B) 2.
C) 3.
D) 4.
Answers
Answer:
Option B - 2
Explanation:
In Crystal lattices, there are different types of unit cells namely;
- Hexagonal Closest Packed (HCP)
- Face Centred Cubic (FCC)
- Body Centred Cubic (BCC)
- Simple Centred Cubic (SC)
Now, each of them have a coordination number and also number of atoms per unit cell.
For this question, we are restricted to the body-centered cubic (bcc) unit cell which has a coordination number of 8 and contains 2 atoms per unit cell.
Answer:
B) 2.
Explanation:
They have 8 1/8 atoms on the edge that add to get 1 atom. Plus one whole atom inside. 1+1=2
A 0.500 g sample of tin (Sn) is reacted with oxygen to give 0.534 g of product. What is the empirical formula of the oxide?
Answers
Answer:
[tex]Sn_2O[/tex]
Explanation:
Hello,
In this case, given the mass of the sample and mass of tin we can compute the mass of oxygen via:
[tex]m_O=0.534g-0.500g=0.034g[/tex]
Thus, by using the atomic bas of tin and oxygen we can compute their moles:
[tex]n_{Sn}=0.500gSn*\frac{1molSn}{118.8gSn} =0.00421mol\\\\n_O=0.034gO*\frac{1molO}{16gO}=0.002125mol[/tex]
Next, we need to divide both moles by the moles of oxygen as those are the smallest in order to compute the subscript in the chemical reaction:
[tex]Sn=\frac{0.00421}{0.002125}=2\\ \\O=\frac{0.002125}{0.002125}= 1[/tex]
Therefore, empirical formula of the oxide should be:
[tex]Sn_2O[/tex]
Best regards.
Students observed cells under the microscope. They observed that the cells had a cell wall, cell membrane,
nucleus, and many chloroplasts.
Which observation helps students identify the type of cell observed?
A The presence of a nucleus means the cells are from a plant.
B The presence of a cell membrane means that the cells are from an animal.
C The presence of chloroplasts means that the cells are from a plant.
D The presence of a cell wall means that the cells are from an animal.
Answers
Answer:
option B is the right answer
The elemental analysis of an organic solid extracted from gum arabic showed that it contained 40.0% C, 6.7% H, and 53.3% O. A solution of 0.650 g of the solid in 27.8 g of the solvent diphenyl gave a freezing point depression of 1.56 °C. Calculate the molar mass and determine the molecular formula of the solid (kf for diphenyl is 8.00 °C/m). To earn full credit, clearly show your work with units and proper significant figures
Answers
Answer:
The molar mass of the organic solid is 119.9g/mol.
The molecular formula of an organic solid is C4H8O4
Explanation:
Step 1
We find the Molar mass
From the above question, we are given:
A solution of 0.650 g of the solid in 27.8 g of the solvent diphenyl gave a freezing point depression of 1.56 °C. Calculate the molar mass and determine the molecular formula of the solid (kf for diphenyl is 8.00 °C/m)
A freezing point depression = 1.56 °C.
Mass of organic solid= 0.650 g
Mass of diphenyl = 27.8 g
Converting to kilograms
1000g = 1kg
27.8g =
Cross Multiply
= 27.8g × 1 kg/1000g
= 0.0278kg
Boiling point constant = 8.00 °C/m
Molar mass of the organic compound = Boiling point constant × Mass of solid /Freezing point depression × Mass of diphenyl
Molar mass of the organic compound =
8.00 °C/m × 0.650g/1.56°C × 0.0278kg
= 5.2 g°C/m ÷ 0.043368 g°C
= 119.9040767 g/mol
Approximately = 119.9 g/mol
Step 2
Find the Molecular formula
Molecular formula = CxHyOz
Let x = Carbon, y = Hydrogen, z = Oxygen
For x = Carbon
Atomic mass of Carbon = 12.01078
x = % of Carbon in the compound × Molar mass of the organic compound/atomic mass of Carbon
x = 40% × 119.9 g/mol / (12.01078
x = 3.99
x = Approximately = 4
For y = Hydrogen
Atomic mass of Hydrogen = 1.007947
y = % of Hydrogen in the compound × Molar mass of the organic compound/Atomic mass of Hydrogen
x = 6.7% × 119.9 g/mol) / 1. 007947
x = 7.97
x is Approximately = 8
For z = Oxygen
Atomic mass of Oxygen = 15.99943
z = % of Oxygen in the compound × Molar mass of the organic compound/Atomic mass of Oxygen
z = 53.3% × 119.9 g/mol /15.99943
z = 3.99
z is approximately ≈ 4
Therefore,
The molar mass of the organic solid is 119.9 g/mol.
The molecular formula of an organic solid is C4H8O4
a nucleus with 4 protons has a positive charge of _____ PLEASE LET ME KNOW
Answers
Answer:
if were talking about berylium then the answer should be 2 because it wants to move 2 spaces back (losing electrons) to become a nobel gas so the answer is 2+
Explanation:
it has 2 valence electrons YW :)
A nucleus with 4 protons has a positive charge of +2.
What are Protons?Protons may be defined as the type of sub-atomic particles that are present in the nucleus of an atom along with the neutrons. These sub-atomic particles possess a positive charge in nature. It may be thought that protons are discovered by Ernest Rutherford.
Beryllium has a nucleus with 4 protons, which means that it has an atomic number of 4. This element belongs to the alkaline earth metals in group 2. Beryllium has the capability to lose two electrons in order to attain a noble gas configuration and occupy stability. It has an electronic configuration [tex]1s^2, 2s^2[/tex]. So, in order to make it octet fulfilled, it loses two electrons and becomes positively charged.
Therefore, a nucleus with 4 protons has a positive charge of +2.
To learn more about Protons, refer to the link:
https://brainly.com/question/1805828
#SPJ2
A factor that does no change in an experiment is the.
a. Controlled variable
b. Data
c. Inconstant
d. Independent variable
Answers
Answer:
A. Controlled variable
Explanation:
a controlled variable or a constant variable is a variable that doesnt change during an experiment
Given sulfur has an electron configuration of 1s22s22p63s23p4, what oxidation numbers would you expect for sulfur? (Hint: Think about how to achieve a full outer shell.)
Answers
Explanation:
1s2 2s2 2p6 3s2 3p4
Oxidation number refers to the number of electrons that an atom gains or loses as it forms a chemical bond with another element.
From the electronic configuration above, it is expected that sulphur has oxidation number of 2. This is because the p orbital can hold a maximum of 6 electrons. However, in the electronic configuration it is just holding 4. To complete it, it needs to gain 2 more electrons.
Answer:
+4, +6, –2
Explanation:
what were the limitations of Dobereiner's classifcation?
Answers
Answer:
Dobereiner could find only three triads; . i.e total of 9 elements only. However the total number of elements were more than that of those encompassed in Dobereiner's Triad
Explanation:
Answer:
Dobereiner could find only three triads; . i.e total of 9 elements only. However the total number of elements were more than that of those encompassed in Dobereiner's Triad. Thus, Dobereiner's could not be classify most of the elements known at that time
Explanation:
This work is not my own.... copied from google but hope this helps you.
13 C4- has _______ electrons.
Answers
Answer:
10 electrons
Explanation:
What is heat?
O Fire
O Hot
O Energy
O Potential
Answers
Answer:
Energy
Explanation:
Heat is a form of energy.
From a 2.875 g sample containing only iron, sand, and salt, 0.660 g of iron and 1.161 g of sand were separated and recovered. What was the percent of salt in the original sample
Answers
Answer:
36.66%
Explanation:
Step 1: Given data
Mass of iron: 0.660 gMass of sand: 1.161 gMass of the sample: 2.875 gMass of salt: ?Step 2: Calculate the mass of salt
The mass of the sample is equal to the sum of the masses of the components.
m(sample) = m(iron) + m(sand) + m(salt)
m(salt) = m(sample) - m(iron) - m(sand)
m(salt) = 2.875 g - 0.660 g - 1.161 g
m(salt) = 1.054 g
Step 3: Calculate the percent of salt in the sample
We will use the following expression.
%(salt) = m(salt) / m(sample) × 100%
%(salt) = 1.054 g / 2.875 g × 100% = 36.66%
The percent of salt in the original sample containing only iron, sand, and salt is 36.66%.
What is salt?Salt is a mineral made up of primarily sodium chloride.
Seawater contains a vast amount of salt.
Given,
The total mass of the sample is 2.875 g
Mass of iron is 0.660 g
Mass of sand is 1.161 g
Step 1: To find the mass of salt
The total mass of the sample = the sum of the masses of the compounds
m(sample) = m(iron) + m(sand) + m(salt)
2.875 g = 0.660 g + 1.161 g + m(salt)
m(salt) = 2.875 g - 0.660 g - 1.161 g
m(salt) = 1.054 g
Step 2: Calculate the percent of salt in the sample
[tex]\%(salt) = \dfrac{m(salt) }{m(sample)} \times 100\%\\\\\\\%(salt) = \dfrac{1.054 g }{2.875 g} \times 100\% = 36.66\%[/tex]
Thus, the percentage of salt in the sample is 36.66%.
Learn more about salts, here:
https://brainly.com/question/16446935
What is the volume of a sample of matter with a density of 6 and a mass of 6 cm3?
Answers
Answer:
We have the final answer as
1.0 cm³Explanation:
The volume of a substance when given the density and mass can be found by using the formula
[tex]volume = \frac{mass}{density} \\[/tex]
From the question
mass = 6 g
density = 6 g/cm³
It's volume is
[tex]volume = \frac{6}{6} = 1 \\ [/tex]
We have the final answer as
1.0 cm³Hope this helps you
Which common item is made from copper?
soap
coins
baby powder
colored pencils
Answers
Answer:
coins
Explanation:
An unknown substance from planet X has a density of 10 g/ml. It occupies a volume of 80 ml. What is the mass of this unknown substance? *
Answers
Answer:
The answer is
800 gExplanation:
The mass of a substance when given the density and volume can be found by using the formula
mass = Density × volumeFrom the question
density = 10 g/ml
volume = 80 ml
The mass of the substance is
mass = 10 × 80
We have the final answer as
800 gHope this helps you
What is the answer? Please
Answers
Answer:
true
Explanation:
what is the answer? please
Why are atoms usually portrayed as spheres when most orbitals are not spherically shaped?
a. The shape of an atom depends on the shape of its nucleus, not on the shape of its orbitals.
b. The shape of an atom depends on the shape of the outer orbital which always spherical
c. The shape of an atom is obtained by superimposing all of its orbitals.
d. The shape of an atom is not important so it is easier to treat atoms as spheres.
Answers
Answer:
The shape of an atom is not important so it is easier to treat atoms as spheres.
Explanation:
In considering the shape of an atom, we do not consider the shape of the orbitals individually.
Hence, we do not seek to determine the exact shape of the atom, rather we simply treat the atom as spheres. Even though most orbitals are not spherically shaped.
How many Calories are there in 4600 Joules?
Answers
Answer:
1099.426
Explanation:
What do metaloids share with nonmetals?
Answers
Answer:
Most metalloids have some physical properties of metals and some physical properties of nonmetals. They fall between metals and nonmetals in their ability to conduct heat and electricity. They are shiny like metals but brittle like nonmetals.
Explanation:
Complete hydrolysis of a hexapeptide gives 2 Gly, Leu, Phe, Pro, and Tyr. Reaction of the peptide with phenylisothiocyanate gave the phenylthiohydantoin of Pro. Partial hydrolysis of the peptide gave the following fragments: Phe-Gly-Tyr, Gly-Phe-Gly, Pro-Leu-Gly, Leu-Gly-Phe. What is the structure of the peptide
Answers
Answer:
The complete sequence : Pro-Leu-Gly-Phe-Gly-Tyr
Explanation:
For the formation of phenylisothiocyanate, the four peptide sequences overlap common residue to get the the complete sequence of the hexapeptide as shown in the diagram attached below
Attached below is the structure of the peptide
substance A is a nonpolar liquid and has only dispersion forces among its constituent particles. Substance B is also a nonpolar liquid and has about the same magnitude of dispersion forces among its constituent particles as substance A. When substance A and substance B are combined, they spontaneously mix. Why
Answers
Explanation:
The substance A and B will mix into one solution as it is a solvent interactions which is greater than or equal to the solute- solute and the solvent-solvent interactions. Thus when such interactions occurs, it is greater or equal to the some of the other two possible interactions. And here both have the same kind of interaction, and same magnitude, so they will makes to form a solution and mixes properly and spontaneously.
The density of water at 40°C is 0.992 g/mL. What is the volume of 2.69 g of water at this temperature? V= mL
Answers
Answer:
[tex]\boxed {\tt 2.71169355 \ mL}[/tex]
Explanation:
Density can be found using the following formula:
[tex]d=\frac {m}{v}[/tex]
Rearrange the formula for v. Multiply both sides by v, then divide both sides by d.
[tex]d*v =\frac {m}{v}*v[/tex]
[tex]d*v=m[/tex]
[tex]\frac{d*v}{d}=\frac{m}{d}[/tex]
[tex]v=\frac{m}{d}[/tex]
The volume can be found by dividing the mass by the density. The mass is 2.69 grams and the density is 0.992 grams per milliliter.
[tex]m= 2.69 \ g\\d= 0.992 \ g/mL[/tex]
Substitute the values into the formula.
[tex]v=\frac{2.69 \ g}{0.992 \ g/mL}[/tex]
Divide. Note that the grams, or g, will cancel each other out.
[tex]v=\frac{2.69}{0.992 \ mL}[/tex]
[tex]v= 2.71169355 \ mL[/tex]
The volume of the water is 2.71169355 milliliters.
A pure copper penny contains approximately 2.9×1022 copper atoms. Use the following definitions to determine how many ______ of copper atoms are in a penny. 1doz=12 1gross=144 1ream=500 1mol=6.022×1023 Part A dozens Express your answer in dozens to two significant figures.
Answers
Complete question is;
A pure copper penny contains approximately 2.9 × 10^(22) copper atoms.
1 doz = 12
1 gross = 144
1 ream = 500
1 mol = 6.022 × 10^(23)
Use these definitions to determine the following:
A) How many dozens of copper atoms are in a penny.
B) How many gross of copper atoms are in a penny
C) How many reams of copper atoms are in a penny.
D) how many moles of copper atoms are in a penny?
All answers can be rounded to two significant figures
Answer:
A) 2.4 × 10^(21) dozens
B) 2.01 × 10^(20) gross
C) 5.8 × 10^(19) reams
D) 0.048 mol
Explanation:
A) A dozen contains 12.
Therefore, 2.9 × 10^(22) copper atoms will contain;
(2.9 × 10^(22))/12 dozens = 2.42 × 10^(21).
In 2 significant figures, we have;
2.4 × 10^(21) dozens
B) 1 gross = 144
Therefore, 2.9 × 10^(22) copper atoms will contain;
(2.9 × 10^(22))/144 gross ≈ 2.01 × 10^(20) gross
C) 1 ream = 500
Therefore, 2.9 × 10^(22) copper atoms will contain;
(2.9 × 10^(22))/500 reams = 5.8 × 10^(19) reams
D) 1 mol = 6.022 × 10^(23)
Therefore, 2.9 × 10^(22) copper atoms will contain;
(2.9 × 10^(22))/(6.022 × 10^(23)) = 0.048 mol
why is a lot of energy needed to break covalent bonds
Answers
Answer:
The strength of a bond between two atoms increases as the number of electron pairs in the bond increases.
Explanation:
What angle is needed to spread 4 bonds as far apart as possible?
Answers
Answer:
109°
Explanation:
According to Valence Shell Electron Pair Repulsion Theory, electron pairs on the valence shell of the central atom of a molecule must be positioned as far apart in space as possible to minimize repulsion between valence shell electron pairs.
The shape of a molecule depends on the number and type of electron pairs on the valence shell of its central atom. Lone pairs generally cause more repulsion than bond pairs of electrons.
The ideal bond angle for a molecule with four bonds is 109° which corresponds to a tetrahedral geometry. This enables the four bonds to spread as far apart in space as possible.
Which technology has helped improve scientists’ ability to gather scientific data about the movement of sea turtles? satellite tracking thermometers probeware microscopes?
Answers
Answer:either satellite tracking or probware.
Explanation:probate. Think its satalite tracking hope this helps.
Answer:
its satellite tracking
Explanation:
i got it right on edge
A peregrine falcon dives 176 meters through the air in 8 seconds. Its
average speed during the dive is 22 m/s. *
Answers
Answer:
This question is asking to find the average speed during the dive. The answer is 22m/s.
Explanation:
Average speed of a substance can be calculated knowing it's distance over a particular amount of time.
The formula for average speed is:
Average speed (s) = Distance (d) / time (t)
In the case of this question where A peregrine falcon dives 176 meters through the air in 8 seconds, the distance of the falcon is 176m, while the time is 8s. Hence;
Average speed = 176/8
Average speed = 22
Therefore, the average speed of the falcon diver is 22m/s.
which of the following is not true about water ? *
Water has a freezing point of 0℃
Water is chemically stable and makes a good energy source
Water has a density of 1 g/mL
water is polar
water has a boiling point of 100℃
Water is less dense as a solid
Answers
Complete the chemical combustion reaction of naphthalene, which
demonstrates the conservation of mass.
C10H8 + 1202 >>
Answers
Answer:
[tex]C_{10}H_{8}+12O_2\rightarrow 10CO_2+4H_2O[/tex]
Explanation:
Hello,
In this case, since combustion reactions yield carbon dioxide and water via the following equation:
[tex]fuel+O_2\rightarrow CO_2+H_2O[/tex]
In such a way, for naphthalene, its combustion reaction is:
[tex]C_{10}H_{8}+12O_2\rightarrow 10CO_2+4H_2O[/tex]
Whereas we see ten carbon atoms, eight hydrogen atoms and twenty four oxygen atoms at both reactants and products as a proof of the law conservation of mass.
Regards.
Convert a speed of 933 cm/s to units of inches per minute
Answers
Answer:
220000 in/min
Explanation:
Step 1: Write out conversions
1 in ≈ 2.54 cm
60 sec = 1 min
Step 2: Set up dimensional analysis
[tex]\frac{933cm}{s} (\frac{60s}{1min} )(\frac{1in}{2.54cm} )[/tex]
Step 3: Evaluate
220039.4 in/min
Step 4: Sig figs
There are 3 sig figs
220039.4 in/min ≈ 220000 in/min
Express 2.99 x 108 m/s (the speed of light) in decimal notation (i.e., express the
number without using scientific notation
Answers
Answer:
speed of light = 299,000,000 m/s
Explanation:
The speed of light in vacuum, denoted as c, is a universal physical constant which unlike space and time, is independent of the observer. It is a constant that is important in many fields of science. Its exact value is given as 299,792,458 metres per second.
In scientific notation, it is approximately given as 2.99 x 10⁸ metres per second.
2.99 x 10⁸ metres per second = 2.99 x 100000000 = 299,000,000 m/s
Therefore, when expressed in decimal notation, the speed of light = 299,000,000 m/s.