4.47 consider the cis and trans isomers of 1,3-di-tert-butylcyclohexane (build molecular models). what unusual feature accounts for the fact that one of these isomers apparently exists in a twist boat conformation rather than a chair conformation?

Answers

Answer 1

Considering the cis and trans isomers of 1,3-di-tert-butylcyclohexane, trans isomer is more likely to exist in twist boat conformation.

What is twist boat ?

Conformation is the spatial arrangement of the atoms in molecule. there are a variety of conformations are possible for cyclohexane. Twist boat conformation moves the hydrogen atoms attached to carbon atoms 1 and 4 farther apart so that the steric strain is reduced.  Free rotation can be frequently observed in linear, single covalent bonds. However, rotation can also be observed in few ring structures.

t-butyl in axial position in cyclohexane is very disfavored by energy.  When you have trans 1,3 - both chairs have 1 axial and 1 equatorial, so both chairs are disfavored due to steric hindrance. Twist boat can minimize the unfavorable interactions among the t-butyls and this makes the molecule more stable.

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Related Questions

Help please I been stuck on this

what might an engineer need to consider when designing a heating/cooling system for a home in a cooler climate?

How might the design differ for a house found in a warmer climate?

Answers

An engineer might need to consider this when designing a heating/cooling system for a home in a cooler climate are Operating Environment, Size Matters, Available Power, and Filtration.

The design might differ for a house found in a warmer climate as the inside environment of buildings will be impacted by a warmer climate, which will also impair the longevity of building materials. A larger requirement for cooling will result from hotter summers. The word "HVAC" refers to the many systems that are employed in both residential and commercial structures for the purpose of heating, cooling, and transferring air between indoor and outdoor areas.

These are the systems that keep you cozy and toasty during the winter and cool and energized during the summer. The three essential elements of heating and cooling systems are a source of hot or cold air, a device for transferring the heated or cooled air into your living space, and a way to control the temperature in your home.

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A sample of 11.7 moles of silver bromide is reacted
with 8.6 moles of sodium thiosulfate to produce
sodium silver thiosulfate and sodium bromide. Using
the balanced equation below, predict which is the
limiting reactant and the maximum amount in moles
of sodium bromide that can be produced.

AgBr + 2Na2S2O3 → Na3Ag (S₂03)2 + NaBr

A. sodium thiosulfate, 4.30 moles
B. sodium thiosulfate, 8.60 moles
C. sodium bromide, 5.85 moles
D. sodium bromide, 11.7 moles

Answers

Answer:

0.30 moles of sodium thiosulfate formula units are needed to make 0.10 moles of AgBr soluble.

Explanation:

3Na2S2O3 + Ag Br→ NaBr + Nas [Ag(S2O3)3 According to reaction, 1 mole of silver bromide dissolves in 3 moles of Sodium thiosulfate. Then 0.10 moles of AgBr will dissolve with:3/1 x 0.10mol = 0.30mol - 0.30 moles of sodium thiosulfate formula units are needed to make 0.10 moles of AgBr soluble. Hope it will be

how does the octet rule explain the formation of a calcium ion? how does the octet rule explain the formation of a calcium ion? by losing two valence electrons from the fourth energy level, calcium achieves an octet in the third energy level so it attains [kr] electron configuration. by gaining two valence electrons into the fourth energy level, calcium achieves an octet in the fourth energy level. by losing two valence electrons from the fourth energy level, calcium achieves an octet in the third energy level so it attains [ne] electron configuration. by losing two valence electrons from the fourth energy level, calcium achieves an octet in the third energy level.

Answers

Group 2 of the periodic table places calcium, or Ca, which has two electrons on its outermost shell. Calcium must lose these two outermost electrons, also known as valence electrons, in order to have a full octet. Ionic compounds will be created when calcium reacts with nonmetals.

What is the octet rule rule?The octet rule describes an atom's propensity to prefer eight electrons in its valence shell. Atoms with fewer than eight electrons are more likely to interact with one another and create more stable compounds.Group 2 of the periodic table places calcium, or Ca, which has two electrons on its outermost shell. Calcium must lose these two outermost electrons, also known as valence electrons, in order to have a full octet. Ionic compounds will be created when calcium reacts with nonmetals.Only the main group elements are subject to the octet rule. The octet rule is known to be followed by the molecules of carbon, oxygen, nitrogen, and halogens. The s-block elements are typically among the elements that follow this rule.

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HELP MEEEEE IMA FAIL
Calcium has a 2+ charge, and
oxygen has a 2- charge. A
Lewis dot diagram should
contain one calcium atom and
one oxygen atom to show how
these atoms form an ionic
bond.
O True
O False

Answers

The statement ,Lewis dot diagram having 1 calcium atom and 1 oxygen atom to form an ionic bond is true.

What is an ionic bond?

Ionic bond or electrovalent bond is a type of bond which is formed between two elements when there is an exchange of electrons which takes place between  the atoms resulting in the formation of ions.

When the atom looses an electron it develops a positive charge and forms an ion called the cation while the other atom gains the electron and develops a negative charge  and forms an ion called the anion.

As the two atoms are oppositely charged they attract each other which results in the formation of a bond called the ionic bond.

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Answer:

A true

Explanation:

this reaction is first order with respect to reactant a and second order with respect to reactant b. if the concentration of a is doubled and the concentration of b is halved, the rate of the reaction would by a factor of .

Answers

The rate of reaction will reduce by a factor of ½ when the concentration of A and B is doubled and halved respectively.

The reaction rate or rate of reaction is the rate at which a chemical reaction occurs, defined as proportional to the rise in product concentration per unit time and the reduction in reactant concentration per unit time. Chemists calculate reaction rates by initiating the reaction, evaluating the concentration of the product or reactant at various time points throughout the reaction, occasionally charting the concentration as a function of the time on a graph, and then computing the alteration in concentration per unit time. The rate of reaction may be calculated by calculating the amount of product created in a given amount of time. The time period used may be determined by the rate of the reaction.

Reaction:

[tex]A + 3B \rightarrow 2C + D[/tex]

Reaction rate is given as:

Rate =  [tex]K [A][B]^2[/tex]

First order:

Rate (1) = [tex]K [A][B]^2[/tex]

When the concentrations of A and B is doubled and halved respectively:

Rate (2) = [tex]K [2A][B/2]^2[/tex]

Rate (2) = 2 [tex]\frac{K [A][B]^2}{4}[/tex]

Rate (2) = ½ [tex]K [A][B]^2[/tex]

Therefore, the rate of reaction will reduce by a factor of ½.

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Particle
Proton
Neutron
Electron
Charge
A =
+1
0
-1
Location
Nucleus
Nucleus
Orbitals
Approximate
mass (amu)
1
1
0
Made of
quarks?
A
B
00
C
Complete the table to summarize the properties of the different subatomic particles by typing in "yes" or
"no."

Answers

Charge on neutron, proton and electron is 0,1,-1 respectively, proton and neutrons are in nucleus while electron are in orbitals, the mass of electron is nearly 0 while mass of proton and neutron is 1 amu and only proton and neutrons are made up of quarks.

Electron, neutron and proton, all three are sub-atomic particles.

The charge on Neutron is 0.

The charge on Electron is -1.

The charge on Proton is +1.

Protons and neutrons are found inside the nucleus because they only are forming the nucleus, this is why they are also called Nucleons.

The electrons are found in the orbitals.

Approximate mass of Proton and Neutron is 1 amu. But the electron is very very light as compared to electron. So, we can assume it to be zero.

Protons and Neutrons are made up of Quarks but electron is not made up of quark.

Electron and Quarks are the fundamental particle in an atom.

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What type of protons do you need to create a galaxy

Answers

According to the question ,[tex]10^{80}[/tex]  protons create a galaxy.

Why do protons exist?

1.67262 1027 kg, or 1,836 times the mass of an electron, is the rest mass of the proton, a stable subatomic particle with a positive charge that is equivalent to one electron's charge.

What materials make up proton?

One down quark and two up quarks make up protons. Two down quarks and one up quark make up neutrons. One of the four fundamental forces, the "strong nuclear force," keeps the nucleus together (gravity and electromagnetism are two others).

The amount of protons in the cosmos is measured by the Eddington number , in astrophysics. Eddington estimated it to be approximately 1.571079; according to recent estimations  [tex]10^{80}[/tex].

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the vibrational frequency of the cl2 molecule in the gas phase is 559.7 cm−1 . calculate the ratio of the number of cl2 molecules in the first excited vibrational state to the number of molecules in the ground state at 298k

Answers

The ratio of the number of chlorine gas molecules in the first excited vibrational state to the number of molecules in the ground state at 298k is calculated to be 0.067.

The formula to calculate this ratio can be given as;

[tex]N_{1} / N_{0}[/tex] = [tex]exp (-\frac{hvc}{k_{B}T } )[/tex]

In this equation;

h represents the Planck's constant whose value equals 6.626 × 10^-34 Js

v represents the vibrational frequency

c represents the speed of light which is equal to 2.998 × 10^10 cm s^-1

[tex]k_{B}[/tex] means the Boltzmann constant which is equal to 1.381 × 10^-23 JK^-1

T is equal to 298 K

substituting these values in the above equations;

[tex]N_{1} / N_{0}[/tex] = exp {- (6.626 × 10^-34) (559.7) (2.998 × 10^10) ÷ (1.381 × 10^-23) (298K)}

[tex]N_{1} / N_{0}[/tex] = 0.067

Therefore, the ratio of the number of chlorine gas molecules in the first excited vibrational state to the number of molecules in the ground state at 298k is equal to 0.067.

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Given this equation: N2 + 3 H2 → 2 NH3, how many moles of NH3 can be produced from 3.1 moles of H2?

Answers

First, we write down our reaction:

N2 + 3H2 → 2NH3

Don't forget to balance it.

We only use moles as units.

Procedure:

3 x 1 mole H2 ------------ 2 x 1 mole NH3

3.1 moles H2 ------------- x

x = 2.1 moles NH3 are produced

Answer: 2.1 moles NH3

a lewis structure will usually require one or more multiple bonds if there is an atom present that does not have a full after all available electrons have already been placed. the multiple bond is formed by exchanging one electron pair for each new bond.

Answers

A lewis structure will usually require one or more multiple bonds if there is an atom present that Octet does not have a full after all available electrons have already been placed. the multiple bonds are formed by exchanging one lone electron pair for each new bond.

The entire number of valence electrons should be known. Step 2: Outline the molecule's skeletal structure. Step 3: Form each bond in the skeletal structure using two valence electrons. Step 4: Attempt to fill the remaining valence electrons' nonbonding positions to fulfill the atoms' octets.

The valence shell electrons in a molecule are depicted in an extremely simplified manner by a Lewis Structure. It is used to demonstrate how the electrons in a molecule are positioned around particular atoms. When two atoms are bonded together, electrons are depicted as "dots" or as a line.

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Most elements' names end in the suffix -ium. This practice started around the year 1800, with many elements discovered before that having a more common name. However, some elements are more recently discovered and don't end in -ium. Do you notice any patterns for these elements?

Answers

Most elements' names end in the suffix -ium this practice started around the year 1800, with many elements discovered before that having a more common name however, some elements are more recently discovered and don't end in -ium because element name start with the latin name and then it give suffix to the element

The ium in helium can be thought of carrying the meaning 'derived from' with the hel part representing greek helios means sun it having being inferred that helium was present in sun atmosphere and the ium suffix is a latin suffix which forms abstract nouns, thus it is used to form chemical elements name from its naming origin

There are 81 elements that end in the suffix ium or um which is derived from the latin and it is denoted a metallic substances

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Consider the balanced reaction below:

Answers

Hint: Tetrafluoromethane, otherwise called carbon tetrafluoride or R−14

, is the most straightforward perfluorocarbon (CF4

). As its IUPAC name shows, tetrafluoromethane is the per fluorinated partner to the hydrocarbon methane. It can likewise be named a haloalkane or halomethane.

Complete step by step answer:

On the off chance that you take a gander at the condition, you will see that for each one mole of C

that is responded, one mole of CF4

is delivered. Thus, 1.46

moles of CF4

are created (expecting that there is sufficient F2

). A mole of CF4

has a mass of around 88

grams, so 1.46

moles is equivalent to 128.48

grams. Adjusted to critical figures, your answer will be 128

grams.

Let’s do it bit by bit:

First Change moles of carbon to moles of CF4

n(CF4)=1.46 mol C × (1 mol CF41 mol C) = 1.46 mol CF4

At that point convert moles of CF4

to grams of CF4

utilizing the molar mass

M(CF4)=(1×12+4×19)gmol−1=88gmol−1

m(CF4)=nM=1.46mol×88gmol−1=128g

So, the required answer is [128g]

THIS IS VERY URGENT IM OFFERING 60 POINTS AND ILL MAKE YOUR BRAINLIEST!!!


An isotope of the element iridium has a 77 protons and 115 neutrons in its nucleus.

Which of the following correctly represents this isotope?


A.115 over 77 Ir

B. 77 over 115 Ir

C. 192 over 77 Ir

D. 192 over 115 Ir


PLEASE HURRY :C

Answers

Answer: 192 over 77 Ir

Explanation:

Iridiums atomic mass is 192.217 and to get 192 you would add both protons and neutrons to get the atomic mass. When writing in isotope notation, the mass goes on top.

at the end of a reaction how much mass is present compared to the start of a reaction (if all products are captured) ?

Answers

Answer:At the end of chemical reactions, the total mass of the reatants compared to the total mass of the products - c) the mass is the same. Reason : all chemical reactions follow law of conservation of mass which states that mass of reactants and products remains the same

Explanation:hope this help <3

Determine the number of bonding electrons and the number of nonbonding electrons in the structure of.

Answers

A full valence shell's number of electrons less the amount of electrons involved in bonding equals the number of non-bonding electrons (which is 2 x the typical number of bonds). The amount of electrons not in bonds is equal to the number of lone pairs divided by two.

How can you tell how many electrons are involved in bonds and how many are not?A full valence shell's number of electrons less the amount of electrons involved in bonding equals the number of non-bonding electrons (which is 2 x the typical number of bonds). The amount of electrons not in bonds is equal to the number of lone pairs divided by two.Method 1 for Calculating Bond Order (immediately determine bond order, half bond order) Antibonding Electrons.According to the molecular orbital theory, the difference between bonding and anti-bonding electrons is accounted for by the bond order. Additionally, the molecule will grow more stable the higher the bond order.

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Mary thought that the number of frogs in the neighborhood pond had decreased over the last few years. So, she decided to count the number of frogs she saw around the pond twice each day for ten days. Mary's data is displayed in the table below. Day 1 2 3 4 5 6 7 8 9 10 # Frogs at 12 PM 3 2 1 0 1 0 3 2 0 2 # Frogs at 7 PM 15 21 22 13 19 15 20 17 23 18 Based on her observations, which of the following can Mary infer? A. The number of frogs at the pond has steadily increased over the last 2 years. B. Frogs are consumed by predators in the morning and are reborn in the evening. C. The number of frogs at the pond has steadily declined over the last 2 years. D. Frogs rest during the afternoon and become more active in the evening.

Answers

Based on her observations, marry infer that Frogs rest during the afternoon and become more active in the evening. option D.

Observations can occur in a lab placing or the herbal world. for example, watching an apple fall from a tree can be a commentary. Noticing that fish only come to a particular part of the river in the early morning is likewise a remark. Smelling garbage decomposing is some other instance of a remark.

The remark is the movement or technique of cautiously looking at a person or something. Careful statement of the motion of the planets. Synonyms looking, have a look at, survey, evaluation more Synonyms of statement.

Observations of a particular setting or state of affairs--this is, take field notes. next, you interpret the notes consistent with the applicable criteria. in the end, you write a nicely prepared paper that presents your observations and interpretations, typically with the goal of answering a research question.

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A molecule contains 3 atoms. It has 1 triple bond and 1 single bond. There are no lone pairs on any of the atoms. How many rheds are within the molecule?.

Answers

The given molecule has only 1 rhed – region of high electron density because of presence of one triple bond.

An electron density zone might be either bonding or non-bonding. Electrons in a covalent bond between two atoms are counted as one region, whether the link is single, double, or triple (or anything in between). The amount of lone pairs on the core atom is used to count non-bonding areas.

Double and triple bonds qualify as one high electron density region. A single unpaired electron counts as one high electron density region. One can utilize any of the resonance structures for molecules or ions that have resonance structures.

A high electron density atom or group indicates that some component of the molecular structure (such as resonance or inductive effects) is transferring negative charge towards this location in the molecule.

In the given molecule, A – B ≡ C

Only one triple bond is there and no lone pairs of electrons. Hence, only 1 rhed (region of high electron density) is present within the molecule.

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write molecular equation (m.e.), ionic equation (i.e.), and net ionic equation (n.i.e.) for each of the following reactions. 1) potassium phosphate with copper (ii) acetate

Answers

The molecular, ionic, and net ionic equations of the reaction between potassium phosphate and copper (II) acetate are given below.

The physical states of the substances are depicted in the balanced chemical equation known as a molecular equation, which we may determine using the solubility principles.

When formulae for compounds are expressed as though they were all molecules, the equation is referred to as a molecular equation.

When dissolved ionic chemicals are represented as free ions, the equation is said to be an ionic equation.

A chemical equation known as an ionic equation expresses the electrolytes in aqueous solution as dissociated ions.

A chemical equation known as the net ionic equation shows how ions or molecules change throughout a process.

Net ionic equations lack the common ions that exist on both sides of the ionic equation and are known as spectator ions. In a reaction, ions that do not change at all are known as spectator ions.

Molecular equation:

[tex]2K_3PO_4 (aq) + 3Cu(CH_3COO)_2 (aq) \rightarrow 6K(CH_3COO) (aq) + Cu_3(PO_4)_2 (s)[/tex]

Ionic equation:

[tex]6K^+ (aq) + 2PO_4^{3-} (aq) + 3Cu^{2+} (aq) + 6CH_3COO^- (aq) \rightarrow 6K^+ (aq) + 6CH_3COO^- (aq) + Cu_3(PO_4)_2 (s)[/tex]

Net Ionic equation:

[tex]3Cu^{2+} (aq) + 2PO_4^{3-} (aq) \rightarrow Cu_3(PO_4)_2 (s)[/tex]

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a 1.00 g sample of gas occupies 250 ml at 273 k and 1.00 atm. calculate the molar mass of the gas. multiple choice question. 89.7 g/mol 24.9 g/mol 1.12 × 10–2 g/mol 0.897 g/mol

Answers

The given sample of gas if found to have a molar mass of 89.686g/mol.

For bulk quantities, the molar mass makes it possible to convert between a substance's mass and its quantity. It is determined as the total of all of the substance's atoms' standard atomic weights.

PV = nRT, where P is pressure (in atm), V is volume (in L), n is the No. of moles of gas, universal gas constant is denoted by R (0.082 Latm/molK), and T is temperature (in K), is the formula used to calculate the molar mass of a gas.

Given:

Mass of gas = 1g

P = 1atm

V = 250mL

T = 273K

To find:

Molar mass of Gas = ?

Formula:

PV = nRT

Calculations:

n = 1 x 0.25 / 0.082 x 273

n = 0.01115 mol

Mass of gas = No. of moles x molar mass

Molar mass = 1 / 0.01115

Molar mass = 89.686g/mol

Result:

The gas is found to have 89.686g/mol molar mass.

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Eukaryotic cells contain a structure called the _______ which is distinct central organelle that contains the cells ____ material.

Answers

Eukaryotic cells are organelles with a developed nucleus. Eukaryotic cell contains a structure called cytoskeletal structure which is distinct central organelle that contains the cells genetic material DNA.

What is Eukaryotic cells?

There are two type of cells based on the nucleus. If the cell is having a well developed nucleus it is called eukaryotic cells and the cell which have no developed nucleus is called prokaryotic cell.

Eukaryotic cells contains nucleus, cytoplasm, endoplasmic reticulum, lysosomes, mitochondria and ribosomes.

In eukaryotic cells contains a cytoskeletal structure inside cytoplasm consist of fibers, microtubules and filaments which make it strong.

The genetic material DNA is placed inside this cytoskeleton. Cytoskeleton provide perfect shape to the cell and helps to stimulate the cell movement.

Therefore, the special organelle contained in eukaryotic cells which contains the genetic material DNA.

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The question is in the photo✨✨✨(Sorry) In the answer: Please leave all the numbers after the decimal point

Answers

36.2L of N2 can be produced.

1st) According to the stoichiometry of the reaction, 2 moles of NaN3 produce 3 moles of N2. Using the molar mass of NaN3 (65.0g/mol ) and N2 (28.0g/mol) we can convert the moles to mass, and we can see that with 130.0g of NaN3 we can produce 84.0g of N2.

Now, we can use a mathematical rule of three to calculate the grams of N2 that can be produced from 71.0g of NaN3:

[tex]\begin{gathered} 130.0gNaN_3-84.0gN_2 \\ 71.0gNaN_3-x=\frac{71.0gNaN_3\cdot84.0gN_2}{130.0gNaN_3} \\ x=45.9gN_2 \end{gathered}[/tex]

So, 45.9g of N2 are produced from 71.0g of NaN3.

2nd) It is necessary to convert the grams of N2 produced to moles, so we can use it in the Ideal gas equation:

[tex]\begin{gathered} 28.0gN_2-1mol \\ 45.9gN_2-x=\frac{45.9gN_2\cdot1mol}{28.0gN_2} \\ x=1.6\text{mol} \end{gathered}[/tex]

Now we know that 1.6mol of N2 are produced.

3rd) To calculate the volume of N2, it is necessary to use the Ideal gas equation and replace the values of Pressure (P), Temperature (T, in Kelvin) and Number of moles (n):

[tex]\begin{gathered} P\mathrm{}V=n\mathrm{}R\mathrm{}T \\ 1.30\text{atm}\cdot V=1.6\text{mol}\cdot0.082\frac{atm\cdot L}{mol\cdot K}\cdot359K \\ V=\frac{1.6mol\cdot0.082\frac{atm\cdot L}{mol\cdot K}\cdot359K}{1.30\text{atm}} \\ V=36.2L \end{gathered}[/tex]

Finally, 36.2L of N2 can be produced from 71.0g of NaN3.

Which of the following statements correctly explains why physical properties of a substance can be used to separate mixtures?
( HELP NEEDED ASAP!!!! )

When substances are mixed together, they retain their physical properties.


Mixtures contain different substances with different properties and chemists can separate one item from the mixture by forcing it to undergo a chemical change.


When substances are mixed together, the mixture assumes the physical properties of each individual substance.


When substances are mixed together, you can see each individual component.

Answers

The statements that correctly explains the use of physical properties of a substance to separate mixtures are

Statement 1: When substances are mixed together, they retain their physical properties.

Statement 3: When substances are mixed together, the mixture assumes the physical properties of each individual substance.

Mixtures are compounds that are made up of two or more chemical compounds which are not linked to each other chemically. They can be easily separated as there are no chemical reaction between each other.

Mixtures are compounds that retain their respective physical properties even though they were mixed together as there are no reaction between the two. Thus, these physical properties can be used to separate mixtures. Example: Oil in water. They have different densities. Thus, oil will float on water. We can exploit this physical property and separate them using separating funnel.

Mixtures contain different substances with different properties and chemists cannot separate one item from the mixture by forcing it to undergo a chemical change as there is no chemical reaction.

When substances are mixed together, you can see each individual component. But without knowing their property, we cannot separate them

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a modified ringer’s irrigation has the following formula: sodium chloride 4.6 g potassium chloride 0.2 g calcium chloride 0.43 g peg 3350 25 g water for injection ad 500 ml assuming that 470 ml of water is used in preparing the irrigation, calculate its specific gravity.

Answers

The specific gravity of a modified ringer's irrigation is 1.06g/ml

We start by calculating total mass of ingredients:

Total mass of ingredients=4.6+0.2+0.43+25+500

                                          =530.23g

Volume of water=500ml

We now get the density of the solution:

Density=Mass of ingredients/volume of water

           =530.23/500

           =1.06g/ml

Calculate the specific gravity:

Specific gravity=Density of substance/Density of water

( Density of water=1g/ml)

Specific gravity=1.06/1

                         =1.06g/ml

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What is the density?

Answers

Answer:

Density = mass/volume (g/cm³)

First find the volume of the stone by subtracting the readings of the measuring cylinder.

Each unit is 4 ml. Take the reading where the lowest point of the curve of the liquid sits.

The first measuring cylinder reading is 24 ml.

The second measuring cylinder reading is 60 ml.

Volume of stone = 60 - 24 = 36 ml

Make sure the units are appropriate. Convert when necessary. ml and cm³ are the same so there is no need to convert. (36 ml = 36 cm³)

Density = 40/36 = 1.11 g/cm³

What volume of gas is generated when 58. 0 l of oxygen gas reacts at stp according to the following balanced equation? assume that the reaction goes to completion and that no starting materials remain.

Answers

The volume of gas that is CO2 generated when 58.0 L of oxygen reacts at STP is 38.67 L.

At STP, Temperature is 0°C and Pressure is 1 atm. So in this condition the one mole of gas will occupy  a volume of 22.4 L.

Since the given equation goes to completion as given in the question, the balanced chemical equation will be:

              CH₃CH₂OH  + 3O₂  ⇒ 2CO₂ + 3H₂O

From this we can calculate the mole ratio O2 to Co2 and that is 3:2.

From this we can find the volume of Co2,

Volume of CO₂ = 58  × ²/₃

Volume of CO₂ = 38.67 L

Hence the volume of gas that is CO2 generated when 58.0 L of oxygen reacts at STP is 38.67 L.

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a sample of gas contains 1.75 moles at 37.8 °c in a volume of 3.61 l. if 2.67 moles of gas are added, what is the new volume (in l) assuming temperature and pressure do not change.

Answers

Using Avogadro’s law, the new volume of the gas is found to be 9.11L

Avogadro's law is a gas law that relates the volume of a gas to the amount of gas substance present. According to Avogadro's law, "equivalent volumes of all gases have the same number of molecules at the same temperature and pressure." Avogadro's law asserts that given the same temperature and pressure conditions, similar volumes of different gases contain an equal number of molecules.

Given:

V1 = 3.61L

n1 = 1.75 moles

n2 = 4.42 moles

To find:

V2 = ?

Formula:

V1/V2 = n1/n2

Calculation:

V2 = V1n2/n1

V2 = 3.61 x 4.42 / 1.75

V2 = 9.11L

Result:

The volume of the gas is found to be 9.11L

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Calculate the density of a fluid that has a mass of 100 grams and a volume of 97.18 cm3. Use a calculator if necessary.

Answers

Answer:

Density = mass÷volume (g/cm³)

= 100÷97.18

= 1.029

= 1.03 g/cm³ (3 significant figures)

3. If an acid has a pH of 2, what is its [H*]?

Answers

If an acid has a pH of 2, then [H⁺] of the given acid is 100.

What is an acid?

An acid is a molecule or ion that may either donate a proton (i.e. hydrogen ion, H+) as a Brnsted-Lowry acid or establish a covalent bond with an electron pair as a Lewis acid. The proton donors, also known as Brnsted-Lowry acids, are the first type of acid. Proton donors in aqueous solutions generate the hydronium ion H3O+ and are known as Arrhenius acids. The Arrhenius hypothesis was expanded by Brnsted and Lowry to include non-aqueous solvents. A Brnsted or Arrhenius acid is often composed of a hydrogen atom coupled to a chemical structure that remains energetically advantageous following the loss of H+.

pH = log[H⁺]

[H⁺] = antilog(pH)

= 10² = 100

Hence, [H⁺] of the given acid is 100.

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HCl has a molarity of 0.010 M and is a 0.010 M solution. Since [H+] = 1 x 10-2 M, this is true. This H+ ion solution is aqueous, and its pH value is 2.

Describe an acid ?

A  Lewis acid is a molecule or ion that can either contribute a proton (such as the hydrogen ion, H+) or form a covalent bond with an electron pair. The first kind of acid is the proton donor, also Brnsted-Lowry acid. Arrhenius acids are proton donors in aqueous solutions that produce the hydronium ion H3O+. Brnsted and Lowry expanded the Arrhenius hypothesis to incorporate non-aqueous solvents. A Brnsted or Arrhenius acid is frequently made up of a hydrogen atom attached to a chemical structure that continues to be energetically beneficial even after H+ is lost.

pH = log[H⁺]

[H⁺] = antilog(pH)

= 10² = 100

Hence, [H⁺] of the given acid is 100.

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What is the name of the product when you reduced 1-
hydroxy-2-hexanone
with sodium borohydride
(NaBH)?
Answer:

Answers

The name of the product on reducing 1-

hydroxy-2-hexanone with sodium borohydride is 1,2 - Dihydroxyhexane

Reduction of carbonyl compounds:

Carbonyl compounds undergo reduction using suitable reducing agent forming alcohols. A number of reducing agents serve this purpose. Some common reducing agents used are:

Sodium borohydrideLithium aluminium hydrideHydrogen in the presence of a catalyst like Platinum or Palladium

What is Sodium borohydride?

Sodium borohydride (NaBH4) is a reducing reagent that transforms aldehydes and ketones to their corresponding alcohol.It converts aldehydes to primary alcohol and ketones to secondary alcohols

We can see that, since the second Carbon on product side has only one hydrogen along with OH group,  thus it is a secondary alcohol.

Primary alcohols have 2 hydrogen with the carbon along with hydroxyl group, while tertiary alcohols have no hydrogen on the carbon with hydroxyl group.

Thus we can conclude that the name of the product on reducing 1-hydroxy-2-hexanone with sodium borohydride is 1,2 - Dihydroxyhexane

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A sample of nitrogen gas occupies a volume of 7.22 L at 60.0°C and 402 torr.

If the volume of the gas sample is decreased to 5.29 L, while its temperature is decreased to –4.0°C, the resulting gas pressure will be

Answers

The resulting gas pressure will be 512.08 torr.

By ideal gas law, PV = nRT

P = pressure

V = volume

n = number of mole of gas

R = gas constant

T = temperature

Using ideal gas law, P₁V₁/ T₁ = P₂V₂/ T₂

P₁= 402 torr

V₁ = 7.22 L

T₁ = 60.0°C

P₂ = ?

T₂ = 56° C

V₂ = 5.29 L

Put these values in formula, P₁V₁/ T₁ = P₂V₂/ T₂

P₂ =  P₁V₁T₂/ T₁ V₂

P₂ = 402 torr ×7.22 L ×56° C / 60.0°C ×5.29 L

P₂ = 512.08 torr

Hence, the resulting gas pressure will be 512.08 torr.

The ideal gas equation is formulated as: PV = nRT.

In this equation, P refers to the pressure of the ideal gas, V is the volume of the ideal gas, n is the overall quantity of ideal gas this is measured in terms of moles, R is the universal gas constant, and T is the temperature.

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